公开(公告)号：US08765272B2

公开(公告)日：2014-07-01

申请号：US13255597

申请日：2010-03-10

申请人： Keitaro Tamura ,  Daisuke Takesawa ,  Hiroki Hara ,  Kozo Kitamura ,  Yasuro Taniguchi ,  Koji Hayashi ,  Akihiro Matsumoto ,  Sung-Pyo Cho

发明人： Keitaro Tamura ,  Daisuke Takesawa ,  Hiroki Hara ,  Kozo Kitamura ,  Yasuro Taniguchi ,  Koji Hayashi ,  Akihiro Matsumoto ,  Sung-Pyo Cho

IPC分类号： B23B9/00

CPC分类号： C22C29/04 ,  C22C2204/00 ,  C23C14/06 ,  C23C16/30 ,  Y10T428/26 ,  Y10T428/30 ,  Y10T428/31678

摘要： A cermet has a hard phase which contains W and nitrogen, and includes at least one selected from a carbide, nitride and carbonitride of a metal having Ti as a main component, and a binder phase having an iron group metal as a main component. A W amount contained in the whole cermet is 5 to 40% by weight, an interfacial phase including a complex carbonitride with a larger W amount than a W amount of the hard phase being present between grains of the hard phase, and when a W amount contained in the interfacial phase based on the whole metal element is represented by Wb (atomic %), and a W amount contained in the hard phase based on the whole metal element is represented by Wh (atomic %), then, an atomic ratio of Wb to Wh (Wb/Wh) is 1.7 or more. The cermet is excellent in fracture resistance and wear resistance.

摘要翻译： 金属陶瓷具有包含W和氮的硬相，并且包括选自具有Ti作为主要成分的金属的碳化物，氮化物和碳氮化物中的至少一种以及以铁族金属为主要成分的粘结相。 包含在整个金属陶瓷中的AW量为5至40重量％，界面相包括具有比硬相的晶粒之间存在的W量大的W量的复合碳氮化物，并且当W含量 在基于整个金属元素的界面相中以Wb（原子％）表示，并且基于整个金属元素包含在硬质相中的W量由Wh（原子％）表示，然后Wb的原子比 至Wh（Wb / Wh）为1.7以上。 金属陶瓷的耐断裂性和耐磨性优异。

公开(公告)号：US20120114960A1

公开(公告)日：2012-05-10

申请号：US13381316

申请日：2010-06-30

申请人： Daisuke Takesawa ,  Keitaro Tamura ,  Hiroki Hara ,  Kozo Kitamura ,  Yasuro Taniguchi ,  Koji Hayashi

发明人： Daisuke Takesawa ,  Keitaro Tamura ,  Hiroki Hara ,  Kozo Kitamura ,  Yasuro Taniguchi ,  Koji Hayashi

IPC分类号： B32B15/00 ,  B22F7/02

CPC分类号： C23C30/005 ,  B22F2207/03 ,  B22F2999/00 ,  C22C1/051 ,  C22C29/08 ,  Y10T428/12146 ,  B22F3/101

摘要： A cermet has a WC first hard phase, a second hard phase including one or more of a carbide, nitride and carbonitride of an element(s) of groups 4, 5 and 6 of the Periodic Table including a titanium element, and a mutual solid solution thereof, and a binder phase. In the cermet, a carbon amount CT (% by weight), a tungsten amount CW (% by weight), and a nitrogen amount CN (% by weight) satisfy 0.25

摘要翻译： 金属陶瓷具有WC第一硬质相，包括元素周期表第4,5和6族元素的碳化物，氮化物和碳氮化物中的一种或多种的第二硬质相，其包括钛元素和相互固体 溶液和粘合剂相。 在金属陶瓷中，碳量CT（重量％），钨量CW（重量％）和氮量CN（重量％）满足0.25 <（CN /（CT-0.0653·CW））<6 。 金属陶瓷具有厚度为5〜100μm的表面区域，其包括第一硬质相和粘结相，以及包含第一和第二硬质相和粘结相的内部区域。 在内部区域的横截面中，第一硬质相的面积与第二硬质相的面积的比率为0.15〜4。

公开(公告)号：US20120003466A1

公开(公告)日：2012-01-05

申请号：US13255597

申请日：2010-03-10

申请人： Keitaro Tamura ,  Daisuke Takesawa ,  Hiroki Hara ,  Kozo Kitamura ,  Yasuro Taniguchi ,  Koji Hayashi ,  Akihiro Matsumoto ,  Sung-Pyo Cho

发明人： Keitaro Tamura ,  Daisuke Takesawa ,  Hiroki Hara ,  Kozo Kitamura ,  Yasuro Taniguchi ,  Koji Hayashi ,  Akihiro Matsumoto ,  Sung-Pyo Cho

