POLYTETRAFLUOROETHYLENE PRODUCTION METHOD

    公开(公告)号:US20220289877A1

    公开(公告)日:2022-09-15

    申请号:US17747655

    申请日:2022-05-18

    IPC分类号: C08F14/26

    摘要: Provided is a method for producing polytetrafluoroethylene, which includes polymerizing tetrafluoroethylene in an aqueous medium in the presence of a nucleating agent and a polymer (I) containing a polymerization unit (I) based on a monomer represented by the general formula (I) to obtain polytetrafluoroethylene: CX1X3═CX2R(—CZ1Z2-A0)m  (I) wherein X1 and X3 are each independently F, Cl, H, or CF3; X2 is H, F, an alkyl group, or a fluorine-containing alkyl group; A0 is an anionic group; R is a linking group; Z1 and Z2 are each independently H, F, an alkyl group, or a fluorine-containing alkyl group; and m is an integer of 1 or more.

    METHOD FOR PRODUCING FLUOROPOLYMER

    公开(公告)号:US20220282007A1

    公开(公告)日:2022-09-08

    申请号:US17747547

    申请日:2022-05-18

    IPC分类号: C08F14/26

    摘要: A method for producing a fluoropolymer, which includes: polymerizing a monomer (I) represented by the general formula (I) below in an aqueous medium substantially in the absence of a fluorine-containing surfactant (except for the monomer (I) represented by the general formula (I)) to obtain a crude composition containing a polymer of the monomer (I); removing a dimer and a trimer of the monomer (I) contained in the crude composition from the crude composition to obtain a polymer (I) in which the content of the dimer and trimer of the monomer (I) is 1.0% by mass or less based on the polymer (I); and polymerizing a fluoromonomer in an aqueous medium in the presence of the polymer (I) to obtain a fluoropolymer: CX1X3═CX2R(—CZ1Z2-A0)m  (I) wherein X1 and X3, X2, A0, R, Z1 and Z2 are as defined herein.

    PRODUCTION METHOD OF FLUOROPOLYMER AQUEOUS DISPERSION

    公开(公告)号:US20230416421A1

    公开(公告)日:2023-12-28

    申请号:US18464931

    申请日:2023-09-11

    IPC分类号: C08F14/26 C08F6/20

    CPC分类号: C08F14/26 C08F6/20

    摘要: A method for producing a fluoropolymer aqueous dispersion, the method including concentrating a composition comprising a polymer (I) containing a polymerization unit (I) derived from a monomer (I) represented by the general formula (I), a fluoropolymer excluding the polymer (I), a nonionic surfactant, a fluorine-free anionic surfactant, and an aqueous medium to thereby obtain an aqueous dispersion containing the fluoropolymer,


    CX1X3═CX2R(—CZ1Z2-A0)m  (I)

    wherein X1 and X3 are each independently F, Cl, H, or CF3; X2 is H, F, an alkyl group, or a fluorine-containing alkyl group; A0 is an anionic group; R is a linking group; Z1 and Z2 are each independently H, F, an alkyl group, or a fluorine-containing alkyl group; and m is an integer of 1 or more.