公开(公告)号：US20230138884A1

公开(公告)日：2023-05-04

申请号：US17820861

申请日：2022-08-18

申请人： P2 SCIENCE, INC.

发明人： Patrick FOLEY

IPC分类号： C07C35/06 ,  C07C39/19 ,  C07C31/27 ,  C07C49/297 ,  C07C49/303 ,  C07C49/537 ,  C07C49/835 ,  C07C13/18 ,  C07C13/10

摘要： The present disclosure is directed to novel derivatives of naturally occurring humulones and lupulones, methods of making them, compositions comprising them, and methods for using them.

公开(公告)号：US20090069610A1

公开(公告)日：2009-03-12

申请号：US11948006

申请日：2007-11-30

申请人： William L. Roberts, IV ,  H. Henry Lamb ,  Larry F. Stikeleather ,  Timothy L. Turner

发明人： William L. Roberts, IV ,  H. Henry Lamb ,  Larry F. Stikeleather ,  Timothy L. Turner

IPC分类号： C10G3/00 ,  C07C9/00 ,  C07C15/24 ,  C07C13/18

CPC分类号： C07C1/22 ,  C10G1/006 ,  C10G3/47 ,  C10G3/50 ,  C10G3/56 ,  C10G45/58 ,  C10G45/68 ,  C10G47/00 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/4081 ,  C10G2300/44 ,  C10G2300/805 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C11C3/10 ,  Y02E50/13 ,  Y02P30/20 ,  Y02T50/678

摘要： The present invention is directed to processes for the direct conversion of lipidic biomass fuelstock to combustible fuels. In particular, the invention provides a process for the direct conversion of animal fats to transportations fuels suitable as replacement for petroleum-derived transportation fuels. In one embodiment, the method comprises the steps of hydrolyzing a lipidic biomass to form free fatty acids, catalytically deoxygenating the free fatty acids to form n-alkanes, and reforming at least a portion of the n-alkanes into a mixture of compounds in the correct chain length, conformations, and ratio to be useful transportation fuels. Particularly, the product prepared according to the invention comprises mixtures of hydrocarbon compounds selected from the group consisting of n-alkanes, isoalkanes, aromatics, cycloalkanes, and combinations thereof.

摘要翻译： 本发明涉及将脂质生物质燃料原料直接转化为可燃燃料的方法。 特别地，本发明提供了一种将动物脂肪直接转化为运输燃料的方法，该燃料适合作为替代石油衍生的运输燃料。 在一个实施方案中，该方法包括以下步骤：水解脂质生物质以形成游离脂肪酸，催化脱氧游离脂肪酸形成正烷烃，并将至少一部分正烷烃重整成化合物的混合物 正确的链长，构象和比例是有用的运输燃料。 特别地，根据本发明制备的产品包括选自正烷烃，异烷烃，芳族化合物，环烷烃及其组合的烃化合物的混合物。

公开(公告)号：US20050192175A1

公开(公告)日：2005-09-01

申请号：US11119563

申请日：2005-05-02

申请人： Omar Yaghi ,  Mohamed Eddaoudi ,  Hailian Li ,  Jaheon Kim ,  Nathaniel Rosi

发明人： Omar Yaghi ,  Mohamed Eddaoudi ,  Hailian Li ,  Jaheon Kim ,  Nathaniel Rosi

IPC分类号： B01J20/22 ,  B01J20/28 ,  B01J20/30 ,  B01J31/16 ,  C07C7/20 ,  C07C9/04 ,  C07C13/18 ,  C07C15/04 ,  C07C19/01 ,  C07C19/04 ,  C07C19/041 ,  C07C63/26 ,  C07F3/00 ,  C07F3/06 ,  F17C11/00 ,  B01J29/06

CPC分类号： B01J20/2808 ,  B01J20/226 ,  B01J20/28011 ,  B01J20/28014 ,  B01J20/28069 ,  B01J20/28078 ,  B01J20/30 ,  B01J31/1691 ,  B01J2531/26 ,  C07F3/003 ,  F17C11/007 ,  Y02C10/08

