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1.
公开(公告)号:US20190169035A1
公开(公告)日:2019-06-06
申请号:US16321118
申请日:2016-08-02
发明人: Pengfei WU , Miao YANG , Peng TIAN , Zhongmin LIU , Linying WANG , Lin LIU
摘要: A method for synthesizing a nano SAPO-34 molecular sieve, and an SAPO-34 molecular sieve catalyst and application thereof. A nano SAPO-34 molecular sieve is synthesized by adding a microporous templating agent and a templating agent having a functionalized organic silane to hydrothermal synthesis. The nano SAPO-34 molecular sieve is calcined to obtain a nano SAPO-34 molecular sieve catalyst. The catalyst can be used in a reaction for preparing low-carbon olefin from an oxygen-containing compound. The nano SAPO-34 molecular sieve obtained by this method has a pure CHA crystal phase. Moreover, the nano SAPO-34 molecular sieve catalyst obtained by this method has good catalytic performance in a MTO reaction, the service life of the catalyst is significantly prolonged, and the selectivity of the low-carbon olefin is improved.
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公开(公告)号:US20180021763A1
公开(公告)日:2018-01-25
申请号:US15547264
申请日:2015-01-30
发明人: Xiao XIANG , Peng TIAN , Zhongmin LIU , Yue YANG , Lin LIU , Miao YANG , Hongyi YANG , Shiyun SANG , Yanli HE
IPC分类号: B01J29/85 , B01J37/00 , B01D53/86 , B01J37/06 , B01J37/08 , C07C1/20 , C01B39/54 , B01J37/30
CPC分类号: B01J29/85 , B01D53/8628 , B01D2255/50 , B01D2258/06 , B01J37/0018 , B01J37/06 , B01J37/08 , B01J37/30 , B01J2229/183 , C01B37/08 , C01B39/026 , C01B39/54 , C07C1/20 , C07C2529/85
摘要: A preparation method for a metal-modified SAPO molecular sieve is disclosed, characterized in adding a raw powder of the SAPO molecular sieve to a solution containing metal ions for performing ion exchange, and then washing and drying the obtained solid after ion exchange, so as to obtain the metal-modified SAPO molecular sieve. The metal-modified SAPO molecular sieve prepared has a relatively high degree of crystallinity, and the metal elements occupy the ionic positions in the channels and/or cages of the SAPO molecular sieve, and the metal-modified SAPO molecular sieve shows excellent catalytic performance in the catalytic reaction.
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