公开(公告)号：US10040904B2

公开(公告)日：2018-08-07

申请号：US14911336

申请日：2014-07-10

Applicant: DSM IP ASSETS B.V.

Inventor： Wilhelmus Petrus Johannes Appel ,  Carel Frederik Constantijn Fitié ,  Atze Jan Nijenhuis ,  Beert Jacobus Keestra ,  Josien Krijgsman ,  Michel Henri Chrétien Joseph Van Houtem ,  Henricus Marie Janssen

IPC: C08G69/44 ,  C08G69/28 ,  C07C231/02 ,  C08G69/40

Abstract: Process for the production of a thermoplastic polymer comprising segments of a diamide, the process comprising: 1) a first step of preparing a reaction mixture comprising a diamine H2N—Y—NH2 Form. (I), and a diester of a dicarboxylic acid Form. (II) 2) a second step of heating the reaction mixture to a temperature at least 5° C. above the crystallization temperature of the diester and a least 5° C. below the melting temperature of the formed amide (formula III) in the presence of an alkaline or earth alkaline alkoxy catalyst Form. (III) wherein X and Y are the same or different and are an aliphatic group comprising 2-12 carbon atoms or an aromatic group comprising 6-20 carbon atoms, R1 and R2 are the same or different and are an aliphatic group comprising 2-15 carbon atoms and wherein R equals R1 or R2 and are the same or different. 3) optionally a third step of quenching the catalyst of the reaction mixture obtained in the second step by adding an acid to the reaction mixture and 4) a fourth step of adding further components to the reaction mixture obtained in the second step, or if the third step has been applied to the reaction mixture obtained in the third step, and so producing the thermoplastic polymer comprising the segments of the diamide.

公开(公告)号：US11448365B2

公开(公告)日：2022-09-20

申请号：US16061757

申请日：2016-12-02

Applicant: DSM IP ASSETS B.V.

Inventor： Beert Jacobus Keestra ,  Tim Leonardus Maria Vorage ,  Godefridus Bernardus Wilhelmus Leonardus Ligthart

IPC: F17C1/16 ,  F17C1/02 ,  B29C70/32 ,  B29C53/58 ,  B29C70/44 ,  B29C70/16 ,  B29C53/82 ,  B29K77/00 ,  B29K101/12 ,  B29L31/00

Abstract: This invention relates to a pressure vessel comprising a hollow body comprising endless fibers embedded in a thermoplastic polymer, in which the thermoplastic polymer comprises one or more polyamides containing one or more aliphatic monomeric units, wherein the one or more polyamides have a CH2-ratio of at least 5.5 and less than 10, calculated by □ identifying the number of different aliphatic monomeric units in the one or more polyamides; □ determining the number of CH2 groups per aliphatic monomeric unit for each of these different aliphatic monomeric units; □ calculating the sum of the so determined numbers of CH2 groups; □ dividing said sum by the number of different aliphatic monomeric units in the one or more polyamides; taking into account only the aliphatic monomeric units present in the one or more polyamides in an amount of at least 10 wt % with respect to the total weight of the one or more polyamides.

公开(公告)号：US11046023B2

公开(公告)日：2021-06-29

申请号：US16062233

申请日：2016-12-02

Applicant: DSM IP ASSETS B.V.

Inventor： Beert Jacobus Keestra ,  Tim Leonardus Maria Vorage ,  Godefridus Bernardus Wilhelmus Leonardus Ligthart

IPC: B29C70/16 ,  B29C53/56 ,  B29C53/58 ,  B29C53/82 ,  F17C1/02 ,  B29C53/60

Abstract: The invention relates to a tape, comprising at least one layer comprising a. endless fiber in an total amount of at least 40 volume % as compared to the total volume of the layer and b. a thermoplastic matrix comprising one or more polyamides containing one or more aliphatic monomeric units, c. and optionally heat stabilizer, flame retardant, colorant, lubricant, mold release agent, UV stabilizer, impact modifier, laser absorbing additive as well as combinations thereof; wherein the one or more polyamides have a CH2-ratio of at least 5.5 and less than 10, calculated by—identifying the number of different aliphatic monomeric units in the one or more polyamides; —determining the number of CH2 groups per aliphatic monomeric unit for each of these different aliphatic monomeric units; —calculating the sum of the so determined numbers of CH2 groups; —dividing said sum by the number of different aliphatic monomeric units in the one or more polyamides; taking into account only the aliphatic monomeric units present in the one or more polyamides in an amount of at least 10 wt % with respect to the total weight of the one or more polyamides. The invention also relates to a vessel prepared by employing these tapes.

公开(公告)号：US09457515B2

公开(公告)日：2016-10-04

申请号：US13959738

申请日：2013-08-06

Applicant: DSM IP ASSETS B.V.

