公开(公告)号：US20120108774A1

公开(公告)日：2012-05-03

申请号：US13348139

申请日：2012-01-11

申请人： Daisuke TAGUCHI ,  Shigeru AIDA

发明人： Daisuke TAGUCHI ,  Shigeru AIDA

IPC分类号： C08F214/26

CPC分类号： C08F214/265 ,  C08F214/186 ,  C08F214/26

摘要： To provide an ethylene/tetrafluoroethylene copolymer which is excellent in heat resistance and flexibility.An ethylene/tetrafluoroethylene copolymer comprising repeating units (A) based on tetrafluoroethylene and repeating units (B) based on ethylene in a ratio of repeating units (A)/repeating units (B)=66/34 to 75/25 (molar ratio) and as an optional component, repeating units (C) based on a monomer represented by CH2═CX(CF2)nY (wherein each of X and Y which are independent of each other is a hydrogen atom or a fluorine atom, and n is from 2 to 8) in an amount of from 0 to 1 mol % based on the total number of moles of the repeating units (A) based on tetrafluoroethylene and the repeating units (B) based on ethylene, and having a volume flow rate measured at 297° C. of from 4 to 1,000 mm3/sec and an elastic modulus of at most 500 MPa.

摘要翻译： 提供耐热性和柔软性优异的乙烯/四氟乙烯共聚物。 以重复单元（A）/重复单元（B）= 66/34〜75/25（摩尔比）的比例，包含基于四氟乙烯的重复单元（A）和基于乙烯的重复单元（B） 作为任选的成分，基于由CH 2 = C X（CF 2）n Y表示的单体的重复单元（C）（X和Y彼此独立地为氢原子或氟原子，n为 2〜8），相对于基于四氟乙烯的重复单元（A）的总摩尔数和基于乙烯的重复单元（B），其摩尔数为0〜1摩尔％，其体积流量为 297℃，为4〜1000mm 3 /秒，弹性模量为500MPa以下。

公开(公告)号：US20110034740A1

公开(公告)日：2011-02-10

申请号：US12908911

申请日：2010-10-21

申请人： Shigeru AIDA ,  Manabu Sato ,  Takeya Sakamoto ,  Nobuo Matsushita ,  Yuuji Hayase ,  Tomohiro Gotou ,  Kenji Fujiwara

发明人： Shigeru AIDA ,  Manabu Sato ,  Takeya Sakamoto ,  Nobuo Matsushita ,  Yuuji Hayase ,  Tomohiro Gotou ,  Kenji Fujiwara

IPC分类号： C07C17/38

CPC分类号： C07C17/389 ,  B01D15/00 ,  B01J20/0229 ,  B01J20/0281 ,  B01J20/0288 ,  B01J20/0296 ,  B01J20/103 ,  B01J20/3204 ,  B01J20/3236 ,  C07C21/185

摘要： To provide a method for purifying tetrafluoroethylene by removing, from tetrafluoroethylene containing a polymerization inhibitor, the polymerization inhibitor by adsorption.A method of bringing tetrafluoroethylene containing a polymerization inhibitor into contact with a silica gel containing a metal salt in an amount of from 250 to 100,000 mass ppm as calculated as metal atoms to remove the polymerization inhibitor by adsorption, and the metal salt is preferably a salt of a metal of Group 3 to 13 of the Periodic Table, more preferably a salt of a metal of Group 8 to 10 of the Periodic Table. For example, as the metal salt, a salt of at least one metal selected from the group consisting of iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium and platinum may be used.

摘要翻译： 为了提供一种通过从包含聚合抑制剂的四氟乙烯中除去聚合抑制剂来提纯四氟乙烯的方法。 将含有聚合抑制剂的四氟乙烯与含有金属盐的硅胶接触的方法，所述硅胶含量为金属原子计为250〜100,000质量ppm，通过吸附除去阻聚剂，金属盐优选为盐 的元素周期表第3〜13族的金属，更优选为元素周期表第8〜10族金属的盐。 例如，作为金属盐，可以使用选自铁，钴，镍，钌，铑，钯，锇，铱和铂中的至少一种金属的盐。

公开(公告)号：US20080102285A1

公开(公告)日：2008-05-01

申请号：US11955979

申请日：2007-12-13

申请人： Shigeru AIDA ,  Toshiyuki Chisaka ,  Atsushi Funaki ,  Hiroki Kamiya

发明人： Shigeru AIDA ,  Toshiyuki Chisaka ,  Atsushi Funaki ,  Hiroki Kamiya

IPC分类号： B32B27/08

CPC分类号： B32B27/28 ,  Y10T428/3154 ,  Y10T428/31551 ,  Y10T428/31786 ,  Y10T428/31855 ,  Y10T428/31935 ,  Y10T428/31938

摘要： A multilayer laminate containing a laminate (I)/(II) formed by directly bonding by means of thermal lamination or the like, a layer (I) made of a fluororesin (A) with a functional group (a) and a layer (II) made of a thermoplastic resin (B) with a functional group (b) capable of forming a chemical bond by reacting with the functional group (a) of the fluororesin, wherein the fluororesin (A) has a low melting point of from 120 to 230° C. The laminate may, for example, be a multiplayer laminate containing a layer obtained by directly laminating a layer (I) made of a fluororesin (A) containing an acid anhydride residue (for example, a tetrafluoroethylene/ethylene/hexafluoropropylene/(perfluorobutyl)ethylene)/itaconic anhydride copolymer) and a layer (II) made of an amine-modified thermoplastic resin (B) (for example, a polyurethane modified with a silane coupling agent containing an amino group). The laminate is excellent in interlayer adhesion and productivity.

