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    Surface area of cobalt catalyst supported by silica carrier material
    1.
    发明申请
    Surface area of cobalt catalyst supported by silica carrier material 审中-公开
    由二氧化硅载体材料负载的钴催化剂的表面积

    公开(公告)号：US20030105170A1

    公开(公告)日：2003-06-05

    申请号：US10252620

    申请日：2002-09-23

    申请人： Conoco Inc.

    发明人： Kandaswamy Jothimurugesan ,  Rafael L. Espinoza ,  Nithya Srinivasan

    IPC分类号： C07C027/06 ,  B01J021/08

    CPC分类号： C10G2/332 ,  B01J21/08 ,  B01J23/75 ,  B01J23/8913 ,  B01J35/0053 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/031 ,  C10G2/333

    摘要： The present invention teaches a method for increasing the cobalt surface area per gram of catalyst in a cobalt Fischer-Tropsch catalyst, supported on a silica-based carrier material, by using cobalt amine carbonate precursors. A Fischer-Tropsch catalyst preferably includes a catalytically active first metal containing cobalt, and a carrier material containing silica or a silica compound with a cobalt surface area greater than 13 m2/g catalyst. The catalyst active in the FT reaction has a minimum alpha value of 0.87 and a CO conversion of 24 wt % or more. In accordance with another preferred embodiment, a process for producing a Fischer-Tropsch catalyst includes saturating silica or silica compounds with a solution of cobalt amine carbonate, removing the excess solution by filtration, heating the resulting product in order to allow cobalt hydroxycarbonate to precipitate, and drying and calcining the resulting product. Optionally the calcined product is reduced.

    摘要翻译： 本发明教导了一种通过使用碳酸钴前体增加负载在二氧化硅基载体材料上的费 - 托催化剂中每克催化剂的钴表面积的方法。 费 - 托催化剂优选包括含有钴的催化活性第一金属和含有二氧化硅或钴表面积大于13m 2 / g催化剂的二氧化硅化合物的载体材料。 在FT反应中活性的催化剂的最小α值为0.87，CO转化率为24重量％以上。 根据另一个优选的实施方案，制备费 - 托催化剂的方法包括用碳酸钴胺溶液使二氧化硅或二氧化硅化合物饱和，通过过滤除去过量的溶液，加热所得产物以使羟基碳酸钴沉淀， 并干燥并煅烧所得产物。 任选地，煅烧产物被还原。

    Metal oxide-containing catalysts and use thereof in fischer-tropsch processes
    4.
    发明申请
    Metal oxide-containing catalysts and use thereof in fischer-tropsch processes 审中-公开
    含金属氧化物的催化剂及其在费 - 托法中的应用

    公开(公告)号：US20030027874A1

    公开(公告)日：2003-02-06

    申请号：US10184472

    申请日：2002-06-27

    申请人： Conoco Inc.

    发明人： Norman Herron ,  Kostantinos Kourtakis ,  Munirpallam A. Subramanian ,  Olga Ionkina ,  Nithya Srinivasan

    IPC分类号： C07C027/06

    CPC分类号： C10G2/331

    摘要： A catalyst and process for producing hydrocarbons using the catalyst is provided. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with the catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention the catalyst used in the process includes at least one catalytic metal for Fischer-Tropsch reactions, preferably cobalt. The catalyst further includes a structural component, preferably a support, that includes a metal selected from the group consisting of oxides of Group 2 metals, Group 3 metals, Group 6 metals, Group 8 metals, Group 12 metals, Group 15 metals, and combinations thereof, preferably as the oxide.

    摘要翻译： 提供了使用该催化剂生产烃的催化剂和方法。 该方法包括使包含氢气和一氧化碳的进料流与催化剂在保持在有效产生包含烃的流出物流的转化促进条件的反应区中接触。 根据本发明，用于该方法的催化剂包括至少一种用于费 - 托反应的催化金属，优选为钴。 催化剂还包括结构组分，优选载体，其包括选自第2族金属，第3族金属，第6族金属，第8族金属，第12族金属，第15族金属和组合的金属的金属 优选作为氧化物。