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公开(公告)号：US09944587B2
公开(公告)日：2018-04-17
申请号：US15110072
申请日：2014-06-12
发明人： Zhongning Xu , Guocong Guo , Siyan Peng , Zhiqiao Wang , Qingsong Chen , Mingsheng Wang , Yuangen Yao
IPC分类号： C07C67/36 , B01J23/89 , B01J37/08 , B01J37/16 , B01J37/34 , B01J21/04 , B01J21/10 , B01J21/06 , B01J21/08 , B01J21/18 , B01J23/02 , B01J23/06 , B01J23/44 , B01J23/48 , B01J23/40 , B01J35/00 , B01J35/02 , B01J37/02 , B01J23/46
CPC分类号： C07C67/36 , B01J21/04 , B01J21/063 , B01J21/066 , B01J21/08 , B01J21/10 , B01J21/18 , B01J23/02 , B01J23/06 , B01J23/40 , B01J23/44 , B01J23/462 , B01J23/464 , B01J23/466 , B01J23/468 , B01J23/89 , B01J23/8906 , B01J23/8913 , B01J23/892 , B01J23/8926 , B01J23/8946 , B01J23/8953 , B01J35/0013 , B01J35/006 , B01J35/023 , B01J37/0201 , B01J37/0203 , B01J37/0207 , B01J37/024 , B01J37/088 , B01J37/16 , B01J37/343 , B01J2523/00 , C07C69/06 , B01J2523/22 , B01J2523/824 , B01J2523/828 , B01J2523/847 , B01J2523/822 , B01J2523/48 , B01J2523/821 , B01J2523/47 , B01J2523/827 , B01J2523/41 , B01J2523/825 , B01J2523/27 , B01J2523/31 , B01J2523/842 , B01J2523/845 , B01J2523/17
摘要： A process for vapor-phase carbonylation of methanol to methyl formate, whereby a feed gas containing methanol, carbon monoxide, hydrogen and oxygen is passed through a reactor loaded with a supported nano-scaled platinum group metal heterogeneous catalyst to produce methyl formate by a vapor-phase carbonylation reaction, under reaction conditions with a space velocity of 500-5000 h−1, a temperature of 50-150° C. and a pressure of 0.01-2 MPa. Supported nano-scaled platinum group metal heterogeneous catalysts are prepared via ultrasonic dispersion and calcination. Methyl formate is produced and isolated under relatively mild conditions.
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公开(公告)号：US09931616B2
公开(公告)日：2018-04-03
申请号：US15146433
申请日：2016-05-04
IPC分类号： B01J37/02 , B01J37/00 , C07C29/50 , C07C29/153 , B01J23/745 , B01J35/10 , B01J37/08 , B01J37/16 , B01J37/06 , B01J23/889 , B01J23/00 , B01J23/80 , B01J23/89 , B01J29/03
CPC分类号： B01J23/745 , B01J21/08 , B01J23/002 , B01J23/72 , B01J23/80 , B01J23/8892 , B01J23/89 , B01J29/0333 , B01J35/1014 , B01J35/1019 , B01J35/1061 , B01J37/0018 , B01J37/0203 , B01J37/0205 , B01J37/0215 , B01J37/06 , B01J37/08 , B01J37/086 , B01J37/16 , B01J2229/18 , B01J2229/38 , C07C29/153 , C07C29/50 , C10G2/332
摘要： The invention relates to templated active material, including those deriving order from organic and/or inorganic templating agents. The invention also relates to methods for producing templated active material, and to active material produced by such methods, and the use of such templated active material for producing oxygenate.
