公开(公告)号：US3722181A

公开(公告)日：1973-03-27

申请号：US3722181D

申请日：1970-05-22

Applicant: DU PONT

Inventor： KIRKLAND J ,  YATES P

IPC: B01J20/286 ,  B01J20/283 ,  B01J20/32 ,  C08G65/22 ,  C08G83/00 ,  G01N30/88 ,  B01D15/08

CPC classification number: B01J20/283 ,  B01J20/286 ,  B01J20/3204 ,  B01J20/3219 ,  B01J20/3257 ,  B01J20/3261 ,  B01J20/3272 ,  B01J20/3276 ,  C08G65/22 ,  C08G83/001

Abstract: A process for making a chromatographic packing having a polymeric stationary phase in which molecules having the formula WHEREIN R3'' is a hydroxyl, or an aliphatic or aromatic hydrocarbon monovalent radical, and R4 is a monovalent aliphatic or aromatic hydrocarbon radical, ARE PARTIALLY PREPOLYMERIZED, CHEMICALLY BONDED TO A POLYVALENT METAL-CONTAINING SUBSTRATE, THE METAL HAVING A VALENCE OF 3-5, AND FURTHER POLYMERIZED. The polymeric stationary phase has a repeating unit of the formula WHEREIN A is -O- or a monovalent aliphatic or aromatic hydrocarbon radical, AND IS CHEMICALLY BONDED TO THE SURFACE OF THE SUBSTRATE BY AN WHERE SILICON IS PART OF A REPEATING UNIT.

Abstract translation: 一种用于制备具有聚合物固定相的色谱填料的方法，其中具有式WHEREIN R 3'的分子是羟基，或脂族或芳族烃一价基团，R 4是一价脂族或芳族烃基，部分预处理，化学 粘合到含金属的多金属基材上，金属具有3-5的价值，并进一步聚合。

公开(公告)号：US3795313A

公开(公告)日：1974-03-05

申请号：US3795313D

申请日：1972-10-25

Applicant: DU PONT

Inventor： KIRKLAND J ,  YATES P

IPC: B01J20/32 ,  C08G65/22 ,  C08G83/00 ,  B01D15/08

CPC classification number: C08G83/001 ,  B01J20/103 ,  B01J20/28004 ,  B01J20/28057 ,  B01J20/286 ,  B01J20/288 ,  B01J20/3204 ,  B01J20/3217 ,  B01J20/3272 ,  B01J20/3282 ,  B01J41/20 ,  B01J2220/54 ,  B01J2220/58 ,  B01J2220/84 ,  B01J2220/86 ,  C08G65/22

Abstract: A process for making a chromatographic packing having a polymeric stationary phase in which molecules having the formula

WHEREIN R3'' is a hydroxyl, or an aliphatic or aromatic hydrocarbon monovalent radical, and R4 is a monovalent aliphatic or aromatic hydrocarbon radical, are partially prepolymerized, chemically bonded to a polyvalent metal-containing substrate, the metal having a valence of 3-5, and futher polymerized. The polymeric stationary phase has a repeating unit of the formula

WHEREIN A is -O- or a monovalent aliphatic or aromatic hydrocarbon radical, and is chemically bonded to the surface of the substrate by an

LINKAGE, WHERE SILICON IS PART OF A REPEATING UNIT.

Abstract translation: 制备具有聚合物固定相的色谱填料的方法，其中具有式WHEREIN R3'的分子是羟基，或脂族或芳族烃一价基团，R 4是一价脂族或芳族烃基，化学上部分地预聚合 与多价金属的基材结合，金属的价数为3-5，进一步聚合。

公开(公告)号：US3782075A

公开(公告)日：1974-01-01

申请号：US3782075D

申请日：1972-04-07

Applicant: DU PONT

Inventor： KIRKLAND J

IPC: B01D15/08 ,  B01J2/08 ,  B01J13/14 ,  B01J20/28 ,  B01J20/281 ,  G01N30/52 ,  G01N30/88

CPC classification number: B01J20/282 ,  B01J2/08 ,  B01J13/14 ,  B01J20/06 ,  B01J20/283 ,  B01J20/284 ,  B01J2220/54 ,  G01N30/52

Abstract: This invention relates to an improved packing material for chromatographic columns, prepared from a powder of uniform-sized porous microspheres composed of a plurality of interconnected colloidal oxide particles.

Abstract translation: 本发明涉及一种用于色谱柱的改进的包装材料，其由由多个相互连接的胶体氧化物颗粒组成的均匀尺寸的多孔微球的粉末制备。