公开(公告)号：US09315625B2

公开(公告)日：2016-04-19

申请号：US14400925

申请日：2013-05-24

Applicant: DSM IP ASSETS B.V.

Inventor： Rudy Rulkens ,  Atze Jan Nijenhuis

IPC: C08G69/26 ,  C08G69/32 ,  C08G69/34 ,  C08G69/36 ,  C08L77/06 ,  C08L77/08 ,  C08G18/60

CPC classification number: C08G69/26 ,  C08G18/603 ,  C08G69/265 ,  C08G69/32 ,  C08G69/34 ,  C08G69/36 ,  C08L77/06 ,  C08L77/08 ,  Y10T428/31725

Abstract: The invention relates to a polyamide comprising units derived from: A. a diamine comprising in its structure at least one cyclohexane fragment according to Structure I, in which the substituents are in the 1,4-trans-position (Structure I), with n a positive integer of at least 1, and the proviso that when n is 2 or higher the cyclohexane rings are connected to each other through the 1,4-trans position, B. an aliphatic dicarboxylic acid with at least 13 carbon atoms and optionally comprising units derived from: C. one or more aliphatic dicarboxylic acids other than B, D. one or more diamines other than A, E. one or more monofunctional carboxylic acids or monofunctional amines, F. one or more polyfunctional monomers comprising carboxylic acid and/or amine groups, G. one or more lactams or corresponding amino acids. The invention further relates to a composition comprising such a polyamide and its uses.

Abstract translation: 本发明涉及包含衍生自以下的单元的聚酰胺：A.一种二胺，其结构包含至少一种根据结构I的环己烷片段，其中取代基在1,4-反式位置（结构I），其中na 正整数为至少1，条件是当n为2或更高时，环己烷环通过1,4-反式位置相互连接，B.具有至少13个碳原子的脂族二羧酸，并且任选地包含单元 一种或多种除B之外的脂族二羧酸，D.一种或多种除A以外的二胺，E.一种或多种单官能羧酸或单官能胺，F.一种或多种包含羧酸和/或其官能团的多官能单体 胺基，G.一种或多种内酰胺或相应的氨基酸。 本发明还涉及包含这种聚酰胺的组合物及其用途。

公开(公告)号：US20150141613A1

公开(公告)日：2015-05-21

申请号：US14400925

申请日：2013-05-24

Applicant: DSM IP ASSETS B.V.

Inventor： Rudy Rulkens ,  Atze Jan Nijenhuis

IPC: C08G69/26

CPC classification number: C08G69/26 ,  C08G18/603 ,  C08G69/265 ,  C08G69/32 ,  C08G69/34 ,  C08G69/36 ,  C08L77/06 ,  C08L77/08 ,  Y10T428/31725

Abstract: The invention relates to a polyamide comprising units derived from: A. a diamine comprising in its structure at least one cyclohexane fragment according to Structure I, in which the substituents are in the 1,4-trans-position (Structure I), with n a positive integer of at least 1, and the proviso that when n is 2 or higher the cyclohexane rings are connected to each other through the 1,4-trans position, B. an aliphatic dicarboxylic acid with at least 13 carbon atoms and optionally comprising units derived from: C. one or more aliphatic dicarboxylic acids other than B, D. one or more diamines other than A, E. one or more monofunctional carboxylic acids or monofunctional amines, F. one or more polyfunctional monomers comprising carboxylic acid and/or amine groups, G. one or more lactams or corresponding amino acids. The invention further relates to a composition comprising such a polyamide and its uses.

Abstract translation: 本发明涉及包含衍生自以下的单元的聚酰胺：A.一种二胺，其结构包含至少一种根据结构I的环己烷片段，其中取代基在1,4-反式位置（结构I），其中na 正整数为至少1，条件是当n为2或更高时，环己烷环通过1,4-反式位置相互连接，B.具有至少13个碳原子的脂族二羧酸，并且任选地包含单元 一种或多种除B之外的脂族二羧酸，D.一种或多种除A以外的二胺，E.一种或多种单官能羧酸或单官能胺，F.一种或多种包含羧酸和/或其官能团的多官能单体 胺基，G.一种或多种内酰胺或相应的氨基酸。 本发明还涉及包含这种聚酰胺的组合物及其用途。

公开(公告)号：US10040904B2

公开(公告)日：2018-08-07

申请号：US14911336

申请日：2014-07-10

Applicant: DSM IP ASSETS B.V.

Inventor： Wilhelmus Petrus Johannes Appel ,  Carel Frederik Constantijn Fitié ,  Atze Jan Nijenhuis ,  Beert Jacobus Keestra ,  Josien Krijgsman ,  Michel Henri Chrétien Joseph Van Houtem ,  Henricus Marie Janssen

IPC: C08G69/44 ,  C08G69/28 ,  C07C231/02 ,  C08G69/40

Abstract: Process for the production of a thermoplastic polymer comprising segments of a diamide, the process comprising: 1) a first step of preparing a reaction mixture comprising a diamine H2N—Y—NH2 Form. (I), and a diester of a dicarboxylic acid Form. (II) 2) a second step of heating the reaction mixture to a temperature at least 5° C. above the crystallization temperature of the diester and a least 5° C. below the melting temperature of the formed amide (formula III) in the presence of an alkaline or earth alkaline alkoxy catalyst Form. (III) wherein X and Y are the same or different and are an aliphatic group comprising 2-12 carbon atoms or an aromatic group comprising 6-20 carbon atoms, R1 and R2 are the same or different and are an aliphatic group comprising 2-15 carbon atoms and wherein R equals R1 or R2 and are the same or different. 3) optionally a third step of quenching the catalyst of the reaction mixture obtained in the second step by adding an acid to the reaction mixture and 4) a fourth step of adding further components to the reaction mixture obtained in the second step, or if the third step has been applied to the reaction mixture obtained in the third step, and so producing the thermoplastic polymer comprising the segments of the diamide.