公开(公告)号：US20160016886A1

公开(公告)日：2016-01-21

申请号：US14378848

申请日：2013-02-14

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Paul R. Elowe ,  Arkady L. Krasovskiy ,  Irina V. Graf ,  Lin Wang

IPC: C07C213/08 ,  C07C217/08 ,  C07C209/28

CPC classification number: C07C217/08 ,  C07C209/28 ,  C07C213/08 ,  C07C2601/14

Abstract: The present invention provides nonionic surfactants, compositions incorporating these surfactants, and related methods of making and using such surfactants and compositions. The nonionic surfactants demonstrate excellent equilibrium and dynamic surface tension properties as well as excellent wetting properties. Further, representative embodiments of the surfactants have shown low foaming characteristics, indicating that the surfactants would be suitable in applications where resistance to foaming is desired. The surfactants can be used singly or in combination with other nonionic and/or ionic surfactants as desired. As an over view, the nonionic surfactants of the present invention have a structure in which the surfactant backbone includes one or more amine moieties. At least one, preferably two or more branched, cyclic, fused cyclic, and/or spyro hydrophobic moieties are pendant from at least one of the amine moieties. Additionally, at least one, preferably two or more hydrophilic moieties, preferably alkylene oxide (i.e., polyether) chains also are pendant from at least one of the amine moieties.

Abstract translation: 本发明提供非离子表面活性剂，掺入这些表面活性剂的组合物，以及制备和使用这些表面活性剂和组合物的相关方法。 非离子表面活性剂表现出优异的平衡和动态表面张力性能以及优异的润湿性能。 此外，表面活性剂的代表性实施方案已经显示出低发泡特性，表明表面活性剂将适用于需要耐发泡性的应用。 表面活性剂可以根据需要单独使用或与其它非离子和/或离子表面活性剂组合使用。 从过去的观点来看，本发明的非离子表面活性剂具有其中表面活性剂主链包括一个或多个胺部分的结构。 至少一个，优选两个或更多个支链，环状稠合的环状和/或间苯二酚疏水部分从至少一个胺部分侧挂。 此外，至少一个，优选两个或更多个亲水部分，优选环氧烷（即聚醚）链也是至少一个胺部分的侧挂。

公开(公告)号：US08993658B2

公开(公告)日：2015-03-31

申请号：US13865272

申请日：2013-04-18

Applicant: Dow Global Technologies LLC

Inventor： Irina V. Graf ,  Arkady L. Krasovskiy

IPC: C08K3/02 ,  C08K5/06 ,  C09D7/12 ,  B05D3/02 ,  C08G65/00 ,  C08L71/00

CPC classification number: C09D7/1233 ,  B05D3/0254 ,  C08G65/00 ,  C08L71/00 ,  C08L2201/54 ,  C09D5/024 ,  C09D7/63 ,  C09D133/06 ,  C09D201/00

Abstract: A surfactant composition selected from the group consisting of: ArO—(CH2CH[CH2CH3]O)1-10(CH2CH2O)5-50H, isomers, aromatic ring substituted analogs, and mixtures thereof; and an aqueous coating composition including an aqueous polymeric dispersion, and certain other compositions, including the surfactant composition are provided. Also provided are a method for forming a coating and a method for improving the freeze/thaw stability of an aqueous composition including an aqueous polymeric dispersion.

Abstract translation: 选自以下的表面活性剂组合物：ArO-（CH 2 CH [CH 2 CH 3）O）1-10（CH 2 CH 2 O）5-50H，异构体，芳环取代的类似物及其混合物; 并且提供包含水性聚合物分散体和包括表面活性剂组合物的某些其它组合物的水性涂料组合物。 还提供了一种形成涂层的方法以及用于提高包含水性聚合物分散体的水性组合物的冻融稳定性的方法。

公开(公告)号：US20140080745A1

公开(公告)日：2014-03-20

申请号：US14027277

申请日：2013-09-16

Applicant: Dow Global Technologies LLC

Inventor： Irina V. Graf ,  Arkady L. Krasovskiy

IPC: C07C43/11 ,  C09D7/12

CPC classification number: C07C43/11 ,  B01F17/0021 ,  B01F17/0028 ,  B01F17/0092 ,  C07C41/03 ,  C09D5/027 ,  C11D1/721 ,  C07C43/135

Abstract: A surfactant composition selected from the group consisting of; (R1O)CH2CH(OCH2CH2)1-20OHCH2(OR2) and mixtures thereof; wherein at least one of R1 and R2 are secondary alkyl groups including from 3 to 9 Carbon atoms; an aqueous coating composition including an aqueous polymeric dispersion; and certain other compositions including the surfactant composition are provided. Also provided is a method for forming a coating.