Inventor： John Southwell ,  Brett A. Register ,  Satyendra Kumar Sarmah ,  Paulus Antonius Maria Steeman ,  Beert Jacobus Keestra ,  Marcus Matheus Driessen

IPC: C08L63/00 ,  B29C67/00 ,  C08G65/18 ,  G03F7/00 ,  G03F7/027 ,  G03F7/038

CPC classification number: B29C67/0055 ,  B29C64/106 ,  B33Y10/00 ,  B33Y70/00 ,  B33Y80/00 ,  C08G65/18 ,  C08L63/00 ,  G03F7/0037 ,  G03F7/027 ,  G03F7/038 ,  Y10T428/31511 ,  C08L2666/04

Abstract: The invention relates to a liquid radiation curable resin capable of curing into a solid upon irradiation comprising: (A) from about 0 to about 12 wt % of a cycloaliphatic epoxide having a linking ester group; (B) from about 30 to about 65 wt % of one or more epoxy functional components other than A; (C) from about 10 to about 30 wt % of one or more oxetanes; (D) from, about 1 to about 10 wt % of one or more polyols; (E) from about 2 to about 20 wt % of one or more radically curable (meth) acrylate components; (F) from about 2 to about 12 wt % of one or more impact modifiers; (G) from about 0.1 to about 8 wt % of one or more free radical photoinitiators; and (H) from about 0.1 to about 8 wt % of one or more cationic photoinitiators; wherein the liquid radiation curable resin has a viscosity at 30° C. of from about 600 cps to about 1300 cps.

Abstract translation: 本发明涉及能够在照射时固化成固体的液体辐射固化树脂，其包含：（A）约0至约12重量％的具有连接酯基的脂环族环氧化物; （B）约30至约65重量％的除A之外的一种或多种环氧官能组分; （C）约10至约30重量％的一种或多种氧杂环丁烷; （D）约1至约10重量％的一种或多种多元醇; （E）约2至约20重量％的一种或多种可自由基固化的（甲基）丙烯酸酯组分; （F）约2至约12重量％的一种或多种抗冲改性剂; （G）约0.1至约8重量％的一种或多种自由基光引发剂; 和（H）约0.1至约8重量％的一种或多种阳离子光引发剂; 其中所述液体辐射可固化树脂在30℃下的粘度为约600cps至约1300cps。

公开(公告)号：US20150072150A1

公开(公告)日：2015-03-12

申请号：US14389869

申请日：2013-03-26

Applicant: DSM IP ASSETS B.V.

Inventor： Beert Jacobus Keestra ,  Angelika Schmidt ,  Agnes Johanna Pauline Björling

IPC: C08L69/00 ,  H01B3/42

CPC classification number: C08L69/005 ,  C08L69/00 ,  C08L75/06 ,  C08L2201/02 ,  C08L2203/202 ,  H01B3/28 ,  H01B3/302 ,  H01B3/426 ,  Y10T428/31507

Abstract: Polymer composition containing a thermoplastic elastomer, comprising hard segments of a polyester and/or a polyurethane and soft segments of an aliphatic polycarbonate, which composition contains polycarbonate. An insulated wire comprising an insulation layer of the polymer composition.

Abstract translation: 包含热塑性弹性体的聚合物组合物，其包含聚酯和/或聚氨酯的硬链段和脂肪族聚碳酸酯的软链段，该组合物含有聚碳酸酯。 一种绝缘电线，包括聚合物组合物的绝缘层。

公开(公告)号：US20140035202A1

公开(公告)日：2014-02-06

申请号：US13959738

申请日：2013-08-06

Applicant: DSM IP ASSETS B.V.

Inventor： John Southwell ,  Brett A. Register ,  Satyendra Kumar Sarmah ,  Paulus Antonius Maria Steeman ,  Beert Jacobus Keestra ,  Marcus Matheus Driessen

IPC: B29C67/00

CPC classification number: B29C67/0055 ,  B29C64/106 ,  B33Y10/00 ,  B33Y70/00 ,  B33Y80/00 ,  C08G65/18 ,  C08L63/00 ,  G03F7/0037 ,  G03F7/027 ,  G03F7/038 ,  Y10T428/31511 ,  C08L2666/04

Abstract: The invention relates to a liquid radiation curable resin capable of curing into a solid upon irradiation comprising: (A) from about 0 to about 12 wt % of a cycloaliphatic epoxide having a linking ester group; (B) from about 30 to about 65 wt % of one or more epoxy functional components other than A; (C) from about 10 to about 30 wt % of one or more oxetanes; (D) from, about 1 to about 10 wt % of one or more polyols; (E) from about 2 to about 20 wt % of one or more radically curable (meth)acrylate components; (F) from about 2 to about 12 wt % of one or more impact modifiers; (G) from about 0.1 to about 8 wt % of one or more free radical photoinitiators; and (H) from about 0.1 to about 8 wt % of one or more cationic photoinitiators; wherein the liquid radiation curable resin has a viscosity at 30° C. of from about 600 cps to about 1300 cps.

Abstract translation: 本发明涉及能够在照射时固化成固体的液体辐射固化树脂，其包含：（A）约0至约12重量％的具有连接酯基的脂环族环氧化物; （B）约30至约65重量％的除A之外的一种或多种环氧官能组分; （C）约10至约30重量％的一种或多种氧杂环丁烷; （D）约1至约10重量％的一种或多种多元醇; （E）约2至约20重量％的一种或多种可自由基固化的（甲基）丙烯酸酯组分; （F）约2至约12重量％的一种或多种抗冲改性剂; （G）约0.1至约8重量％的一种或多种自由基光引发剂; 和（H）约0.1至约8重量％的一种或多种阳离子光引发剂; 其中所述液体辐射可固化树脂在30℃下的粘度为约600cps至约1300cps。