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公开(公告)号：US20070196569A1
公开(公告)日：2007-08-23
申请号：US11641014
申请日：2006-12-19
CPC分类号： G02B1/10 , B05D1/005 , B29D11/00903 , G02B5/22
摘要： The installation includes elements for the temporary injection of inert gas; and at least one individual and autonomous casing (6) provided with a window (13) and including receiving elements for a support (3) carrying an ophthalmic lens (2), and sealing elements (21) adapted to form around the ophthalmic lens (2) a sealed enclosure, that enclosure including a non-return inlet member adapted to cooperate with the elements for the temporary injection of inert gas.
摘要翻译： 该装置包括临时注入惰性气体的元件; 以及设置有窗口（13）并且包括用于承载眼用透镜（2）的支撑件（3）的接收元件的至少一个单独和自主的壳体（6），以及适于围绕眼科镜片形成的密封元件（21） 2）密封的外壳，该外壳包括适于与用于临时注入惰性气体的元件配合的止回入口构件。
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公开(公告)号：US07735446B2
公开(公告)日：2010-06-15
申请号：US11641014
申请日：2006-12-19
CPC分类号： G02B1/10 , B05D1/005 , B29D11/00903 , G02B5/22
摘要： The installation includes elements for the temporary injection of inert gas; and at least one individual and autonomous casing (6) provided with a window (13) and including receiving elements for a support (3) carrying an ophthalmic lens (2), and sealing elements (21) adapted to form around the ophthalmic lens (2) a sealed enclosure, that enclosure including a non-return inlet member adapted to cooperate with the elements for the temporary injection of inert gas.
摘要翻译： 该装置包括临时注入惰性气体的元件; 以及设置有窗口（13）并且包括用于承载眼用透镜（2）的支撑件（3）的接收元件的至少一个单独和自主的壳体（6），以及适于围绕眼镜片形成的密封元件（21） 2）密封的外壳，该外壳包括适于与用于临时注入惰性气体的元件配合的止回入口构件。
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公开(公告)号：US20100144918A1
公开(公告)日：2010-06-10
申请号：US12594560
申请日：2008-04-04
CPC分类号： C01G25/02 , B01J13/0047 , B82Y30/00 , C01P2004/04 , C01P2004/64 , C01P2006/60
摘要： A method for preparing a colloidal solution of non-aggregated zirconia particles, comprising the following steps: a) providing a zirconium hydroxide sol, b) adding to said sol an inorganic acid according to an [inorganic acid]/[Zr] molar ratio of
摘要翻译： 一种制备非聚集氧化锆颗粒的胶体溶液的方法，包括以下步骤：a）提供氢氧化锆溶胶，b）根据[无机酸] / [Zr]摩尔比，向所述溶胶中加入无机酸 <0.5，c）进行所述溶胶的水热处理，和d）回收氧化锆颗粒的胶体溶液。
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4.发明申请Mold and Method of Injection Molding Objects Made of Polymeric Materials and Object Obtained Therefrom 失效注塑成型模具和方法由聚合材料制成，并由其获得公开(公告)号：US20070132123A1
公开(公告)日：2007-06-14
申请号：US11422500
申请日：2006-06-06
申请人： Matthieu Koscher , Noemie Lesartre
发明人： Matthieu Koscher , Noemie Lesartre
CPC分类号： B29D11/00538 , B29D11/00413 , B29D11/00432 , Y10S425/808
摘要： A mold for molding an optical element, in particular using a reaction injection molding method (RIM). The mold comprises a generally circular shaped, mold cavity having a geometrical center and a main plane, a sprue base with a longitudinal axis and a feed connection that makes the sprue base communicate with a feed sill of the mold cavity, the longitudinal axis of the sprue base and the geometrical center of the mold cavity defining a mold symmetry plane orthogonal to the main plane of the mold cavity, which intersection with said main plane defines a mold main axis, characterized in that the longitudinal axis of the sprue base together with a line perpendicular to the main plane of the mold cavity forms an angle ranging from 0 to 30°, preferably from 0 to 15°. Methods of using the mold and objects made thereby are also disclosed.
