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    Multilayer laminate of fluororesin
    1.
    发明授权
    Multilayer laminate of fluororesin 有权
    氟树脂多层层压板

    公开(公告)号：US07462396B2

    公开(公告)日：2008-12-09

    申请号：US11955979

    申请日：2007-12-13

    申请人： Shigeru Aida ,  Toshiyuki Chisaka ,  Atsushi Funaki ,  Hiroki Kamiya

    发明人： Shigeru Aida ,  Toshiyuki Chisaka ,  Atsushi Funaki ,  Hiroki Kamiya

    IPC分类号： B32B27/08 ,  B32B27/28 ,  B32B27/32 ,  B32B27/36 ,  B32B27/40

    CPC分类号： B32B27/28 ,  Y10T428/3154 ,  Y10T428/31551 ,  Y10T428/31786 ,  Y10T428/31855 ,  Y10T428/31935 ,  Y10T428/31938

    摘要： A multilayer laminate containing a laminate (I)/(II) that is formed by directly bonding a layer (I) made of a fluororesin (A) having a functional group (a), said fluororesin (A) being an ethylene/tetrafluoroethylene/hexafluoropropylene/CH2═CH—Rf, wherein Rf copolymer is a C2-6 perfluoroalkyl group, and in the copolymer, the molar ratio of repeating units based on ethylene/repeating units based on tetrafluoroethylene/repeating units based on hexafluoropropylene/repeating units based on CH2═ CH—Rf ranges from 40/47/10/3 to 46.9/46.9/6/0.2 and a layer (II) made of a thermoplastic resin (B) having a functional group (b) that is capable of forming a chemical bond by reacting with the functional group (a) of the fluororesin, wherein the fluororesin (A) has a melting point ranging from 120 to 230° C.

    摘要翻译： 包含通过直接粘合由具有官能团（a）的氟树脂（A）制成的层（I）形成的层压体（I）/（II）的多层层压体，所述氟树脂（A）是乙烯/四氟乙烯/ 六氟丙烯/ CH2-CH-Rf，其中Rf共聚物是C2-6全氟烷基，在共聚物中，基于乙烯的重复单元/基于四氟乙烯/基于六氟丙烯的重复单元/基于重复单元的重复单元的摩尔比基于 CH 2 -CH-Rf为40/47/10/3至46.9 / 46.9 / 6 / 0.2，由具有能形成化学物质的官能团（b）的热塑性树脂（B）制成的层（II） 通过与氟树脂的官能团（a）反应，其中氟树脂（A）的熔点为120-230℃。

    MULTILAYER LAMINATE OF FLUORORESIN
    3.
    发明申请
    MULTILAYER LAMINATE OF FLUORORESIN 有权
    多层层状荧光素

    公开(公告)号：US20080102285A1

    公开(公告)日：2008-05-01

    申请号：US11955979

    申请日：2007-12-13

    申请人： Shigeru AIDA ,  Toshiyuki Chisaka ,  Atsushi Funaki ,  Hiroki Kamiya

    发明人： Shigeru AIDA ,  Toshiyuki Chisaka ,  Atsushi Funaki ,  Hiroki Kamiya

    IPC分类号： B32B27/08

    CPC分类号： B32B27/28 ,  Y10T428/3154 ,  Y10T428/31551 ,  Y10T428/31786 ,  Y10T428/31855 ,  Y10T428/31935 ,  Y10T428/31938

    摘要： A multilayer laminate containing a laminate (I)/(II) formed by directly bonding by means of thermal lamination or the like, a layer (I) made of a fluororesin (A) with a functional group (a) and a layer (II) made of a thermoplastic resin (B) with a functional group (b) capable of forming a chemical bond by reacting with the functional group (a) of the fluororesin, wherein the fluororesin (A) has a low melting point of from 120 to 230° C. The laminate may, for example, be a multiplayer laminate containing a layer obtained by directly laminating a layer (I) made of a fluororesin (A) containing an acid anhydride residue (for example, a tetrafluoroethylene/ethylene/hexafluoropropylene/(perfluorobutyl)ethylene)/itaconic anhydride copolymer) and a layer (II) made of an amine-modified thermoplastic resin (B) (for example, a polyurethane modified with a silane coupling agent containing an amino group). The laminate is excellent in interlayer adhesion and productivity.

    摘要翻译： 包含通过热层压等直接接合形成的层叠体（I）/（II）的多层层叠体，由具有官能团（a）的氟树脂（A）和层（II）构成的层（I） ）由与氟树脂的官能团（a）反应能够形成化学键的官能团（b）的热塑性树脂（B）制成，其中氟树脂（A）的熔点低于120℃ 层压体可以是例如包含通过直接层压由含有酸酐残基（例如四氟乙烯/乙烯/六氟丙烯）的氟树脂（A）制成的层（I）而获得的层的多层叠层叠体， （全氟丁基）乙烯）/衣康酸酐共聚物）和由胺改性热塑性树脂（B）制成的层（II）（例如，用含有氨基的硅烷偶联剂改性的聚氨酯）。 该层叠体的层间粘合性和生产率优异。