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公开(公告)号：US09878308B2
公开(公告)日：2018-01-30
申请号：US15309930
申请日：2015-01-16
发明人： Junji Ito , Yasunari Hanaki , Tetsuro Naito , Misaki Akaishi
IPC分类号： B01J23/00 , B01J23/02 , B01J23/83 , B01D53/94 , B01J23/10 , B01J23/34 , B01J23/46 , B01J35/00 , B01J35/04 , B01J35/10 , B01J35/02 , B01J37/02 , B01J37/08
CPC分类号： B01J23/83 , B01D53/94 , B01D53/9472 , B01D2255/204 , B01D2255/2063 , B01D2255/2065 , B01D2255/2068 , B01D2255/207 , B01D2255/20715 , B01D2255/20738 , B01D2255/402 , B01D2255/9032 , B01J21/066 , B01J23/002 , B01J23/10 , B01J23/34 , B01J23/464 , B01J23/63 , B01J23/656 , B01J23/6562 , B01J23/89 , B01J23/894 , B01J23/8946 , B01J35/0006 , B01J35/0013 , B01J35/023 , B01J35/026 , B01J35/04 , B01J35/1038 , B01J35/1066 , B01J35/1071 , B01J37/0009 , B01J37/0201 , B01J37/0236 , B01J37/0244 , B01J37/0248 , B01J37/088 , B01J2523/00 , C01B3/16 , C01B3/40 , B01J2523/3706 , B01J2523/3725 , B01J2523/48 , B01J2523/822 , B01J2523/24 , B01J2523/3712 , B01J2523/842 , B01J2523/31 , B01J2523/845 , B01J2523/72
摘要： An exhaust gas purification catalyst includes: a first catalyst unit that consists of a hydrogen generating catalyst including a noble metal and an oxide that contains lanthanum, zirconium and an additional element such as neodymium; a second catalyst unit that consists of an oxygen storage/release material and a perovskite oxide disposed in contact with the oxygen storage/release material and represented by the general formula LaxM11-xM2O3-δ, where La is lanthanum, M1 is at least one element selected from the group consisting of barium (Ba), strontium (Sr) and calcium (Ca), M2 is at least one element selected from the group consisting of iron (Fe), cobalt (Co) and manganese (Mn), x satisfies 0
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公开(公告)号：US09873107B2
公开(公告)日：2018-01-23
申请号：US15126801
申请日：2015-03-17
申请人： BASF SE
发明人： Andreas Hass , Ekkehard Schwab , Franz Weber , Nicole Becker
IPC分类号： B01J21/18 , B01J23/648 , B01J35/00 , B01J37/03 , B01J37/02 , B01J37/08 , B01J35/10 , B01J37/00
CPC分类号： B01J21/18 , B01J23/63 , B01J23/6484 , B01J23/6522 , B01J23/89 , B01J35/0013 , B01J35/002 , B01J35/0033 , B01J35/006 , B01J35/0093 , B01J35/1019 , B01J35/1023 , B01J35/1028 , B01J37/0045 , B01J37/0203 , B01J37/0221 , B01J37/035 , B01J37/08 , B01J37/16 , H01M4/9083 , H01M4/926
摘要： A process for the production of a carbon supported catalyst, which comprises the following steps: (a) precipitation of at least one metal oxide onto a surface of a carbon-comprising support by preparing an initial mixture, comprising the carbon-comprising support, at least one metal oxide precursor and an organic solvent, and spray-drying of the initial mixture to obtain an intermediate product, (b) loading of noble-metal-comprising particles onto the surface of the intermediate product in a liquid medium by deposition, precipitation and/or reduction of a noble-metal-comprising precursor with a reducing agent, (c) heat treatment of the catalyst precursor resulting from step (b) at a temperature higher than 400° C.
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公开(公告)号：US09825308B1
公开(公告)日：2017-11-21
申请号：US15203083
申请日：2016-07-06
发明人： Di-Jia Liu , Lina Chong
CPC分类号： H01M4/921 , B01J23/89 , B01J37/086 , H01M4/8657 , H01M4/926 , H01M2008/1095
摘要： A low platinum catalyst and method for making same. The catalyst comprises platinum-transition metal bimetallic alloy microcrystallites over a transition metal-nitrogen-carbon composite. A method of making a catalyst comprises preparation of transition metal organic frameworks, infusion of platinum, thermal treatment, and reduction to form the microcrystallites and composite.