IPC分类号： B32B9/04 ,  B22F1/00

CPC分类号： C22C29/04 ,  C22C2204/00 ,  C23C14/06 ,  C23C16/30 ,  Y10T428/26 ,  Y10T428/30 ,  Y10T428/31678

摘要： A cermet has a hard phase which contains W and nitrogen, and includes at least one selected from a carbide, nitride and carbonitride of a metal having Ti as a main component, and a binder phase having an iron group metal as a main component. A W amount contained in the whole cermet is 5 to 40% by weight, an interfacial phase including a complex carbonitride with a larger W amount than a W amount of the hard phase being present between grains of the hard phase, and when a W amount contained in the interfacial phase based on the whole metal element is represented by Wb (atomic %), and a W amount contained in the hard phase based on the whole metal element is represented by Wh (atomic %), then, an atomic ratio of Wb to Wh (Wb/Wh) is 1.7 or more. The cermet is excellent in fracture resistance and wear resistance.

摘要翻译： 金属陶瓷具有包含W和氮的硬相，并且包括选自具有Ti作为主要成分的金属的碳化物，氮化物和碳氮化物中的至少一种以及以铁族金属为主要成分的粘结相。 包含在整个金属陶瓷中的AW量为5至40重量％，界面相包括具有比硬相的晶粒之间存在的W量大的W量的复合碳氮化物，并且当W含量 在基于整个金属元素的界面相中以Wb（原子％）表示，并且基于整个金属元素包含在硬质相中的W量由Wh（原子％）表示，然后Wb的原子比 至Wh（Wb / Wh）为1.7以上。 金属陶瓷的耐断裂性和耐磨性优异。

公开(公告)号：US20110117368A1

公开(公告)日：2011-05-19

申请号：US13054466

申请日：2009-07-15

申请人： Hideaki Matsubara ,  Mineaki Matsumoto ,  Hiroshi Nomura ,  Yasuro Taniguchi ,  Kozo Kitamura ,  Hiroki Hara ,  Keitaro Tamura ,  Daisuke Takesawa

发明人： Hideaki Matsubara ,  Mineaki Matsumoto ,  Hiroshi Nomura ,  Yasuro Taniguchi ,  Kozo Kitamura ,  Hiroki Hara ,  Keitaro Tamura ,  Daisuke Takesawa

IPC分类号： C01B21/082 ,  C04B35/58 ,  C22C29/04

CPC分类号： C01B21/0828 ,  B82Y30/00 ,  C01P2002/85 ,  C01P2004/03 ,  C01P2004/61 ,  C01P2004/64 ,  C04B35/5607 ,  C04B35/5611 ,  C04B35/5622 ,  C04B35/5626 ,  C04B35/58007 ,  C04B35/58021 ,  C04B35/58035 ,  C04B35/6262 ,  C04B2235/3839 ,  C04B2235/3843 ,  C04B2235/3847 ,  C04B2235/3856 ,  C04B2235/3886 ,  C04B2235/422 ,  C04B2235/46 ,  C04B2235/5436 ,  C04B2235/5445 ,  C04B2235/656 ,  C04B2235/658 ,  C04B2235/77 ,  C04B2235/96 ,  C22C1/051 ,  C22C19/03 ,  C22C19/07 ,  C22C29/04 ,  Y10T428/2982

摘要： A hard powder contains much amount of a complex carbonitride solid solution, which can improve sinterability of a sintered hard alloy and give a uniform structure. The hard powder is a powder containing 90 vol % or more of a complex carbonitride solid solution represented by (Ti1-x,Mx)(C1-y,Ny), wherein M represents at least one element selected from the group consisting of W, Mo, Nb, Zr and Ta, x represents an atomic ratio of M based on the sum of Ti and M, y represents an atomic ratio of N based on the sum of C and N, x and y satisfy 0.05≦x≦0.5 and 0.01≦y≦0.75.

摘要翻译： 硬粉末含有大量的复合碳氮化物固溶体，可以提高烧结硬质合金的烧结性，赋予均匀的结构。 该硬质粉末是由（Ti1-x，Mx）（C1-y，Ny）表示的含有90体积％以上的复合碳氮化物固溶体的粉末，其中M表示选自W， Mo，Nb，Zr和Ta，x表示基于Ti和M的总和的M的原子比，y表示基于C和N之和的N的原子比，x和y满足0.05＆nlE; x＆nlE; 0.5 和0.01＆nlE; y＆nlE; 0.75。

公开(公告)号：US4633432A

公开(公告)日：1986-12-30

申请号：US767066

申请日：1985-08-19

申请人： Kozo Kitamura

发明人： Kozo Kitamura

IPC分类号： G06F12/16 ,  G06F3/02 ,  G06F12/00 ,  G06F17/21 ,  G06F17/22 ,  G06F13/00

CPC分类号： G06F3/0227

摘要： A word processing apparatus includes a random access memory for temporarily storing the document data, and a floppy disc for permanently memorizing the document data. A character number counter is included in the word processing apparatus, which develops a control signal when, for example, 100 stroke key input operation is conducted through a keyboard panel. In response to the control signal, the document data temporarily stored in the random access memory is transferred to the floppy disc for updating the document data memorized in the floppy disc.