摘要翻译： 一种用于模制光学元件的模具，特别是使用反应注射成型方法（RIM）。 模具包括具有几何中心和主平面的大致圆形的模具腔，具有纵向轴线的浇道底座和进料连接件，其使浇道底座与模腔的进料口连通， 浇口基部和模腔的几何中心限定与模具腔的主平面正交的模具对称平面，与所述主平面的交点限定模具主轴，其特征在于，浇口的纵向轴线与一个 垂直于模腔主平面的线形成0至30°，优选0至15°的角度。 还公开了使用模具的方法和由此制成的物体。
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5.发明授权Thermosetting poly(thio)urethane formulation comprising at least one block copolymer and use thereof in optics for the production of organic lenses having improved toughness 有权包含至少一种嵌段共聚物的热固性聚（硫代）氨基甲酸酯配制剂及其在用于生产具有改进的韧性的有机透镜的光学中的用途公开(公告)号：US08299176B2
公开(公告)日：2012-10-30
申请号：US11910175
申请日：2006-03-29
CPC分类号： C08L75/04 , C08G2270/00 , C08L33/08 , G02B1/041 , C08L33/00 , C08L2666/04
摘要： The invention relates to a polymerisable liquid mixture comprising: (a) a polymerisable thermosetting composition which is a precursor by polymerization of a first thermoset polymer material, said composition containing at least one polythiol and/or one polyol, preferably a polythiol, and at least one polyiso(thio)cyanate; and (b) a second polymer material solubilized in the aforementioned polymerisable thermosetting composition, whereby the second material (i) contains at least one block copolymer comprising at least two polymer blocks A and B, namely an elastomer block A and a hydrophilic block B, and, following polymerization of the polymerisable mixture, (ii) forms domains which are rich in elastomer block A and which are dispersed throughout the first material, said domains being smaller than 80 nanometers and preferably smaller than 50 nanometers. The invention also relates to a transparent article having improved toughness, which is produced by means of polymerization of the above-mentioned polymerisable mixture, comprising an alloy of a first thermoset polymer material forming the matrix of said article and of a second polymer material which is dispersed throughout said first material. The aforementioned articles have improved resistance to impact and to crack propagation. The invention is suitable for use in ophthalmic optics.
摘要翻译： 本发明涉及可聚合液体混合物，其包含：（a）可聚合的热固性组合物，其是通过第一热固性聚合物材料的聚合的前体，所述组合物含有至少一种多硫醇和/或一种多元醇，优选多硫醇，并且至少 一种多异（硫）氰酸酯; 和（b）溶解在上述可聚合热固性组合物中的第二聚合物材料，其中第二材料（i）含有至少一种包含至少两个聚合物嵌段A和B的嵌段共聚物，即弹性体嵌段A和亲水嵌段B， 并且在聚合可聚合的混合物之后，（ii）形成富含弹性体嵌段A并且分散在整个第一材料中的畴，所述畴小于80纳米，优选小于50纳米。 本发明还涉及具有改进的韧性的透明制品，其通过上述可聚合混合物的聚合制备，包括形成所述制品的基质的第一热固性聚合物材料和第二聚合物材料的合金，所述第二聚合物材料是 分散在所述第一材料中。 上述制品具有改善的抗冲击性和抗裂纹性。 本发明适用于眼科光学。
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6.发明申请METHOD FOR THE PREPARATION OF A TRANSPARENT MOULDING BASED ON A BLEND OF THERMOPLASTIC POLYMER AND THERMOSETTING POLYMER 审中-公开基于热塑性聚合物和热固性聚合物的混合物制备透明模塑的方法公开(公告)号：US20090054547A1
公开(公告)日：2009-02-26
申请号：US12197626
申请日：2008-08-25
CPC分类号： C08F222/1006 , C08F265/06 , C08F287/00 , C08F290/06 , C08F290/061 , C08L33/14 , C08L51/003 , C08L51/006 , C08L53/00 , C08L2666/02
摘要： The present invention relates to a method of preparing a transparent moulding comprising a blend of a first thermoset polymeric material forming the matrix of said moulding, and of a second polymeric material dispersed within said first material, said method comprising at least the following stages: i) preparation of a liquid polymerizable mixture by dissolving said second polymeric material in a thermosetting polymerizable composition that is a precursor of said first thermoset polymeric material, ii) filling of a mould with the liquid polymerizable mixture obtained in stage i), iii) cooling of the liquid polymerizable mixture in the mould to a temperature T less than or equal to 0° C., iv) initiation of the polymerization of said cooled liquid polymerizable mixture at a temperature T′ less than or equal to 0° C., v) continuation of the polymerization of said liquid polymerizable mixture until a hardened blend of polymers is obtained, and vi) removal of the moulding formed from said blend of polymers from the mould. The invention also relates to a transparent moulding obtainable by such a method comprising a blend of polymers, at least one of which is a thermosetting polymer.