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公开(公告)号：US20170291164A1
公开(公告)日：2017-10-12
申请号：US15509785
申请日：2015-09-10
发明人： Yiling Zhang
IPC分类号： B01J23/63 , B01D53/88 , B01J23/10 , B01J35/00 , B01J37/08 , B01J37/34 , B01J37/02 , B01J37/00 , B01J37/06 , B01D53/86 , B01J37/04
CPC分类号： B01J23/63 , B01D53/8668 , B01D53/885 , B01D2253/1124 , B01D2255/1021 , B01D2255/2065 , B01D2255/2073 , B01D2255/802 , B01D2257/704 , B01D2257/708 , B01D2258/06 , B01D2259/4508 , B01D2259/802 , B01J23/02 , B01J23/06 , B01J23/08 , B01J23/10 , B01J23/14 , B01J23/22 , B01J23/30 , B01J23/34 , B01J23/58 , B01J23/60 , B01J23/62 , B01J23/626 , B01J23/6482 , B01J23/6527 , B01J23/6562 , B01J23/72 , B01J23/745 , B01J23/75 , B01J23/83 , B01J23/89 , B01J27/04 , B01J27/045 , B01J35/004 , B01J37/009 , B01J37/0203 , B01J37/0209 , B01J37/0215 , B01J37/0236 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/343 , B01J37/344
摘要： A system for decomposing contaminants, including volatile compounds (VOCs), with a visible-spectrum photocatalytic composition.
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公开(公告)号：US20160251230A1
公开(公告)日：2016-09-01
申请号：US15031197
申请日：2014-10-27
申请人： Zhejiang University
发明人： Jie Fan , Wuzhong Yi , Renhong Li , Shihui Zou , Liping Xiao , Linfang Lu
CPC分类号： C01C3/11 , B01J21/08 , B01J23/52 , B01J23/89 , B01J35/0013 , C01C3/08 , C01P2002/72 , C01P2002/82 , C01P2004/04
摘要： This disclosure provides a facial green method for metal cyanides preparation, including the following steps: 1) supported metal nanoparticles and Fenton's reagent are mixed with nitrile and then stirred to obtain suspension, wherein metal nanoparticles are selected from a nano metal, nano metal oxide and nano metal salt; 2) centrifuging the suspension to obtain a product and drying the product after stirring to obtain the metal cyanides. As prepared metal cyanides have broad application prospects in the fields of sensor, battery, medicine, electroplating and catalysis. This Fenton-improved cyanation (FIC) method may effectively exclude the toxicity from free cyanide anions and get rid of UV-light, being more energy-saving and more feasible for large-scale industrial production of MCs.
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公开(公告)号：US09415385B2
公开(公告)日：2016-08-16
申请号：US13677564
申请日：2012-11-15
发明人： Terry E. Helton , Benjamin S. Umansky , William J. Tracy, III , Stephen J. McCarthy , Timothy L. Hilbert , Mohan Kalyanaraman , Christopher G. Oliveri
IPC分类号： B01J37/20 , B01J23/89 , C10G65/04 , C10G45/10 , C10G45/12 , B01J38/10 , B01J38/58 , B01J38/74 , B01J29/03 , B01J29/85 , B01J29/90 , B01J29/12 , B01J29/14 , B01J29/44 , B01J29/46 , B01J29/67 , B01J29/68 , B01J29/74 , B01J29/76
CPC分类号： B01J37/20 , B01J23/89 , B01J23/8993 , B01J29/0325 , B01J29/0333 , B01J29/126 , B01J29/143 , B01J29/44 , B01J29/46 , B01J29/67 , B01J29/68 , B01J29/7415 , B01J29/7461 , B01J29/7492 , B01J29/7615 , B01J29/7661 , B01J29/7692 , B01J29/85 , B01J29/90 , B01J38/10 , B01J38/58 , B01J38/74 , B01J2229/42 , C10G45/10 , C10G45/12 , C10G65/043 , C10G2300/4031 , C10G2300/703
摘要： Methods are provided for liquid phase activation of dewaxing and/or hydrofinishing catalysts that include a molecular sieve or other acidic crystalline support. The methods are compatible with activating the catalysts as part of a catalyst system that also includes a hydrotreating catalyst.