Abstract translation: 选自以下的表面活性剂组合物： （R 1 O）CH 2 CH（OCH 2 CH 2）1-20 OHCH 2（OR 2）及其混合物; 其中R 1和R 2中的至少一个是包括3至9个碳原子的仲烷基; 包含含水聚合物分散体的水性涂料组合物; 并提供包括表面活性剂组合物的某些其它组合物。 还提供了一种形成涂层的方法。

公开(公告)号：US09388106B2

公开(公告)日：2016-07-12

申请号：US14027277

申请日：2013-09-16

Applicant: Dow Global Technologies LLC

Inventor： Irina V. Graf ,  Arkady L. Krasovskiy

IPC: B01F17/28 ,  C07C43/11 ,  C09D7/12 ,  B01F17/00 ,  C07C41/03 ,  C09D5/02 ,  C11D1/72

CPC classification number: C07C43/11 ,  B01F17/0021 ,  B01F17/0028 ,  B01F17/0092 ,  C07C41/03 ,  C09D5/027 ,  C11D1/721 ,  C07C43/135

Abstract: A surfactant composition selected from the group consisting of: (R1O)CH2—CH[(OCH2CH2)1-20OH]—CH2(OR2) and mixtures thereof; wherein at least one of R1 and R2 are secondary alkyl groups including from 3 to 9 Carbon atoms; an aqueous coating composition including an aqueous polymeric dispersion; and certain other compositions including the surfactant composition are provided. Also provided is a method for forming a coating.

Abstract translation: 选自：（R 1 O）CH 2 -CH [（OCH 2 CH 2）1-20 OH] -CH 2（OR 2）及其混合物的表面活性剂组合物; 其中R 1和R 2中的至少一个是包括3至9个碳原子的仲烷基; 包含含水聚合物分散体的水性涂料组合物; 并提供包括表面活性剂组合物的某些其它组合物。 还提供了一种形成涂层的方法。

公开(公告)号：US20130280433A1

公开(公告)日：2013-10-24

申请号：US13863675

申请日：2013-04-16

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Irina V. Graf ,  Arkady L. Krasovskiy ,  Cynthia L. Rand

IPC: C09D7/12

CPC classification number: C09D7/1233 ,  C08G65/2612 ,  C09D7/63 ,  C09D171/02

Abstract: An aqueous coating composition including an aqueous polymeric dispersion and from 0.1% to 40% by weight, based on the weight of the aqueous polymeric dispersion solids, Phenylphenol-(CH2CH2O)2-50H, isomers thereof, aromatic ring substituted analogues thereof, and mixtures thereof is provided. Also provided are a method for forming a coating therefrom, a method for improving the freeze-thaw stability of an aqueous coating including a polymeric dispersion and alternative uses for Phenylphenol-(CH2CH2O)2-50H, isomers thereof, aromatic ring substituted analogues thereof, and mixtures thereof.

Abstract translation: 一种水性涂料组合物，其包含水性聚合物分散体和0.1重量％至40重量％，基于水性聚合物分散体固体的重量，苯酚 - （CH 2 CH 2 O）2-50H，其异构体，其芳环取代的类似物，以及混合物 提供。 还提供了用于形成涂层的方法，提高包含聚合物分散体的水性涂料的冻融稳定性的方法和用于苯酚 - （CH 2 CH 2 O）2-50H的其它用途，其异构体，其芳香环取代的类似物， 及其混合物。

公开(公告)号：US20170158610A1

公开(公告)日：2017-06-08

申请号：US15176402

申请日：2016-10-17

Applicant: Dow Global Technologies LLC

Inventor： Paul R. Elowe ,  Arkady L. Krasovskiy ,  Irina V. Graf ,  Lin Wang

IPC: C07C217/08

CPC classification number: C07C217/08 ,  C07C209/28 ,  C07C213/08 ,  C07C2601/14

Abstract: The present invention provides nonionic surfactants, compositions incorporating these surfactants, and related methods of making and using such surfactants and compositions. The nonionic surfactants demonstrate excellent equilibrium and dynamic surface tension properties as well as excellent wetting properties. Further, representative embodiments of the surfactants have, shown low foaming characteristics, indicating that the surfactants would be suitable in applications where resistance to foaming is desired. The surfactants can be used singly or in combination with other nonionic and/or ionic surfactants as desired. As an overview, the nonionic surfactants of the present invention have a structure in which the surfactant backbone includes one or more amine moieties. At least one, preferably two or more branched, cyclic, fused cyclic, and/or spyro hydrophobic moieties are pendant from at least one of the amine moieties. Additionally, at least one, preferably two or more hydrophilic moieties, preferably alkylene oxide (i.e., polyether) chains also are pendant from at least one of the amine moieties.