摘要翻译： 包含通过热层压等直接接合形成的层叠体（I）/（II）的多层层叠体，由具有官能团（a）的氟树脂（A）和层（II）构成的层（I） ）由与氟树脂的官能团（a）反应能够形成化学键的官能团（b）的热塑性树脂（B）制成，其中氟树脂（A）的熔点低于120℃ 层压体可以是例如包含通过直接层压由含有酸酐残基（例如四氟乙烯/乙烯/六氟丙烯）的氟树脂（A）制成的层（I）而获得的层的多层叠层叠体， （全氟丁基）乙烯）/衣康酸酐共聚物）和由胺改性热塑性树脂（B）制成的层（II）（例如，用含有氨基的硅烷偶联剂改性的聚氨酯）。 该层叠体的层间粘合性和生产率优异。

公开(公告)号：US20090239123A1

公开(公告)日：2009-09-24

申请号：US12408191

申请日：2009-03-20

申请人： Seigo KOTERA ,  Hiroyuki WATABE ,  Shigeru AIDA

发明人： Seigo KOTERA ,  Hiroyuki WATABE ,  Shigeru AIDA

IPC分类号： H01M8/10 ,  H01M8/14

CPC分类号： H01M8/1018 ,  H01M8/1044 ,  H01M8/1053 ,  H01M8/106 ,  H01M8/1062 ,  H01M8/1067 ,  H01M8/1083 ,  Y02P70/56 ,  Y10T428/26 ,  Y10T428/269 ,  Y10T428/2913 ,  Y10T428/2973 ,  Y10T428/3154

摘要： To provide an electrolyte membrane having excellent dimensional stability even upon absorption of water, a high proton conductance and high power generation performance; and a process for producing the electrolyte membrane with a high productivity.An electrolyte membrane for polymer electrolyte fuel cells, which is made mainly of an ion exchange resin and reinforced with a nonwoven fabric made of fiber of a fluororesin wherein at least some of intersecting points of the fiber are fixed, and which has, as the outermost layer on one side or each side, a layer not reinforced, made of an ion exchange resin which may be the same as or different from the above ion exchange resin, wherein the fluororesin is an ethylene/tetrafluoroethylene copolymer having a melting point of at most 240° C., and the above fixing is fixing by fusion of the fiber.

摘要翻译： 提供即使在吸收水时也具有优异的尺寸稳定性的电解质膜，高质子传导性和高发电性能; 以及生产率高的电解质膜的制造方法。 一种用于聚合物电解质燃料电池的电解质膜，其主要由离子交换树脂制成，并用由氟树脂纤维制成的无纺布增强，其中至少一些纤维的相交点固定，并且具有作为最外层 在一侧或每一侧上的层，未加强的层，由可与上述离子交换树脂相同或不同的离子交换树脂制成，其中氟树脂是熔点最高的乙烯/四氟乙烯共聚物 240℃，并且上述固定通过纤维的融合来固定。

公开(公告)号：US20070232754A1

公开(公告)日：2007-10-04

申请号：US11689737

申请日：2007-03-22

申请人： Shigeru AIDA ,  Takashi Sato ,  Yoshiaki Higuchi ,  Hiroki Kamiya

发明人： Shigeru AIDA ,  Takashi Sato ,  Yoshiaki Higuchi ,  Hiroki Kamiya

IPC分类号： C08L27/12

CPC分类号： C08F214/265 ,  C08L23/0846 ,  C08L23/0892 ,  C08L27/18 ,  C08L2205/02 ,  C08L2666/04 ,  C08L2666/06

摘要： To provide an ethylene/tetrafluoroethylene copolymer composition having a high melt flowability while the mechanical properties of the obtainable molded product are maintained. The ethylene/tetrafluoroethylene copolymer composition (C) has a melt viscosity of from 80 to 500 Pa·s, preferably from 100 to 300 Pa·s and a tensile elongation of from 200 to 500%, preferably from 350 to 450%. The copolymer composition (C) is obtainable by melt kneading an ethylene/tetrafluoroethylene copolymer (A) having a low melt viscosity of from 60 to 400 Pa·s, preferably from 80 to 300 Pa·s and an ethylene/tetrafluoroethylene copolymer (B) having a melt viscosity higher than this i.e. from 600 to 10,000 Pa·s, preferably from 1,000 to 7,000 Pa·s in a mass ratio of (A)/(B)=50/50 to 99/1, preferably (A)/(B)=60/40 to 97/3.

摘要翻译： 提供具有高熔体流动性的乙烯/四氟乙烯共聚物组合物，同时保持获得的模制产品的机械性能。 乙烯/四氟乙烯共聚物组合物（C）的熔融粘度为80-500Pa·s，优选为100-300Pa·s，拉伸伸长率为200-500％，优选为350-450％。 共聚物组合物（C）可以通过熔融捏合具有60至400Pa·s，优选80至300Pa·s的低熔体粘度和乙烯/四氟乙烯共聚物（B）的乙烯/四氟乙烯共聚物（A） （A）/（B）= 50/50〜99/1，优选（A）/（B）的质量比为600〜10000Pa·s，优选为1,000〜 （B）= 60/40〜97/3。