摘要翻译： 提供了用于液相活化脱蜡和/或加氢精制催化剂的方法，其包括分子筛或其它酸性结晶载体。 该方法与催化剂的活化相容，催化剂体系的一部分还包括加氢处理催化剂。
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公开(公告)号：US09353044B2
公开(公告)日：2016-05-31
申请号：US14369427
申请日：2012-11-14
发明人： Stephen W. King , Sadeka Onam , Thomas Z. Srnak
IPC分类号： C07D295/00 , C07C213/02 , C07D295/023 , B01J21/12 , B01J23/889 , B01J23/89 , B01J37/02
CPC分类号： C07C213/02 , B01J21/12 , B01J23/8896 , B01J23/89 , B01J37/0201 , C07C2529/89 , C07D295/00 , C07D295/023 , C07C215/14
摘要： The invention provides a method for the reductive amination of diethanolamine to form a product composition that includes piperazine (PIP) and aminoethylethanolamine (AEEA). A catalyst with a transitional alumina/second metal oxide support and a mixture of catalytic metals is used for the reaction which results in low levels of non-PIP and non-AEEA side products.
摘要翻译： 本发明提供二乙醇胺还原胺化以形成包括哌嗪（PIP）和氨基乙基乙醇胺（AEEA））的产品组合物的方法。 使用具有过渡氧化铝/第二金属氧化物载体和催化金属的混合物的催化剂用于反应，其导致低水平的非PIP和非AEEA副产物。
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公开(公告)号：US08785340B2
公开(公告)日：2014-07-22
申请号：US13278130
申请日：2011-10-20
申请人： Takuma Kimura , Mohammad Abdullah Al-Saleh , Halim Hamid Redhwi , Mohammad Ashraf Ali , Shakeel Ahmed , Masayuki Inui
发明人： Tomoyuki Inui , Takuma Kimura , Mohammad Abdullah Al-Saleh , Halim Hamid Redhwi , Mohammad Ashraf Ali , Shakeel Ahmed
CPC分类号： B01J37/0201 , B01J21/16 , B01J23/652 , B01J23/89 , B01J23/8913 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J37/0205 , B01J37/18 , C10G29/205 , C10G45/10 , C10G47/14
摘要： The catalyst exhibiting hydrogen spillover effect relates to the composition of a catalyst exhibiting hydrogen spillover effect and to a process for preparing the catalyst. The catalyst has a reduced transition base metal of Group VIB or Group VIIIB, such as cobalt, nickel, molybdenum or tungsten, supported on a high porous carrier, such as saponite, the base metal being ion-exchanged with at least one precious metal of Group VIIIB. The process includes the steps of loading the base metal onto the support, reducing the base metal, preferably with H2 at 600° C., and thereafter ion-exchanging the precious metal with the base metal. Preferred examples of the catalyst include a saponite support loaded with about 10-20 wt % cobalt and about 0.1-1 wt % precious metal. The catalyst is optimized for reactions that occur in commercial processes at about 360-400° C., such as in hydrocracking.
摘要翻译： 表现出氢气溢出效应的催化剂涉及显示氢气溢出效应的催化剂的组成和制备催化剂的方法。 该催化剂具有负载在诸如皂石的高多孔载体上的VIB族或VIIIB族的钌基过渡金属，例如钴，镍，钼或钨，贱金属与至少一种贵金属离子交换 第VIIIB组。 该方法包括以下步骤：将贱金属加载到载体上，优选在600℃下用H 2还原贱金属，然后将贵金属与贱金属进行离子交换。 催化剂的优选实例包括负载有约10-20重量％钴和约0.1-1重量％贵金属的皂石载体。 该催化剂针对在约360-400℃的商业过程中发生的反应进行优化，例如在加氢裂化中。
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