    Fluorocopolymer and its applications
    4.
    发明授权
    Fluorocopolymer and its applications 有权
    含氟共聚物及其应用

    公开(公告)号：US07112640B2

    公开(公告)日：2006-09-26

    申请号：US11224969

    申请日：2005-09-14

    申请人： Atsushi Funaki ,  Hiroki Kamiya ,  Shigeru Aida ,  Toshiyuki Chisaka

    发明人： Atsushi Funaki ,  Hiroki Kamiya ,  Shigeru Aida ,  Toshiyuki Chisaka

    IPC分类号： C08F214/28 ,  C08F214/18 ,  C08F222/06 ,  C08J7/04 ,  G03C1/492

    CPC分类号： B32B27/322 ,  B32B27/08 ,  B32B2250/24 ,  B32B2255/10 ,  B32B2255/26 ,  B32B2274/00 ,  B32B2307/306 ,  B32B2307/54 ,  B32B2307/712 ,  B32B2307/714 ,  B32B2307/7265 ,  B32B2605/00 ,  C08F214/24 ,  C08F214/26 ,  Y10T428/31507 ,  Y10T428/3154 ,  Y10T428/31721 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31855 ,  Y10T428/31935 ,  Y10T428/31938

    摘要： A fluorocopolymer which comprises repeating units (a) based on tetrafluoroethylene and/or chlorotrifluoroethylene, repeating units (b) based on a cyclic hydrocarbon monomer having a dicarboxylic anhydride group and an endocyclic polymerizable unsaturated group, and repeating units (c) based on other monomer, wherein the repeating units (a) are from 50 to 99.89 mol %, the repeating units (b) are from 0.01 to 5 mol % and the repeating units (c) are from 0.1 to 49.99 mol %, based on the total molar amount of the repeating units (a), (b) and (c), and which has a volume flow rate of from 0.1 to 1,000 mm3/sec., and a laminate and coated product thereof. The fluorocopolymer is excellent in adhesion, heat resistance, weather resistance, stress cracking resistance and fuel barrier properties. The laminate is excellent in interlaminar bonding and fuel barrier properties. The coated product is excellent in heat resistance, chemical resistance, corrosion resistance, oil resistance, weather resistance, abrasion resistance and lubricating properties.

    摘要翻译： 包含基于四氟乙烯和/或三氟氯乙烯的重复单元（a）的含氟共聚物，基于具有二羧酸酐基和环内可聚合不饱和基团的环状烃单体的重复单元（b）和基于其它单体的重复单元（c） ，其中重复单元（a）为50〜99.89摩尔％，重复单元（b）为0.01〜5摩尔％，重复单元（c）为0.1〜49.99摩尔％ 的重复单元（a），（b）和（c），并且其体积流动速率为0.1至1,000mm 3 / sec，以及其层压体和涂布产品。 含氟共聚物的粘合性，耐热性，耐候性，耐应力开裂性和燃料阻隔性优异。 层压板具有优异的层间结合和燃料阻隔性能。 涂布产品的耐热性，耐化学性，耐腐蚀性，耐油性，耐候性，耐磨性和润滑性优异。

    Ethylene/tetrafluoroethylene copolymer composition
    8.
    发明授权
    Ethylene/tetrafluoroethylene copolymer composition 有权
    乙烯/四氟乙烯共聚物组合物

    公开(公告)号：US07820774B2

    公开(公告)日：2010-10-26

    申请号：US11689737

    申请日：2007-03-22

    申请人： Shigeru Aida ,  Takashi Sato ,  Yoshiaki Higuchi ,  Hiroki Kamiya

    发明人： Shigeru Aida ,  Takashi Sato ,  Yoshiaki Higuchi ,  Hiroki Kamiya

    IPC分类号： C08F14/18 ,  C08F114/18 ,  C08F210/00 ,  C08L27/12 ,  C08L23/04

    CPC分类号： C08F214/265 ,  C08L23/0846 ,  C08L23/0892 ,  C08L27/18 ,  C08L2205/02 ,  C08L2666/04 ,  C08L2666/06

    摘要： The present invention provides an ethylene/tetrafluoroethylene copolymer composition having a high melt flowability while maintaining satisfactory mechanical properties in the obtainable molded product are maintained. The ethylene/tetrafluoroethylene copolymer composition (C) has a melt viscosity of from 80 to 500 Pa·s, preferably from 100 to 300 Pa·s and a tensile elongation of from 200 to 500%, preferably from 350 to 450%. The copolymer composition (C) is may be obtained by melt kneading an ethylene/tetrafluoroethylene copolymer (A) having a low melt viscosity of from 60 to 400 Pa·s, preferably from 80 to 300 Pa·s and an ethylene/tetrafluoroethylene copolymer (B) having a melt viscosity higher than this i.e. from 600 to 10,000 Pa·s, preferably from 1,000 to 7,000 Pa·s in a mass ratio of (A)/(B)=50/50 to 99/1, preferably (A)/(B)=60/40 to 97/3.

