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    OLEFIN POLYMERIZATION CATALYST SYSTEMS AND METHODS OF USE THEREOF
    2.
    发明申请
    OLEFIN POLYMERIZATION CATALYST SYSTEMS AND METHODS OF USE THEREOF 审中-公开

    公开(公告)号：US20200277411A1

    公开(公告)日：2020-09-03

    申请号：US16089008

    申请日：2017-03-30

    Applicant: Dow Global Technologies LLC

    Inventor： Brad C. Bailey ,  Matthew D. Christianson ,  Anna V. Davis ,  Jasson T. Patton ,  Tomas D. Paine

    IPC: C08F4/64 ,  C08F2/38 ,  C08F210/16

    Abstract: Olefin polymerization catalyst systems are provided that include a procatalyst component having a metal-ligand complex of Formula (I): [formula] (I) where each X is a neutral, monoanionic, or dianionic, monodentate or polydentate ligand such that the complex of Formula (I) is neutral; each R1 and R10 is a (C6-C40)aryl, substituted (C6-C40)aryl, (C3-C40)heteroaryl, or substituted (C3-C40)heteroaryl; each R2, R3, R4, R7, R8, and R9 is a hydrogen; (C1-C40)hydrocarbyl; substituted (C1-C40)hydrocarbyl; (C1-C40)heterohydrocarbyl; substituted (C1-C40)heterohydrocarbyl; halogen; or nitro (NO2) group; and each R5 and R6 is a (C1-C)alkyl; substituted (C1-C40)alkyl; or [(Si)1—(C+Si)40] substituted organosilyl. Additionally, olefin-based polymers and processes for polymerizing one or more olefin-based polymers in the presence of the olefin polymerization catalyst systems are also provided.

    ZINC CATALYST/ADDITIVE SYSTEM FOR THE POLYMERIZATION OF EPOXIDE MONOMERS
    4.
    发明申请
    ZINC CATALYST/ADDITIVE SYSTEM FOR THE POLYMERIZATION OF EPOXIDE MONOMERS 有权
    ZINC催化剂/用于环氧化物单体聚合的添加剂体系

    公开(公告)号：US20160289381A1

    公开(公告)日：2016-10-06

    申请号：US15035422

    申请日：2014-11-18

    Applicant: DOW GLOBAL TECHNOLOGIES LLC

    Inventor： Anna V. Davis ,  Peter N. Nickias

    IPC: C08G65/12

    CPC classification number: C08G65/12 ,  B01J2531/11 ,  C08G65/10 ,  C08G65/266 ,  C08G65/269

    Abstract: The present invention concerns a catalyst formulation comprising: (a) a Zn catalyst comprising a Zn compound having alcoholate ligand(s) derived from one or more polyols, and (b) a catalyst additive comprising a metal compound (i) having alcoholate ligand(s) derived from one or monohydric alcohol wherein the metal is selected from: (I) first row transition metals excluding Zn, preferably Sc, Ti, V, Cr, Mn, Ni, and Co, more preferably Ti, (II) second row transition metals, preferably Y and Zr, more preferably Zr, and (III) combinations of at least two metals selected from (I) and (II). The present invention also relates to a process for polymerizing an epoxide monomer, preferably ethylene oxide, comprising carrying out the process in the presence of the catalyst formulation.

    Abstract translation: 本发明涉及一种催化剂制剂，其包含：（a）包含衍生自一种或多种多元醇的具有醇化物配体的Zn化合物的Zn催化剂，和（b）包含具有醇化物配体的金属化合物（i） s），其中金属选自：（I）不包括Zn的第一排过渡金属，优选Sc，Ti，V，Cr，Mn，Ni和Co，更优选Ti，（II）第二排 过渡金属，优选Y和Zr，更优选Zr，和（III）选自（I）和（II）中的至少两种金属的组合。 本发明还涉及聚合环氧化物单体，优选环氧乙烷的方法，包括在催化剂制剂存在下进行该方法。

    ZINC CATALYST/ADDITIVE SYSTEM FOR THE POLYMERIZATION OF EPOXIDE MONOMERS
    5.
    发明申请
    ZINC CATALYST/ADDITIVE SYSTEM FOR THE POLYMERIZATION OF EPOXIDE MONOMERS 有权
    ZINC催化剂/用于环氧化物单体聚合的添加剂体系

    公开(公告)号：US20160289380A1

    公开(公告)日：2016-10-06

    申请号：US15035407

    申请日：2014-11-18

    Applicant: DOW GLOBAL TECHNOLOGIES LLC

    Inventor： Anna V. Davis ,  Peter N. Nickias

    IPC: C08G65/12 ,  C08G65/26

    CPC classification number: C08G65/12 ,  B01J31/0212 ,  B01J2231/14 ,  C08G65/10 ,  C08G65/2648 ,  C08G65/2651 ,  C08G65/266 ,  C08G65/269

    Abstract: The present invention concerns a catalyst formulation comprising: (a) a Zn catalyst comprising a Zn compound having alcoholate ligand(s) derived from one or more polyols, and (b) a catalyst additive comprising a metal compound (i) having alcoholate ligand(s) derived from one or monohydric alcohol wherein the metal is selected from: (I) group 2 metals, preferably Mg, Ca, Sr, and Ba, more preferably Mg, (II) Li, and (III) combinations of at least two metals selected from (I) and (II). The present invention also relates to a process for polymerizing an epoxide monomer, preferably ethylene oxide, comprising carrying out the process in the presence of the catalyst formulation.

    Abstract translation: 本发明涉及一种催化剂制剂，其包含：（a）包含衍生自一种或多种多元醇的具有醇化物配体的Zn化合物的Zn催化剂，和（b）包含具有醇化物配体的金属化合物（i） s）衍生自一种或一元醇的金属，其中金属选自：（I）第2族金属，优选Mg，Ca，Sr和Ba，更优选Mg，（II）Li和（III）至少两种 选自（I）和（II）的金属。 本发明还涉及聚合环氧化物单体，优选环氧乙烷的方法，包括在催化剂制剂存在下进行该方法。

    Zinc catalyst/additive system for the polymerization of epoxide monomers
    9.
    发明授权
    Zinc catalyst/additive system for the polymerization of epoxide monomers 有权

    公开(公告)号：US09879115B2

    公开(公告)日：2018-01-30

    申请号：US15035422

    申请日：2014-11-18

    Applicant: Dow Global Technologies LLC

    Inventor： Anna V. Davis ,  Peter N. Nickias

    IPC: C08G65/12 ,  C08G65/10 ,  C08G65/26

    CPC classification number: C08G65/12 ,  B01J2531/11 ,  C08G65/10 ,  C08G65/266 ,  C08G65/269

    Abstract: The present invention concerns a catalyst formulation comprising: (a) a Zn catalyst comprising a Zn compound having alcoholate ligand(s) derived from one or more polyols, and (b) a catalyst additive comprising a metal compound (i) having alcoholate ligand(s) derived from one or monohydric alcohol wherein the metal is selected from: (I) first row transition metals excluding Zn, preferably Sc, Ti, V, Cr, Mn, Ni, and Co, more preferably Ti, (II) second row transition metals, preferably Y and Zr, more preferably Zr, and (III) combinations of at least two metals selected from (I) and (II). The present invention also relates to a process for polymerizing an epoxide monomer, preferably ethylene oxide, comprising carrying out the process in the presence of the catalyst formulation.

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