摘要翻译： 本发明涉及一种制备透明模制品的方法，其包括形成所述模制品的基质的第一热固性聚合物材料和分散在所述第一材料内的第二聚合材料的共混物，所述方法至少包括以下阶段：i ）通过将所述第二聚合物材料溶解在作为所述第一热固性聚合物材料的前体的热固性可聚合组合物中制备液体可聚合混合物，ii）用步骤i）中获得的液体可聚合混合物填充模具，iii）冷却 模具中的液体可聚合混合物的温度T小于或等于0℃，iv）在低于或等于0℃的温度T'下引发所述冷却的液体可聚合混合物的聚合，v） 继续所述液体可聚合混合物的聚合，直到获得硬化的聚合物共混物，和vi）除去由所述聚合物形成的模制品 从模具中混合聚合物。 本发明还涉及通过这种方法获得的透明模塑件，其包括聚合物的共混物，其中至少一种是热固性聚合物。
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公开(公告)号：US20080230931A1
公开(公告)日：2008-09-25
申请号：US10598357
申请日：2005-02-25
CPC分类号： B29C67/246 , B29C45/0001 , B29D11/00009 , Y10S425/808
摘要： The object of the invention is a process for molding an optical element such as a lens (2). According to the invention, the element is obtained by a reaction injection molding process comprising the steps of mixing at least two polymerizing reactants and forcing the obtained reacting mixture by an injection duct (5) for filling under pressure a scaled mold cavity (4) having an entry side (43) provided with a casting opening (42) and an evacuation side (44) and providing a laminated flow of mixture in a spout (6) having a progressive enlarging transversal section between the outlet opening (52) of the injection duct (5) and the casting opening (42) of the mold cavity (4), for avoiding any turbulent area in said laminated flow, said evacuation side (44) being provided with means (45) for evacuating air contained in the mixture during mold filling. The invention also covers the molding installation adapted for using such a process.
摘要翻译： 本发明的目的是用于模制诸如透镜（2）的光学元件的工艺。 根据本发明，通过反应注射成型方法获得元件，该方法包括以下步骤：混合至少两种聚合反应物，并通过注射管道（5）强制所得反应混合物，以在压力下填充比例缩放的模腔（4） 设置有铸造开口（42）和排气侧（44）的进入侧（43），并且在喷射器（6）的出口（52）之间具有逐渐扩大横截面的喷口（6）中提供混合物的层压流 管道（5）和模腔（4）的铸造开口（42），用于避免所述层压流中的任何湍流区域，所述抽空侧（44）设置有用于抽空混合物中的空气的装置（45） 模具填充。 本发明还包括适于使用这种方法的成型装置。
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公开(公告)号：US20070212518A1
公开(公告)日：2007-09-13
申请号：US11677661
申请日：2007-02-22
IPC分类号： B32B3/04
CPC分类号： B29C41/32 , B29C63/02 , B29D11/0073 , B29K2995/0034 , B29L2025/00 , G02B5/305 , Y10T428/10 , Y10T428/1005 , Y10T428/24248
摘要： A multilayer polarizing structure is produced on a temporary support. The structure comprises at least one orienting layer and one polarizing layer comprising dichroic dyes, the dichroic dyes having an angular orientation determined by the orienting layer. The multilayer structure is separated from the temporary substrate before being applied onto a surface of an optical element. Applying the structure onto the optical element may be easily carried out while obtaining a quality compatible with many uses of the optical element, in particular ophthalmic use.
