Abstract:
The disclosure aims to provide a fluororesin composition having excellent tensile properties and excellent handleability while containing a fluororesin having a history of being heated to a temperature equal to or higher than the melting point thereof and a molded article obtainable from the fluororesin composition. The disclosure relates to a non-melt-flowable fluororesin composition containing: a non-melt-flowable fluororesin A having a history of being heated to a temperature equal to or higher than a melting point thereof; a fluororesin B including at least one selected from the group consisting of a melt-flowable fluororesin and a non-melt-flowable fluororesin having no history of being heated to a temperature equal to or higher than a melting point thereof; and a filler.
Abstract:
The present disclosure provides a method for producing a fluoropolymer, the method includes polymerizing a fluoromonomer in an aqueous medium in the presence of a polymer (1) to obtain a fluoropolymer, wherein the polymer (1) is a polymer of a monomer (1) represented by the general formula (1) below, in which the content of a dimer and a trimer of the monomer (1) is 1.0% by mass or less based on the polymer (1): CF2═CF—R—CZ1Z1-A0 (1) wherein R is a linking group; Z1 and Z2 are each independently F or CF3; and A0 is an anionic group.
Abstract:
A composition having a breaking strength of 10.0 N or more, containing a polytetrafluoroethylene, and substantially free from a compound represented by the following general formula (3): (H—(CF2)8—SO3)qM2 General Formula (3): wherein M2 is H, a metal atom, NR54, where each R5 may be the same or different and is H or an organic group having 1 to 10 carbon atoms, imidazolium optionally having a substituent, pyridinium optionally having a substituent, or phosphonium optionally having a substituent; and q is 1 or 2.
Abstract:
A method for producing a polytetrafluoroethylene composition including mixing a polytetrafluoroethylene resin and a filler using an airflow mixer to provide a polytetrafluoroethylene composition containing the polytetrafluoroethylene resin and the filler. The airflow mixer is a pulse-type airflow mixer or an airflow stirrer. Also disclosed is a polytetrafluoroethylene composition produced by the production method, a polytetrafluoroethylene composition having specific physical properties, as well as a molded article, electrically conductive tube, thermally conductive film, and substrate for CCL each obtained from the polytetrafluoroethylene composition.
Abstract:
The disclosure provides a method for removing a C4-C20 hydrophilic compound. The method for removing a hydrophilic compound includes step (a) of exposing a composition containing a C4-C20 hydrophilic compound to 0.1 to 500 kGy of radiation to remove the hydrophilic compound.
Abstract:
A manufacturing method for a polytetrafluoroethylene formed product according to an aspect of the invention is a manufacturing method for a polytetrafluoroethylene formed product, the method including a step of irradiating a forming material containing a polytetrafluoroethylene as a principal component with ionizing radiation, wherein the polytetrafluoroethylene has a melt viscosity at 380° C. of not greater than 7×105 Pa·s.
Abstract:
The invention provides a production method for producing low molecular weight polytetrafluoroethylene enabling easy removal of most of C8-C14 perfluorocarboxylic acids and salts thereof, which are unfortunately generated by irradiation, from the low molecular weight polytetrafluoroethylene. The method for producing low molecular weight polytetrafluoroethylene includes: (1) irradiating polytetrafluoroethylene to provide low molecular weight polytetrafluoroethylene having a melt viscosity of 1×102 to 7×105 Pa·s at 380° C.; (2) pulverizing the low molecular weight polytetrafluoroethylene; and (3) heating the low molecular weight polytetrafluoroethylene pulverized in the step (2).
Abstract:
The invention provides a method for producing low molecular weight polytetrafluoroethylene less likely to generate C8-C14 perfluorocarboxylic acids and salts thereof. The method for producing low molecular weight polytetrafluoroethylene includes: (1) feeding into an airtight container: polytetrafluoroethylene; at least one additive selected from the group consisting of hydrocarbons, chlorinated hydrocarbons, alcohols, and carboxylic acids other than C8-C14 perfluorocarboxylic acids; and at least one selected from the group consisting of inert gases other than the above additive and oxygen adsorbents; and (2) irradiating the polytetrafluoroethylene to provide low molecular weight polytetrafluoroethylene having a complex viscosity of 1×102 to 7×105 Pa·s at 380° C.
Abstract:
The invention provides a composition capable of providing an electric wire with small fluctuations in the wire diameter. The composition includes a modified polytetrafluoroethylene (A) having a cylinder extrusion pressure of 80 MPa or lower at a reduction ratio of 1600 and a non-fibrillatable low-molecular-weight polytetrafluoroethylene (B).
Abstract:
The present invention aims to provide a modified polytetrafluoroethylene fine powder capable of providing a stretched body having high strength, a small pore size, and excellent homogeneity. The modified polytetrafluoroethylene fine powder of the present invention has non-melt-processability, has a standard specific gravity of 2.155 or lower, includes 0.015 mol % or more of a polymer unit derived from perfluoro(methyl vinyl ether) in all the monomer units, is obtained by emulsion polymerizing tetrafluoroethylene and at least the perfluoro(methyl vinyl ether) in the presence of a fluorosurfactant having a LogPOW value of 3.4 or lower, and has an extrusion pressure of 20.0 MPa or lower.