摘要翻译： 一种文字处理装置，包括用于临时存储文件数据的随机存取存储器和用于永久存储文档数据的软盘。 在文字处理装置中包括字符数计数器，当通过键盘面板进行例如100次笔划键输入操作时，该字符计数器产生控制信号。 响应于控制信号，临时存储在随机存取存储器中的文档数据被传送到软盘以更新存储在软盘中的文档数据。

公开(公告)号：US5919968A

公开(公告)日：1999-07-06

申请号：US966651

申请日：1997-11-10

申请人： Kozo Kitamura ,  Tsuyoshi Kihara ,  Yoshinori Tanaka ,  Yoshimi Yano

发明人： Kozo Kitamura ,  Tsuyoshi Kihara ,  Yoshinori Tanaka ,  Yoshimi Yano

IPC分类号： C07F9/40 ,  C07F9/09

CPC分类号： C07F9/4006

摘要： A process for preparing an organic pentavalent phosphorus compound comprising oxidizing an organic trivalent phosphorus compound with an aqueous hydrogen peroxide solution in the presence of an inorganic or organic base at a temperature of 0.degree. C. to 50.degree. C. to obtain the corresponding organic pentavalent phosphorus compound.

摘要翻译： 一种制备有机五价磷化合物的方法，包括在无机或有机碱的存在下，在0℃至50℃的温度下，用过氧化氢水溶液氧化有机三价磷化合物，得到相应的有机五价 磷化合物。

公开(公告)号：US5145505A

公开(公告)日：1992-09-08

申请号：US832316

申请日：1992-02-07

申请人： Takeshi Saito ,  Kozo Kitamura ,  Mitsuo Ueki

发明人： Takeshi Saito ,  Kozo Kitamura ,  Mitsuo Ueki

IPC分类号： B22F3/10 ,  C22C1/05 ,  C22C29/02 ,  C22C29/04 ,  C22C29/16

CPC分类号： C22C29/02

摘要： Disclosed are a high toughness cermet comprising a sintered alloy comprising 75 to 95% by weight of a hard phase of carbide, nitride or carbonitride containing Ti, at least one of W, Mo and Cr, and N and C, and the balance of a binder phase composed mainly of an iron group metal, and inevitable impurities,wherein the content of Ti in said sintered alloy is 35 to 85% by weight calculated on TiN or TiN and TiC, and the contents of W, Mo and Cr are 10 to 40% by weight in total calculated on WC, Mo.sub.2 C and/or Cr.sub.3 C.sub.2,the relative concentration of said binder phase at the 0.01 mm-inner portion from the surface of said sintered alloy is 5 to 50% of the average binder phase concentration of the inner portion, and the relative concentration of said binder phase at the 0.1 mm-inner portion from the surface of said sintered alloy is 70 to 100% of the average binder phase concentration of the inner portion, anda compression stress of 30 kgf/mm.sup.2 or more remains at the surface of said sintered alloy,and a process for preparing the same.

公开(公告)号：US3983577A

公开(公告)日：1976-09-28

申请号：US500928

申请日：1974-08-27

申请人： Youichi Ito ,  Kozo Kitamura

发明人： Youichi Ito ,  Kozo Kitamura

IPC分类号： G06F3/02 ,  G06K17/00 ,  G07G1/12 ,  G11B15/02 ,  G11B20/12 ,  G11B27/30 ,  G11B19/04 ,  G11B15/04

CPC分类号： G11B27/3027 ,  G11B15/026 ,  G11B20/1205

摘要： The data processing terminal unit in the form of a point of sale transaction device disclosed herein contains a keyboard for introducing data into the data processing terminal unit and a cassette tape deck which includes a cassette type magnetic tape and a cassette tape recording scheme for data storage. There are provided an E key and an M key on the keyboard for introducing end marking signals (EM signals) which indicates completion of data entry. The EM signals are introduced into the data processing terminal unit when the E key and the M key are depressed successively or simultaneously, thereby preventing erroneous introduction of the EM signals at an undesired time.