摘要翻译： 在临时支架上产生多层极化结构。 该结构包括至少一个取向层和一个包含二色性染料的偏振层，二色性染料具有由取向层确定的角度取向。 在施加到光学元件的表面上之前，将多层结构与临时衬底分离。 将结构应用于光学元件可以容易地实现，同时获得与光学元件的许多用途相适应的质量，特别是眼用。
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9.发明申请公开(公告)号：US20100136290A1
公开(公告)日：2010-06-03
申请号：US11993796
申请日：2006-06-22
CPC分类号： G02B1/10 , B29D11/00865 , Y10T428/24364
摘要： A method for producing an article which is made of a transparent material and devoid of visible surface lines consists in producing a substrate which is made of a transparent material having a refractive index ns, whose at least main face is machined and polished in such a way that the Ra value thereof ranges from 0.001 to 0.1 μm, but has visible surface defects in the form of thin individual scratches, in deposing, a liquid polymerisable composition of a masking coating, whose contact angle with said substrate main face is equal or less than 30° and which is formed by polymerising a masking coating having a refractive index nc such as 0.01
摘要翻译： 由透明材料制成且没有可见表面线的制品的制造方法在于制造由折射率为ns的透明材料制成的基板，其至少主面以这种方式被加工和抛光 其Ra值范围为0.001〜0.1μm，但是在剥离时，具有薄的个别刮痕形式的可见表面缺陷，所述掩模涂层的液体可聚合组合物与所述基板主面的接触角等于或小于 30°，其通过聚合具有折射率nc（例如0.01 <| ns-nc | = 0.15）和厚度小于10微米的掩模涂层而形成，直接在基板的经机加工和抛光的主面上， 掩蔽涂料组合物和去除透明制品。
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10.发明申请Method for the preparation of a transparent thermosetting polymer / thermoplastic polymer blend type material and its use in optics for the manufacture of organic glasses 审中-公开用于制备透明热固性聚合物/热塑性聚合物共混物类型材料的方法及其在制造有机玻璃的光学中的应用公开(公告)号：US20090076185A1
公开(公告)日：2009-03-19
申请号：US12197630
申请日：2008-08-25
CPC分类号： C08F287/00 , C08F285/00 , G02B1/041
摘要： The present invention relates to a method for the preparation of a transparent moulding comprising a blend of a thermoset polymeric material forming the matrix of said article, and a thermoplastic polymeric material, dispersed within said thermoset polymeric material, said process comprising at least the following stages: i) preparation of a liquid polymerizable mixture by dissolving said thermoplastic polymeric material in a thermosetting composition that is a precursor of said matrix, ii) filling of a mould with the liquid polymerizable mixture prepared in stage i), iii) polymerization of the liquid polymerizable mixture until a hardened blend of polymers is obtained, and iv) removal of the moulding formed by said blend of polymers, said process being characterized by the fact that the thermosetting composition comprises at least 60% by weight of 4,4′-di(ethoxyethyl)-bisphenol A dimethacrylate and at least 12% by weight of at least one monofunctional or multifunctional acrylic comonomer and by the fact that the thermoplastic polymeric material comprises at least one polystyrene-block-polybutadiene-block-poly(methyl methacrylate) (PS-b-PB-b-PMMA) triblock copolymer. The invention also relates to a transparent moulding obtained by this method as well as the polymerizable liquid mixture prepared in stage i).
摘要翻译： 本发明涉及一种制备透明模制品的方法，该透明模塑料包括形成所述制品的基质的热固性聚合材料和分散在所述热固性聚合物材料中的热塑性聚合材料的共混物，所述方法至少包括以下阶段 ：i）通过将所述热塑性聚合物材料溶解在作为所述基质的前体的热固性组合物中来制备液体可聚合混合物，ii）用步骤i）中制备的液体可聚合混合物填充模具，iii）液体的聚合 可聚合的混合物直到得到聚合物的硬化共混物，以及iv）除去由所述聚合物共混物形成的模制品，所述方法的特征在于，热固性组合物包含至少60重量％的4,4'-二 （乙氧基乙基） - 双酚A二甲基丙烯酸酯和至少12重量％的至少一个单官能或多功能丙烯酸共聚物 并且由于热塑性聚合物材料包含至少一种聚苯乙烯 - 嵌段 - 聚丁二烯 - 嵌段 - 聚（甲基丙烯酸甲酯）（PS-b-PB-b-PMMA）三嵌段共聚物。 本发明还涉及通过该方法获得的透明模制品以及在步骤i）中制备的可聚合液体混合物。
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