公开(公告)号：US09382192B2

公开(公告)日：2016-07-05

申请号：US14378848

申请日：2013-02-14

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Paul R. Elowe ,  Arkady L. Krasovskiy ,  Irina V. Graf ,  Lin Wang

IPC: C07C217/08 ,  C07C213/08 ,  C07C209/28

CPC classification number: C07C217/08 ,  C07C209/28 ,  C07C213/08 ,  C07C2601/14

Abstract: The present invention provides nonionic surfactants, compositions incorporating these surfactants, and related methods of making and using such surfactants and compositions. The nonionic surfactants demonstrate excellent equilibrium and dynamic surface tension properties as well as excellent wetting properties. Further, representative embodiments of the surfactants have shown low foaming characteristics, indicating that the surfactants would be suitable in applications where resistance to foaming is desired. The surfactants can be used singly or in combination with other nonionic and/or ionic surfactants as desired. As an over view, the nonionic surfactants of the present invention have a structure in which the surfactant backbone includes one or more amine moieties. At least one, preferably two or more branched, cyclic, fused cyclic, and/or spyro hydrophobic moieties are pendant from at least one of the amine moieties. Additionally, at least one, preferably two or more hydrophilic moieties, preferably alkylene oxide (i.e., polyether) chains also are pendant from at least one of the amine moieties.

Abstract translation: 本发明提供非离子表面活性剂，掺入这些表面活性剂的组合物，以及制备和使用这些表面活性剂和组合物的相关方法。 非离子表面活性剂表现出优异的平衡和动态表面张力性能以及优异的润湿性能。 此外，表面活性剂的代表性实施方案已经显示出低发泡特性，表明表面活性剂将适用于需要耐发泡性的应用。 表面活性剂可以根据需要单独使用或与其它非离子和/或离子表面活性剂组合使用。 从过去的观点来看，本发明的非离子表面活性剂具有其中表面活性剂主链包括一个或多个胺部分的结构。 至少一个，优选两个或更多个支链，环状稠合环状和/或间苯二酚疏水部分从至少一个胺部分侧挂。 此外，至少一个，优选两个或更多个亲水部分，优选环氧烷（即聚醚）链也是至少一个胺部分的侧挂。

公开(公告)号：US08901213B2

公开(公告)日：2014-12-02

申请号：US13863675

申请日：2013-04-16

Applicant: Dow Global Technologies LLC

Inventor： Irina V. Graf ,  Arkady L. Krasovskiy ,  Cynthia L. Rand

IPC: C08K3/02 ,  C08K5/13 ,  C09D7/12 ,  C09D171/02

CPC classification number: C09D7/1233 ,  C08G65/2612 ,  C09D7/63 ,  C09D171/02

Abstract: An aqueous coating composition including an aqueous polymeric dispersion and from 0.1% to 40% by weight, based on the weight of the aqueous polymeric dispersion solids, Phenylphenol-(CH2CH2O)2-50H, isomers thereof, aromatic ring substituted analogs thereof, and mixtures thereof is provided. Also provided are a method for forming a coating therefrom, a method for improving the freeze-thaw stability of an aqueous coating including a polymeric dispersion and alternative uses for Phenylphenol-(CH2CH2O)2-50H, isomers thereof, aromatic ring substituted analogs thereof, and mixtures thereof.

Abstract translation: 基于水性聚合物分散体固体，苯酚 - （CH 2 CH 2 O）2-50H，其异构体，其芳环取代的类似物和其混合物的混合物的水性聚合物分散体和0.1重量％至40重量％的水性涂料组合物， 提供。 还提供了形成涂层的方法，提高包含聚合物分散体的水性涂料的冻融稳定性的方法，以及苯酚 - （CH 2 CH 2 O）2-50H的其它用途，其异构体，芳香环取代的类似物， 及其混合物。

公开(公告)号：US20130280434A1

公开(公告)日：2013-10-24

申请号：US13865272

申请日：2013-04-18

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Irina V. Graf ,  Arkady L. Krasovskiy

IPC: C09D7/12 ,  B05D3/02

CPC classification number: C09D7/1233 ,  B05D3/0254 ,  C08G65/00 ,  C08L71/00 ,  C08L2201/54 ,  C09D5/024 ,  C09D7/63 ,  C09D133/06 ,  C09D201/00

Abstract: A surfactant composition selected from the group consisting of: ArO—(CH2CH[CH2CH3]O)1-10(CH2CH2O)5-50H, isomers, aromatic ring substituted analogues, and mixtures thereof; and an aqueous coating composition including an aqueous polymeric dispersion, and certain other compositions, including the surfactant composition are provided. Also provided are a method for forming a coating and a method for improving the freeze/thaw stability of an aqueous composition including an aqueous polymeric dispersion.

Abstract translation: 选自以下的表面活性剂组合物：ArO-（CH 2 CH [CH 2 CH 3）O）1-10（CH 2 CH 2 O）5-50H，异构体，芳环取代的类似物及其混合物; 并且提供包含水性聚合物分散体和包括表面活性剂组合物的某些其它组合物的水性涂料组合物。 还提供了一种形成涂层的方法以及用于提高包含水性聚合物分散体的水性组合物的冻融稳定性的方法。