摘要： The ability to design and construct solid-state materials with pre-determined structures is a grand challenge in chemistry. An inventive strategy based on reticulating metal ions and organic carboxylate links into extended networks has been advanced to a point that has allowed the design of porous structures in which pore size and functionality can be varied systematically. MOF-5, a prototype of a new class of porous materials and one that is constructed from octahedral Zn—O—C clusters and benzene links, was used to demonstrate that its 3-D porous system can be functionalized with the organic groups, —Br, —NH2, —OC3H7, —OC5H11, —H4C2, and —H4C4, and its pore size expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl. The ability to direct the formation of the octahedral clusters in the presence of a desired carboxylate link is an essential feature of this strategy, which resulted in the design of an isoreticular (having the same framework topology) series of sixteen well-defined materials whose crystals have open space representing up to 91.1% of the crystal volume, and homogeneous periodic pores that can be incrementally varied from 3.8 to 28.8 angstroms. Unlike the unpredictable nature of zeolite and other molecular sieve syntheses, the deliberate control exercised at the molecular level in the design of these crystals is expected to have tremendous implications on materials properties and future technologies. Indeed, data indicate that members of this series represent the first monocrystalline mesoporous organic/inorganic frameworks, and exhibit the highest capacity for methane storage (155 cm3/cm3 at 36 atm) and the lowest densities (0.41 to 0.21 g/cm3) attained to date for any crystalline material at room temperature.

公开(公告)号：US06930193B2

公开(公告)日：2005-08-16

申请号：US10137043

申请日：2002-04-30

申请人： Omar M. Yaghi ,  Mohamed Eddaoudi ,  Hailian Li ,  Jaheon Kim ,  Nathaniel Rosi

发明人： Omar M. Yaghi ,  Mohamed Eddaoudi ,  Hailian Li ,  Jaheon Kim ,  Nathaniel Rosi

IPC分类号： B01J20/22 ,  B01J20/28 ,  B01J20/30 ,  B01J31/16 ,  C07C7/20 ,  C07C9/04 ,  C07C13/18 ,  C07C15/04 ,  C07C19/01 ,  C07C19/04 ,  C07C19/041 ,  C07C63/26 ,  C07F3/00 ,  C07F3/06 ,  F17C11/00 ,  C07F13/00 ,  C07F11/00 ,  C07F15/00

CPC分类号： B01J20/2808 ,  B01J20/226 ,  B01J20/28011 ,  B01J20/28014 ,  B01J20/28069 ,  B01J20/28078 ,  B01J20/30 ,  B01J31/1691 ,  B01J2531/26 ,  C07F3/003 ,  F17C11/007 ,  Y02C10/08

摘要： An isoreticular metal-organic framework (IRMOF) and method for systematically forming the same. The method comprises the steps of dissolving at least one source of metal cations and at least one organic linking compound in a solvent to form a solution; and crystallizing the solution under predetermined conditions to form a predetermined IRMOF. At least one of functionality, dimension, pore size and free volume of the IRMOF is substantially determined by the organic linking compound.

摘要翻译： 一种非线性金属有机骨架（IRMOF）及其系统形成方法。 该方法包括将至少一种金属阳离子源和至少一种有机连接化合物源溶解在溶剂中以形成溶液的步骤; 并在预定条件下使溶液结晶以形成预定的IRMOF。 IRMOF的功能，尺寸，孔径和自由体积中的至少一个基本上由有机连接化合物确定。

公开(公告)号：US20050065388A1

公开(公告)日：2005-03-24

申请号：US10943896

申请日：2004-09-20

申请人： Patrick Briot ,  Sylvie Lacombe ,  Jean-Francois Joly ,  Eric Llido

发明人： Patrick Briot ,  Sylvie Lacombe ,  Jean-Francois Joly ,  Eric Llido

IPC分类号： C07C2/64 ,  C07C2/66 ,  C07C2/86 ,  C07C5/10 ,  C07C13/18 ,  C10L1/08

CPC分类号： C10L1/08 ,  C07C2/64 ,  C07C2/66 ,  C07C2/861 ,  C07C5/10 ,  C07C13/18 ,  C07C2521/04 ,  C07C2527/126 ,  C07C2529/18 ,  C07C2601/14 ,  C07C15/107

摘要： The invention relates to a method for formulation of a synthetic gas oil or an additive for gas oil in which an alkyl-aromatic compound or a mixture of alkyl-aromatic compounds is selected based on at least one parameter that is selected from the group that consists of the number of cycles of the aromatic core, the number of alkyl chains that are grafted to the aromatic cycle, the length of the alkyl chain or chains, the position of the aromatic cycle or cycles on the alkyl chain or chains of said alkyl-aromatic compound or compounds such that the cetane number of the synthetic gas oil or the additive for gas oil is greater than 30. The invention also relates to a process for the production of alkyl-aromatic compounds for use as a gas oil or additive.