    摘要翻译： 本发明提供一种在保持所得模塑产品中保持令人满意的机械性能的情况下具有高熔体流动性的乙烯/四氟乙烯共聚物组合物。 乙烯/四氟乙烯共聚物组合物（C）的熔融粘度为80〜500Pa·s，优选为100〜300Pa·s，拉伸伸长率为200〜500％，优选为350〜450％。 共聚物组合物（C）可以通过熔融混炼熔融粘度为60〜400Pa·s，优选为80〜300Pa·s的乙烯/四氟乙烯共聚物（A）和乙烯/四氟乙烯共聚物（ B）具有比（A）/（B）= 50/50〜99/1的质量比高的600〜10000Pa·s，优选为1,000〜7,000Pa·s的熔融粘度，优选（A ）/（B）= 60/40〜97/3。

    Fluorocopolymer
    9.
    发明授权
    Fluorocopolymer 有权
    含氟共聚物

    公开(公告)号：US06753393B2

    公开(公告)日：2004-06-22

    申请号：US10356536

    申请日：2003-02-03

    申请人： Atsushi Funaki ,  Tatsuya Miyajima ,  Naoko Sumi ,  Eiichi Nishi ,  Hiroki Kamiya

    发明人： Atsushi Funaki ,  Tatsuya Miyajima ,  Naoko Sumi ,  Eiichi Nishi ,  Hiroki Kamiya

    IPC分类号： C08F11418

    CPC分类号： C08F214/265

    摘要： A fluorocopolymer which comprises (A) polymerized units based on tetrafluoroethylene, (B) polymerized units based on ethylene and (C) polymerized units based on a compound represented by CH2═CX(CF2)2Y (wherein each of X and Y which are independent of each other, is a hydrogen atom or a fluorine atom), wherein the molar ratio of (A)/(B) is from 20/80 to 80/20, and the molar ratio of (C)/((A)+(B)) is from 1/1000 to 15/100, and which has a volume flow rate of from 1 to 1000 mm3/sec. The fluorocopolymer has a low fuel permeability coefficient and is excellent in the fuel barrier properties.

    摘要翻译： 一种含氟共聚物，其包含（A）基于四氟乙烯的聚合单元，（B）基于乙烯的聚合单元和（C）基于由CH 2 = CX（CF 2）2 Y表示的化合物的聚合单元（其中X和Y各自独立地 （A）/（B）的摩尔比为20/80〜80/20，摩尔比（C）/（（A）+ （B））为1/1000〜15/100，体积流量为1〜1000mm 3 / sec。 含氟共聚物的燃料渗透系数低，燃料阻隔性优异。

    ETHYLENE/TETRAFLUOROETHYLENE COPOLYMER COMPOSITION
    10.
    发明申请
    ETHYLENE/TETRAFLUOROETHYLENE COPOLYMER COMPOSITION 有权
    乙烯/四氢氟乙烯共聚物组合物

    公开(公告)号：US20070232754A1

    公开(公告)日：2007-10-04

    申请号：US11689737

    申请日：2007-03-22

    申请人： Shigeru AIDA ,  Takashi Sato ,  Yoshiaki Higuchi ,  Hiroki Kamiya

    发明人： Shigeru AIDA ,  Takashi Sato ,  Yoshiaki Higuchi ,  Hiroki Kamiya

    IPC分类号： C08L27/12

    CPC分类号： C08F214/265 ,  C08L23/0846 ,  C08L23/0892 ,  C08L27/18 ,  C08L2205/02 ,  C08L2666/04 ,  C08L2666/06

    摘要： To provide an ethylene/tetrafluoroethylene copolymer composition having a high melt flowability while the mechanical properties of the obtainable molded product are maintained. The ethylene/tetrafluoroethylene copolymer composition (C) has a melt viscosity of from 80 to 500 Pa·s, preferably from 100 to 300 Pa·s and a tensile elongation of from 200 to 500%, preferably from 350 to 450%. The copolymer composition (C) is obtainable by melt kneading an ethylene/tetrafluoroethylene copolymer (A) having a low melt viscosity of from 60 to 400 Pa·s, preferably from 80 to 300 Pa·s and an ethylene/tetrafluoroethylene copolymer (B) having a melt viscosity higher than this i.e. from 600 to 10,000 Pa·s, preferably from 1,000 to 7,000 Pa·s in a mass ratio of (A)/(B)=50/50 to 99/1, preferably (A)/(B)=60/40 to 97/3.

    摘要翻译： 提供具有高熔体流动性的乙烯/四氟乙烯共聚物组合物，同时保持获得的模制产品的机械性能。 乙烯/四氟乙烯共聚物组合物（C）的熔融粘度为80-500Pa·s，优选为100-300Pa·s，拉伸伸长率为200-500％，优选为350-450％。 共聚物组合物（C）可以通过熔融捏合具有60至400Pa·s，优选80至300Pa·s的低熔体粘度和乙烯/四氟乙烯共聚物（B）的乙烯/四氟乙烯共聚物（A） （A）/（B）= 50/50〜99/1，优选（A）/（B）的质量比为600〜10000Pa·s，优选为1,000〜 （B）= 60/40〜97/3。