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公开(公告)号:US10512594B2
公开(公告)日:2019-12-24
申请号:US15766397
申请日:2016-10-10
Applicant: DENTSPLY SIRONA Inc.
Inventor: Joachim E. Klee , Florian Szillat , Maximilian Maier , Helmut Ritter , Jacques Lalevee , Jean Pierre Fouassier , Fabrice Morlet-Savary , Celine Dietlin , Mariem Bouzrati-Zerelli , Christoph P Fik
Abstract: The present invention relates to a dental composition comprising an initiator system comprising a sensitizer compound having an acylsilyl- or acylgermyl-group and a specific coinitiator compound. The present invention also relates to an initiator system consisting essentially of the sensitizer compound having an acylsilyl- or acylgermyl-group and a coinitiator compound wherein a C—H bond dissociation energy is less than 95 Kcal/mol. Furthermore, the present invention relates to the use of this initiator system for the preparation of a dental composition.
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公开(公告)号:US10980713B2
公开(公告)日:2021-04-20
申请号:US16296307
申请日:2019-03-08
Applicant: DENTSPLY SIRONA Inc.
Inventor: Maximilian Maier , Huaibing Liu , Sven Pohle , Florian Szillat
Abstract: Disclosed is a resin modified dental luting cement composition having a polymerizable resin component, a polyacidic polymer component, a filler component, a redox initiator system, and water.
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公开(公告)号:US10588830B2
公开(公告)日:2020-03-17
申请号:US15766382
申请日:2016-10-07
Applicant: DENTSPLY SIRONA Inc.
Inventor: Joachim E. Klee , Florian Szillat , Maximilian Maier , Helmut Ritter , Jacques Lalevee , Jean Pierre Fouassier , Fabrice Morlet-Savary , Celine Dietlin , Mariem Bouzrati-Zerelli , Christoph P Fik
Abstract: The present invention relates to a dental composition comprising a specific polymerization initiator system comprising a compound having an acylsilyl- or acylgermanyl-group. The present invention also relates the use of the compound having an acylsilyl- or acylgermanyl group for the preparation of a dental composition.
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公开(公告)号:US10899861B2
公开(公告)日:2021-01-26
申请号:US15754303
申请日:2016-09-09
Applicant: DENTSPLY SIRONA inc.
Inventor: Joachim Klee , Caroline Renn , Florian Szillat , Oliver Elsner , Christian Scheufler , Ulrich Lampe , Helmut Ritter
IPC: A61F2/00 , C08F220/56 , C08F8/30 , C08F290/12 , C08F220/06 , C07C233/20
Abstract: The present invention relates to a polymerizable polyacidic polymer and to a process for preparing the polymerizable polyacidic polymer. Furthermore, the present invention relates to an aqueous dental composition comprising the polymerizable polyacidic polymer, to a use of the polymerizable polyacidic polymer for the preparation of a dental composition and to an acrylic acid derivative copolymer.
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公开(公告)号:US20250082550A1
公开(公告)日:2025-03-13
申请号:US18936697
申请日:2024-11-04
Applicant: Dentsply Sirona Inc.
Inventor: Joachim E. Klee , Oliver Elsner , Florian Szillat , Caroline Renn
Abstract: A dental composition comprising (a) a polymerizable monomer; and (b) an initiator system comprising (b-1) a sensitizer or an oxidizing agent of a redox initiator system; and (b-2) a coinitiator of the following formula (I): Q-X (I) wherein Q and X are as defined in claim 1.
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公开(公告)号:US11883510B2
公开(公告)日:2024-01-30
申请号:US17959768
申请日:2022-10-04
Applicant: DENTSPLY SIRONA INC.
Inventor: Maximilian Maier , Joachim E. Klee , Christian Scheufler , Caroline Renn , Florian Szillat
Abstract: The present invention relates to a dental composition comprising a photoinitiator system comprising a particulate carrier supporting a coinitiator covalently bonded to the surface of the carrier. Furthermore, the present invention relates to a use of the particulate carrier in a dental composition.
The particulate carrier displays multiple covalently bonded tertiary amino groups and/or tertiary phosphine groups on the surface, for crosslinking monomers, oligomers and/or polymers having one or more polymerizable double bonds.-
公开(公告)号:US10849831B2
公开(公告)日:2020-12-01
申请号:US16237983
申请日:2019-01-02
Applicant: DENTSPLY SIRONA Inc.