摘要翻译： 本发明涉及一种用于制备瓦斯油的合成瓦斯油或其添加剂的方法，其中烷基芳族化合物或烷基芳族化合物的混合物基于至少一个参数，该参数选自组成 的芳族核心的循环次数，接枝到芳香环的烷基链的数量，烷基链或链的长度，芳族环或在所述烷基链或烷基链的烷基链上的循环的位置， 芳族化合物或化合物，使得合成瓦斯油的十六烷值或瓦斯油的添加剂大于30.本发明还涉及用作瓦斯油或添加剂的烷基 - 芳族化合物的制备方法。

公开(公告)号：US6153805A

公开(公告)日：2000-11-28

申请号：US335896

申请日：1999-06-18

申请人： Anibal Miguel Jose

发明人： Anibal Miguel Jose

IPC分类号： C07C5/10 ,  C07C13/18 ,  C10C5/10 ,  C10G45/44

CPC分类号： C07C13/18 ,  C07C5/10 ,  C07C2101/14 ,  C07C2523/40 ,  C07C2523/74

摘要： A process for the obtention of low impurity cyclohexane content, practically methylcyclopentane (MCP) free, by catalytic hydrogenation of benzene in gas phase in the presence of group VIII metal catalyzers. The catalytic hydrogenation is performed in the presence of ammonia or nitrogenated organic basis as MCP formation inhibitors, being incorporated in a 0.2 to 100 ppm concentration.

摘要翻译： 在VIII族金属催化剂存在下，通过气相催化氢化苯，获得低杂质环己烷含量，实际上是甲基环戊烷（MCP）的方法。 催化氢化在氨或有机碱的存在下进行，作为MCP形成抑制剂，以0.2至100ppm的浓度掺入。

公开(公告)号：US5605907A

公开(公告)日：1997-02-25

申请号：US531201

申请日：1995-09-19

申请人： Yasuhiro Kabasawa ,  Fumihiro Ozaki ,  Keiji Ishibashi ,  Takashi Hasegawa ,  Hitoshi Oinuma ,  Manabu Shirato ,  Katsuhiro Moriya ,  Toshiaki Ogawa ,  Satoshi Katayama ,  Shigeru Souda

发明人： Yasuhiro Kabasawa ,  Fumihiro Ozaki ,  Keiji Ishibashi ,  Takashi Hasegawa ,  Hitoshi Oinuma ,  Manabu Shirato ,  Katsuhiro Moriya ,  Toshiaki Ogawa ,  Satoshi Katayama ,  Shigeru Souda

IPC分类号： C07C13/18 ,  A61K31/015 ,  A61K31/13 ,  A61P21/00 ,  C07C327/46 ,  C07D471/04 ,  C07D521/00 ,  A61K31/435

CPC分类号： C07D231/12 ,  C07D233/56 ,  C07D249/08 ,  C07D471/04

摘要： To provide a novel cyclohexane derivative, a cyclohexane derivative is defined by the formula (I) or a pharmacologically acceptable salt thereof: ##STR1## (wherein R.sup.1 and R.sup.2 may be the same or different from each other and each represents hydrogen or lower alkyl; R.sup.3 represents optionally substituted aryl or optionally substituted heteroaryl; X represents oxygen or sulfur; and Y represents a group represented by the formula: ##STR2## or the like). The compound of the present invention is useful as a preventive and therapeutic agent for diseases against which a potassium channel opening action is efficacious.

摘要翻译： 为了提供新的环己烷衍生物，环己烷衍生物由式（I）或其药理学上可接受的盐定义：其中R 1和R 2可以彼此相同或不同，并且各自表示氢或 低级烷基; R 3表示任选取代的芳基或任选取代的杂芳基; X表示氧或硫; Y表示由下式表示的基团：等等）。 本发明的化合物可用作钾通道开放作用有效的疾病的预防和治疗剂。

公开(公告)号：US5407886A

公开(公告)日：1995-04-18

申请号：US200585

申请日：1994-02-22

申请人： Michael Schneider ,  Karl Kochloefl ,  Gerhardt Maletz

发明人： Michael Schneider ,  Karl Kochloefl ,  Gerhardt Maletz

IPC分类号： B01J23/72 ,  B01J23/70 ,  B01J23/74 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/03 ,  C07C5/10 ,  C07C13/18

CPC分类号： B01J37/031 ,  B01J23/70 ,  B01J35/023 ,  B01J35/10 ,  C07C5/10 ,  B01J35/006 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  C07C2101/14 ,  C07C2521/08 ,  C07C2523/00 ,  C07C2523/755

摘要： A molded catalyst body that contains in a reduced state a metal of the ferrous group and/or copper on a support and is characterized by the following features:(a) Metal content: about 5 to about 40 weight percent, based on the total weight of the catalyst;(b) Metal-crystal size: .ltoreq.3 nm;(c) Volume of the pores with a diameter of 7.5 nm to 15 .mu.m: 0.05 to 0.9 ml/g catalyst;(d) BET surface area: 80-400 m.sup.2 /g catalyst;(e) Fracture strength: >30N (based on cylindrical molded body with a diameter of 1.5 mm and a length of 5 mm);(f) Bulk density: 250-350 g/l.

