摘要:
The disclosure aims to provide a polytetrafluoroethylene powder for an electrode binder which is a sustainable product and can reduce or prevent gas generation inside a battery cell and deterioration of battery characteristics, an electrode binder, an electrode mixture, an electrode, and a secondary battery. Provided is a polytetrafluoroethylene powder for use as an electrode binder, the polytetrafluoroethylene powder being substantially free from water and a fluorine-containing compound having a molecular weight of 1000 or less.
摘要:
The present disclosure provides a method for producing a fluoropolymer, the method includes polymerizing a fluoromonomer in an aqueous medium in the presence of a polymer (1) to obtain a fluoropolymer, wherein the polymer (1) is a polymer of a monomer (1) represented by the general formula (1) below, in which the content of a dimer and a trimer of the monomer (1) is 1.0% by mass or less based on the polymer (1): CF2═CF—R—CZ1Z1-A0 (1) wherein R is a linking group; Z1 and Z2 are each independently F or CF3; and A0 is an anionic group.
摘要:
A composition having a breaking strength of 10.0 N or more, containing a polytetrafluoroethylene, and substantially free from a compound represented by the following general formula (3): (H—(CF2)8—SO3)qM2 General Formula (3): wherein M2 is H, a metal atom, NR54, where each R5 may be the same or different and is H or an organic group having 1 to 10 carbon atoms, imidazolium optionally having a substituent, pyridinium optionally having a substituent, or phosphonium optionally having a substituent; and q is 1 or 2.
摘要:
The invention provides a production method for producing low molecular weight polytetrafluoroethylene enabling easy removal of most of C8-C14 perfluorocarboxylic acids and salts thereof, which are unfortunately generated by irradiation, from the low molecular weight polytetrafluoroethylene. The method for producing low molecular weight polytetrafluoroethylene includes: (1) irradiating polytetrafluoroethylene to provide low molecular weight polytetrafluoroethylene having a melt viscosity of 1×102 to 7×105 Pa·s at 380° C.; (2) pulverizing the low molecular weight polytetrafluoroethylene; and (3) heating the low molecular weight polytetrafluoroethylene pulverized in the step (2).
摘要:
The invention provides a method for producing low molecular weight polytetrafluoroethylene less likely to generate C8-C14 perfluorocarboxylic acids and salts thereof. The method for producing low molecular weight polytetrafluoroethylene includes: (1) feeding into an airtight container: polytetrafluoroethylene; at least one additive selected from the group consisting of hydrocarbons, chlorinated hydrocarbons, alcohols, and carboxylic acids other than C8-C14 perfluorocarboxylic acids; and at least one selected from the group consisting of inert gases other than the above additive and oxygen adsorbents; and (2) irradiating the polytetrafluoroethylene to provide low molecular weight polytetrafluoroethylene having a complex viscosity of 1×102 to 7×105 Pa·s at 380° C.
摘要:
The present invention aims to provide a modified polytetrafluoroethylene fine powder capable of providing a stretched body having high strength, a small pore size, and excellent homogeneity. The modified polytetrafluoroethylene fine powder of the present invention has non-melt-processability, has a standard specific gravity of 2.155 or lower, includes 0.015 mol % or more of a polymer unit derived from perfluoro(methyl vinyl ether) in all the monomer units, is obtained by emulsion polymerizing tetrafluoroethylene and at least the perfluoro(methyl vinyl ether) in the presence of a fluorosurfactant having a LogPOW value of 3.4 or lower, and has an extrusion pressure of 20.0 MPa or lower.
摘要:
Provided is a dripping inhibitor excellent in handling characteristics. The present invention provides a dripping inhibitor including a modified polytetrafluoroethylene, the inhibitor having an average particle size of 300 to 800 μm, an apparent density of 0.40 to 0.52 g/ml, a compression ratio of 1.20 or less, an aggregate disintegration degree with 50-sec vibration of 70% or more, a cylinder extrusion pressure at a reduction ratio 1500 of 80 MPa or less, and a standard specific gravity (SSG) of 2.140 to 2.230.
摘要:
A fluororesin composition, and a molded article obtained from the fluororesin composition. The fluororesin composition containing: a non-melt-flowable fluororesin A having a history of being heated to a melting point thereof or higher; and a non-melt-flowable fluororesin B having no history of being heated to a melting point thereof or higher. The fluororesin composition contains a tetrafluoroethylene unit and a modifying monomer unit based on a modifying monomer copolymerizable with tetrafluoroethylene. Further, the fluororesin composition is a powder for compression molding excluding ram extrusion molding.
摘要:
A method for producing a fluoropolymer aqueous dispersion, the method including concentrating a composition comprising a polymer (I) containing a polymerization unit (I) derived from a monomer (I) represented by the general formula (I), a fluoropolymer excluding the polymer (I), a nonionic surfactant, a fluorine-free anionic surfactant, and an aqueous medium to thereby obtain an aqueous dispersion containing the fluoropolymer,
CX1X3═CX2R(—CZ1Z2-A0)m (I)
wherein X1 and X3 are each independently F, Cl, H, or CF3; X2 is H, F, an alkyl group, or a fluorine-containing alkyl group; A0 is an anionic group; R is a linking group; Z1 and Z2 are each independently H, F, an alkyl group, or a fluorine-containing alkyl group; and m is an integer of 1 or more.
摘要:
A modified polytetrafluoroethylene aqueous dispersion having low viscosity at high temperature. The modified polytetrafluoroethylene aqueous dispersion contains a modified polytetrafluoroethylene and a nonionic surfactant, has a modified polytetrafluoroethylene solid concentration of 50 to 70% by mass, is substantially free from a fluorine-containing surfactant, and has a viscosity at 55° C. of 80 mPa•s or lower, and the modified polytetrafluoroethylene contains 0.050% by mass or more and 1.00% by mass or less of a polymerized unit based on a modifying monomer.