Inventor: Caroline Renn , Florian Szillat , Joachim E. Klee , Christian Scheufler , Oliver Elsner , Thomas Tigges , Mattias Worm , Helmut Ritter , Xiaoming Jin
Abstract: A dental composition comprising a polymerizable acidic compound of the following formula (I): wherein R1 which may be the same or different when more than one R1 is present, represents a hydrogen atom or a methyl group; R2 which may be the same or different when more than one R2 is present, represents a hydrogen atom, a straight-chain or branched C1-6 alkyl group, a C3-8 cycloalkyl group or a straight-chain or branched C2-6 alkenyl group; R3 which may be the same or different when more than one R3 is present, represents a monovalent organic moiety substituted by a group selected from —COOM, —PO3M, —O—PO3M2 and —SO3M, wherein M independently represents a hydrogen atom or a metal atom; or R2 and R3 form together a divalent organic moiety substituted by a group selected from —COOM, —PO3M, —O—PO3M2 and —SO3M, wherein M independently represents a hydrogen atom or a metal atom; L represents a (m+n+1)-valent organic linker group; X represents a hydrogen atom or a group selected from —COOM, —PO3M, —O—PO3M2 or —SO3M, wherein M independently is a hydrogen atom or a metal atom; m is an integer of 0 to 6; n is an integer of 0 to 6; wherein (m+n) is at least 2; provided that when n is 0, then X cannot be a hydrogen atom.
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公开(公告)号:US10272017B2
公开(公告)日:2019-04-30
申请号:US15486342
申请日:2017-04-13
Applicant: DENTSPLY SIRONA Inc.
Inventor: Caroline Renn , Oliver Elsner , Florian Szillat , Joachim Klee , Christoph Weber , Uwe Walz , Christian Scheufler , Andrew Lichkus , Xiaoming Jin
Abstract: An aqueous dental glass ionomer composition comprising (A) a reactive particulate glass, (B) a water-soluble polymer comprising acidic groups, which is reactive with the particulate glass in a cement reaction, (C) a water-soluble, hydrolysis-stable monomer having a single polymerizable double bond and optionally a carboxylic acid group or hydroxyl group; (D) a water-soluble, hydrolysis-stable polymerizable crosslinker having at least two polymerizable carbon-carbon double bonds; and (E) a polymerization initiator system.
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公开(公告)号:US20170296441A1
公开(公告)日:2017-10-19
申请号:US15486335
申请日:2017-04-13
Applicant: DENTSPLY SIRONA Inc.
Inventor: Caroline RENN , Oliver Elsner , Maximilian Maier , Florian Szillat , Joachim Klee , Christoph Weber , Uwe Walz , Christian Scheufler , Helmut Ritter , Andrew Lichkus , Xiaoming Jin
IPC: A61K6/083
CPC classification number: A61K6/0835 , C08L33/00 , C08L33/10 , C08L33/08
Abstract: The present disclosure relates to an aqueous dental glass ionomer composition comprising a reactive particulate glass, a water-soluble, polymerizable polymer which is reactive with the particulate glass in a cement reaction, a hydrolysis-stable, water-soluble monomer having a single polymerizable double bond and optionally a carboxylic acid group or hydroxyl group; and a polymerization initiator system, wherein the polymerizable polymer is obtainable by a process comprising a step of polymerizing a mixture comprising a first polymerizable monomer comprising at least one optionally protected carboxylic acid group and a first polymerizable organic moiety, and optionally a second copolymerizable monomer comprising one or more optionally protected primary and/or secondary hydroxyl and/or amino group(s) and a second polymerizable organic moiety, for obtaining an water-soluble polymer; a step of coupling to the water-soluble polymer a compound having a olymerizable moiety and a functional group reactive with an optionally protected carboxylic acid group of repeating units derived from the first polymerizable monomer or an optionally protected hydroxyl and/or amino group of repeating units derived from the second copolymerizable monomer in the water-soluble polymer obtained in step a), wherein the optionally protected carboxylic acid group and the optionally protected hydroxyl and/or amine group are deprotected, so that polymerizable pendant groups are linked to the backbone by ester groups, urethane groups and/or amide groups, and, optionally, a step of deprotecting the protected carboxylic acid group for obtaining a polymerizable polymer.
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公开(公告)号:US11918664B2
公开(公告)日:2024-03-05
申请号:US17343886
申请日:2021-06-10
Applicant: DENTSPLY SIRONA inc.
Inventor: Florian Szillat , Caroline Renn , Christoph Weber , Uwe Walz , Joachim Klee
Abstract: The present invention relates to an aqueous dental glass ionomer composition for use in the treatment of cavitated carious lesions, which composition comprises a water-soluble, polymerizable polymer comprising acidic groups, which is reactive with the particulate glass in a cement reaction, whereby the polymerizable polymer has a polymer backbone and pendant groups having one or more polymerizable carbon-carbon double bonds. The dental glass ionomer composition is used as a permanent direct restoration.
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