摘要翻译： 一种模制催化剂体，其在还原状态下含有亚铁基团和/或铜的金属在载体上，其特征在于以下特征：（a）金属含量：约5至约40重量％，基于总重量 的催化剂; （b）金属晶体尺寸： 30N（基于直径为1.5mm，长度为5mm的圆筒形成型体）; （f）体积密度：250-350g / l。

公开(公告)号：US4826799A

公开(公告)日：1989-05-02

申请号：US181357

申请日：1988-04-14

申请人： Wu-Cheng Cheng ,  Christian B. Lundsager ,  Robert M. Spotnitz

发明人： Wu-Cheng Cheng ,  Christian B. Lundsager ,  Robert M. Spotnitz

IPC分类号： B01J25/00 ,  B01J37/00 ,  C07B31/00 ,  C07B61/00 ,  C07C1/00 ,  C07C5/03 ,  C07C5/333 ,  C07C9/14 ,  C07C13/18 ,  C07C15/46 ,  C07C27/00 ,  C07C29/141 ,  C07C29/153 ,  C07C31/04 ,  C07C31/08 ,  C07C67/00 ,  C07C209/00 ,  C07C209/34 ,  C07C209/48 ,  C07C211/03 ,  C22C21/00 ,  B01J25/02

CPC分类号： B01J25/00 ,  B01J37/0018

摘要： Catalysts made by the Raney process (e.g., Raney process nickel) pelletized in matrix of polymer and plasticizer are activated by either (a) removal of plasticizer (e.g., by solvent extraction) followed by leaching out Al with caustic solution, leaving an active catalyst made by the Raney process in a polymer matrix; or (b) removal of plasticizer, then calcining to remove polymer, followed by leaching with caustic. The activated catalyst pellets have sufficient strength and attrition resistance for efficient use in fixed beds and packed columns for superior hydrogenation of toluene, heptene, butyraldehyde, and other conventional feedstockers used with catalysts made by the Raney process.

摘要翻译： 通过（a）去除增塑剂（例如，通过溶剂萃取）然后用苛性碱溶液浸出Al而使通过在聚合物和增塑剂基质中造粒的Raney方法（例如，Raney工艺镍）制成的催化剂被活化，留下活性催化剂 由拉尼法制成的聚合物基体; 或（b）去除增塑剂，然后煅烧以除去聚合物，然后用苛性碱浸出。 活化的催化剂颗粒具有足够的强度和耐磨性，用于固定床和填充柱，用于甲苯，庚烯，丁醛和用于与雷尼法制备的催化剂一起使用的其它常规进料器的优良氢化。

公开(公告)号：US4481375A

公开(公告)日：1984-11-06

申请号：US94795

申请日：1979-11-16

申请人： Philippe Kalk ,  Rene Poilblanc ,  Antoine Gaset

发明人： Philippe Kalk ,  Rene Poilblanc ,  Antoine Gaset

IPC分类号： C10G49/02 ,  B01J31/18 ,  B01J31/22 ,  B01J31/24 ,  C07B61/00 ,  C07C1/00 ,  C07C5/02 ,  C07C7/163 ,  C07C9/14 ,  C07C13/18 ,  C07C45/50 ,  C07C67/00 ,  C07F15/00 ,  C07C45/49

CPC分类号： C07F15/008 ,  B01J31/185 ,  B01J31/226 ,  B01J31/2404 ,  C07C45/50 ,  B01J2231/321 ,  B01J2231/645 ,  B01J2531/822

摘要： The present invention relates to hydrogenation and hydroformylation catalysts based on a binuclear rhodium complex having the formula: ##STR1## wherein X and X' can be the same or different; when X and X' are the same they are organic tertiary phosphite groups and when different X is a CO group and X' is an organic tertiary phosphite group or an aromatic phosphine group, and SY and SY' are thiolato groups. The invention also comprises the processes of hydroformylation and hydrogenation using such catalytic complex.

摘要翻译： 本发明涉及基于具有下式的双核铑络合物的氢化和加氢甲酰化催化剂：其中X和X'可以相同或不同; 当X和X'相同时，它们是有机叔亚磷酸酯基团，当不同的X是CO基团且X'是有机叔亚磷酸酯基团或芳香族膦基团时，SY和SY'是硫醇基团。 本发明还包括使用这种催化复合物的加氢甲酰化和氢化的方法。