摘要翻译： 本文公开的销售点交易装置形式的数据处理终端单元包括用于将数据引入数据处理终端单元的键盘和包括盒型磁带和用于数据存储的盒式磁带记录方案的盒式磁带 。 在键盘上提供E键和M键，用于引入表示数据输入完成的结束标记信号（EM信号）。 当E键和M键被连续或同时按下时，EM信号被引入数据处理终端单元，从而防止EM信号在不期望的时间被错误地引入。

公开(公告)号：US5918103A

公开(公告)日：1999-06-29

申请号：US693343

申请日：1996-08-06

申请人： Masaki Kobayashi ,  Kozo Kitamura ,  Satoshi Kinoshita

发明人： Masaki Kobayashi ,  Kozo Kitamura ,  Satoshi Kinoshita

IPC分类号： C22C1/05 ,  C22C29/08 ,  B22F7/00

CPC分类号： C22C1/055 ,  C22C29/08 ,  Y10T428/12056 ,  Y10T428/12063

摘要： Disclosed are a plate-crystalline tungsten carbide-containing hard alloy which comprises 4 to 40% by volume of a binder phase containing at least one of iron group metals selected from Co, Ni and Fe as a main component; and the balance of a hard phase comprising tungsten carbide alone, or tungsten carbide and 50% by volume or less of a compound with a cubic structure selected from at least one of carbide and nitride of the 4a (Ti, Zr and Hf), 5a (V, Nb and Ta) or 6a (Cr, Mo and W) group element of the periodic table and mutual solid solutions thereof, and inevitable impurities,wherein when peak intensities at a (001) face and a (101) face in X-ray diffraction using K.alpha. rays with Cu being a target are represented by h(001) and h(101), respectively, the tungsten carbide satisfies h(001)/h(101).gtoreq.0.50, a composition for forming a plate-crystalline tungsten carbide, and a process for preparing the plate-crystalline tungsten carbide-containing hard alloy.

摘要翻译： 公开了含有4〜40体积％的含有选自Co，Ni和Fe中的铁族金属中的至少一种作为主要成分的粘结相的4〜40体积％的硬质合金。 并且包括单独的碳化钨或碳化钨的硬质相的余量和50体积％以下的具有选自4a（Ti，Zr和Hf），5a（Ti，Zr和Hf）的碳化物和氮化物中的至少一种的立方结构的化合物 （V，Nb和Ta）或6a（Cr，Mo和W）族元素及其相互固溶体和不可避免的杂质，其中当X（001）面和（101）面的峰值强度 使用K为靶的Kα射线的射线衍射分别由h（001）和h（101）表示，碳化钨满足h（001）/ h（101）> / = 0.50，用于形成 板状碳化钨，以及制备含板状碳化钨的硬质合金的方法。

公开(公告)号：US5993506A

公开(公告)日：1999-11-30

申请号：US977628

申请日：1997-11-25

申请人： Masaki Kobayashi ,  Kozo Kitamura ,  Satoshi Kinoshita

发明人： Masaki Kobayashi ,  Kozo Kitamura ,  Satoshi Kinoshita

IPC分类号： C22C1/05 ,  C22C29/08

CPC分类号： C22C1/055 ,  C22C29/08 ,  Y10T428/12056 ,  Y10T428/12063

摘要： Disclosed are a plate-crystalline tungsten carbide-containing hard alloy which comprises 4 to 40% by volume of a binder phase containing at least one of iron group metals selected from Co, Ni and Fe as a main component; and the balance of a hard phase comprising tungsten carbide alone, or tungsten carbide and 50% by volume or less of a compound with a cubic structure selected from at least one of carbide and nitride of the 4a (Ti, Zr and Hf), 5a (V, Nb and Ta) or 6a (Cr, Mo and W) group element of the periodic table and mutual solid solutions thereof, and inevitable impurities,wherein when peak intensities at a (001) face and a (101) face in X-ray diffraction using K.alpha. rays with Cu being a target are represented by h(001) and h(101), respectively, the tungsten carbide satisfies h(001)/h(101) .gtoreq.0.50, a composition for forming a plate-crystalline tungsten carbide, and a process for preparing the plate-crystalline tungsten carbide-containing hard alloy.

摘要翻译： 公开了含有4〜40体积％的含有选自Co，Ni和Fe中的铁族金属中的至少一种作为主要成分的粘结相的4〜40体积％的硬质合金。 并且包括单独的碳化钨或碳化钨的硬质相的余量和50体积％以下的具有选自4a（Ti，Zr和Hf），5a（Ti，Zr和Hf）的碳化物和氮化物中的至少一种的立方结构的化合物 （V，Nb和Ta）或6a（Cr，Mo和W）族元素及其相互固溶体和不可避免的杂质，其中当X（001）面和（101）面的峰值强度 使用K为靶的Kα射线的射线衍射分别由h（001）和h（101）表示，碳化钨满足h（001）/ h（101）> / = 0.50，用于形成 板状碳化钨，以及制备含板状碳化钨的硬质合金的方法。