Anionically copolymerized living random (meth)acrylic copolymers and
copolymers prepared therefrom
    4.
    发明授权
    Anionically copolymerized living random (meth)acrylic copolymers and copolymers prepared therefrom 失效
    阴离子共聚的活性无规(甲基)丙烯酸共聚物和由其制备的共聚物

    公开(公告)号:US5977261A

    公开(公告)日:1999-11-02

    申请号:US98981

    申请日:1998-06-17

    CPC分类号: C08F20/12 C08F220/12

    摘要: Living random (meth)acrylic copolymers, facilely converted into random co(meth)acrylates and block copolymers thereof, comprise the anionic copolymerizates of at least one comonomer A with at least one comonomer B selected from among the (meth)acrylates and maleimides, at least one of the comonomers A and B comprising a (meth)acrylate, in the presence of (i) at least one alkali or alkaline earth metal, mono- or difunctional initiator and (ii) at least one ligand, for example a nonnitrogenous macrocyclic complexant, e.g., a crown ether, or an alkali metal alcoholate.

    摘要翻译: 活性无规(甲基)丙烯酸共聚物易于转化为无规共聚(甲基)丙烯酸酯及其嵌段共聚物,包含至少一种共聚单体A与至少一种选自(甲基)丙烯酸酯和马来酰亚胺的共聚单体B的阴离子共聚物, 在(i)至少一种碱金属或碱土金属,单 - 或双官能引发剂存在下,包含(甲基)丙烯酸酯的至少一种共聚单体A和B,和(ii)至少一种配体,例如非氮大环 络合剂,例如冠醚或碱金属醇化物。