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公开(公告)号：US20170173565A1
公开(公告)日：2017-06-22
申请号：US15300139
申请日：2015-05-14
发明人： Vera P. Santos Castro , Adam Chojecki , Garmt R. Meima , Adrianus Koeken , Matthijs Ruitenbeek , Thomas Davidian , Gascon Jorge , Michiel Makkee , Freek Kapteijn , Tim A. Wezendonk
CPC分类号： B01J23/78 , B01J27/22 , B01J31/1691 , B01J31/223 , B01J35/002 , B01J35/006 , B01J35/023 , B01J37/0201 , B01J37/0203 , B01J37/086 , B01J37/18 , B01J2231/648 , B01J2531/0216 , B01J2531/842 , C10G2/332 , C10G2300/70
摘要： Preparation of a catalyst suitable for use in Fischer-Tropsch Synthesis reactions using a two step process in which the steps may be performed in either order. In step a), impregnate an iron carboxylate metal organic framework selected from a group consisting of iron-1,3,5-benzenetricarboxylate (Fe-(BTC), Basolite™ F-300 and/or MIL-100 (Fe)), iron-1,4 benzenedicarboxylate (MIL-101(Fe)), iron fumarate (MIL-88 A (Fe)), iron-1,4 benzenedicarboxylate (MIL-53 (Fe)), iron-1,4 benzenedicarboxylate (MIL-68 (Fe)) or iron azobenzenetetracarboxylate (MIL-127 (Fe)) with a solution of a promoter element selected from alkali metals and alkaline earth metals. In step b) thermally decompose the iron carboxylate metal organic framework under an inert gaseous atmosphere to yield a catalyst that is a porous carbon matrix having embedded therein a plurality of discrete aliquots of iron carbide. If desired, add a step intermediate between steps a) and b) or preceding step b) wherein the metal organic framework is impregnated with an oxygenated solvent solution of a polymerizable additional carbon source and the polymerizable additional carbon source is thereafter polymerized.
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公开(公告)号：US09833774B2
公开(公告)日：2017-12-05
申请号：US15300139
申请日：2015-05-14
发明人： Vera P. Santos Castro , Adam Chojecki , Garmt R. Meima , Adrianus Koeken , Matthijs Ruitenbeek , Thomas Davidian , Gascon Jorge , Michiel Makkee , Freek Kapteijn , Tim A. Wezendonk
CPC分类号： B01J23/78 , B01J27/22 , B01J31/1691 , B01J31/223 , B01J35/002 , B01J35/006 , B01J35/023 , B01J37/0201 , B01J37/0203 , B01J37/086 , B01J37/18 , B01J2231/648 , B01J2531/0216 , B01J2531/842 , C10G2/332 , C10G2300/70
摘要： Preparation of a catalyst suitable for use in Fischer-Tropsch Synthesis reactions using a two step process in which the steps may be performed in either order. In step a), impregnate an iron carboxylate metal organic framework selected from a group consisting of iron-1,3,5-benzenetricarboxylate (Fe-(BTC), Basolite™ F-300 and/or MIL-100 (Fe)), iron-1,4 benzenedicarboxylate (MIL-101(Fe)), iron fumarate (MIL-88 A (Fe)), iron-1,4 benzenedicarboxylate (MIL-53 (Fe)), iron-1,4 benzenedicarboxylate (MIL-68 (Fe)) or iron azobenzenetetracarboxylate (MIL-127 (Fe)) with a solution of a promoter element selected from alkali metals and alkaline earth metals. In step b) thermally decompose the iron carboxylate metal organic framework under an inert gaseous atmosphere to yield a catalyst that is a porous carbon matrix having embedded therein a plurality of discrete aliquots of iron carbide. If desired, add a step intermediate between steps a) and b) or preceding step b) wherein the metal organic framework is impregnated with an oxygenated solvent solution of a polymerizable additional carbon source and the polymerizable additional carbon source is thereafter polymerized.
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