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公开(公告)号：US4271323A
公开(公告)日：1981-06-02
申请号：US621416
申请日：1975-10-10
申请人： Daniel Durand , Gerard Hillion , Christian Lassau , Lucien Sajus
发明人： Daniel Durand , Gerard Hillion , Christian Lassau , Lucien Sajus
IPC分类号： C07C29/20 , B01J23/00 , B01J31/04 , B01J31/14 , B01J31/22 , C07B31/00 , C07B35/02 , C07B61/00 , C07C1/00 , C07C5/02 , C07C13/10 , C07C13/12 , C07C13/18 , C07C13/273 , C07C27/00 , C07C29/19 , C07C35/08 , C07C67/00 , C07C5/10 , C07C85/12
CPC分类号： B01J31/04 , B01J31/0212 , B01J31/12 , B01J31/143 , B01J31/2234 , B01J2231/645 , B01J2231/646 , B01J2531/26 , B01J2531/48 , B01J2531/64 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847
摘要： Process for hydrogenating unsaturated compounds in the liquid phase in the presence of a soluble catalyst obtained by reacting an organometal derivative or a metal hydride with a synergistic mixture of (a) a compound of zinc, zirconium, manganese, molybdenum, or iron and (b) a nickel or cobalt compound.
摘要翻译： 在有机金属衍生物或金属氢化物与（a）锌，锆，锰，钼或铁的化合物和（b）的协同混合物反应获得的可溶性催化剂存在下，使液相中的不饱和化合物氢化的方法 ）镍或钴化合物。
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2.发明授权Process for manufacturing dicyclohexanol propane by hydrogenation of diphenol propane 失效通过氢化二酚丙烷制备二环己醇丙烷的方法
公开(公告)号：US4192960A
公开(公告)日：1980-03-11
申请号：US885223
申请日：1978-03-10
申请人： Gerard Hillion , Christian Lassau
发明人： Gerard Hillion , Christian Lassau
CPC分类号： C07C29/20 , C07C2101/14
摘要： Diphenol propane is hydrogenated in the presence of a homogeneous catalyst; water and an alcohol are added at the end of the reaction to assist in the separation of the catalyst residues.
摘要翻译： 二苯酚丙烷在均相催化剂存在下氢化; 在反应结束时加入水和醇，以帮助分离催化剂残余物。
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公开(公告)号：US3946087A
公开(公告)日：1976-03-23
申请号：US448483
申请日：1974-03-06
申请人： Gerard Hillion , Christian Lassau
发明人： Gerard Hillion , Christian Lassau
CPC分类号： B01J31/04 , B01J31/0212 , B01J31/143 , C07C29/145 , B01J2231/643 , C07B2200/07 , C07C2101/14
摘要： Ketones are converted by hydrogenation to the corresponding secondary alcohols, in the presence of a soluble catalyst which is obtained by contacting a metal compound, for example a cobalt, nickel or iron salt, with a reducing agent, preferably a trialkylaluminum compound, the reaction being carried out with added metal alcoholate, preferably an alkali metal alcoholate.
摘要翻译： 在通过使金属化合物，例如钴，镍或铁盐与还原剂，优选三烷基铝化合物接触而获得的可溶性催化剂存在下，将酮通过氢化转化为相应的仲醇，反应为 用添加的金属醇化物，优选碱金属醇化物进行。
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公开(公告)号：US4357478A
公开(公告)日：1982-11-02
申请号：US152961
申请日：1980-05-23
申请人： Gerard Hillion , Christian Lassau
发明人： Gerard Hillion , Christian Lassau
IPC分类号： C07C5/02 , B01J31/00 , B01J31/04 , B01J31/12 , B01J31/14 , C07B31/00 , C07B35/02 , C07B61/00 , C07C1/00 , C07C5/03 , C07C5/10 , C07C9/00 , C07C13/02 , C07C13/18 , C07C27/00 , C07C29/20 , C07C35/21 , C07C67/00 , C07C29/19 , B01J31/02
CPC分类号： B01J31/143 , B01J31/04 , C07C5/10 , B01J2231/645 , B01J2231/646
摘要： Unsaturated compounds are hydrogenated in the presence of a catalyst obtained by reacting an organoaluminum compound with a transition metal carboxylate and an organic carboxylic acid.
摘要翻译： 不饱和化合物在有机铝化合物与过渡金属羧酸盐和有机羧酸反应得到的催化剂存在下氢化。
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5.发明授权Process for manufacturing dicyclohexanol propane by hydrogenating diphenol propane 失效通过加氢二苯醚丙烷制备二苯甲醇丙酸的方法
公开(公告)号：US4001343A
公开(公告)日：1977-01-04
申请号：US575996
申请日：1975-05-09
申请人： Jean Gaillard , Christian Lassau
发明人： Jean Gaillard , Christian Lassau
CPC分类号： C07C35/22
摘要： Process for manufacturing dicyclohexanol propane by hydrogenating, with molecular hydrogen, in the presence of a hydrogenation catalyst, diphenol propane dissolved in 2 ethyl-hexanol, adding water at the end of the reaction, distilling the reaction product and separating from the distillate an aqueous phase and a 2 ethyl-hexanol phase, the latter being reused as solvent for the reaction.
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