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1.发明授权Method for converting cyclic polycarbonate oligomer mixtures to linear polycarbonate, and composition resulting therefrom 失效将环状聚碳酸酯低聚物混合物转化为线性聚碳酸酯的方法，以及由其制得的组合物
公开(公告)号：US4740583A
公开(公告)日：1988-04-26
申请号：US888673
申请日：1986-07-24
申请人： Daniel J. Brunelle , Thomas L. Evans , Michael A. Vallance , Kevin R. Stewart , Thomas G. Shannon , David A. Williams , Dwight J. Patterson , Niles R. Rosenquist , William Hilakos
发明人： Daniel J. Brunelle , Thomas L. Evans , Michael A. Vallance , Kevin R. Stewart , Thomas G. Shannon , David A. Williams , Dwight J. Patterson , Niles R. Rosenquist , William Hilakos
摘要： Cyclic polycarbonate (or thiol analog) oligomer mixtures are prepared by the reaction of bishaloformates or their thio analogs, or mixtures thereof with dihydroxy or dimercapto compounds, with alkali metal hydroxides and various amines. The oligomer mixtures may be converted to polycarbonates or their thiol analogs by a method which is particularly adaptable to integration with polycarbonate processing operations. Polymerization may be conducted simultaneously with molding, extrusion and the like. The oligomer mixtures are adaptable to the preparation of filled prepregs.
摘要翻译： 通过双卤代甲酸酯或其硫代类似物或其与二羟基或二巯基化合物的混合物与碱金属氢氧化物和各种胺的反应制备环状聚碳酸酯（或硫醇类似物）低聚物混合物。 低聚物混合物可以通过特别适用于与聚碳酸酯加工操作整合的方法转化为聚碳酸酯或其硫醇类似物。 聚合可以与成型，挤出等同时进行。 低聚物混合物适用于填充的预浸料的制备。
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2.发明授权
公开(公告)号：US4644053A
公开(公告)日：1987-02-17
申请号：US704122
申请日：1985-02-22
摘要： Cyclic polycarbonate (or thiol analog) oligomer mixtures are prepared by the reaction of bishaloformates or their thio analogs or mixtures thereof with dihydroxy or dimercapto compounds, with alkali metal hydroxides and various amines. The oligomer mixtures may be converted to polycarbonates or their thiol analogs by a method which is particularly adaptable to integration with polycarbonate processing operations.
摘要翻译： 通过双卤代甲酸酯或其硫代类似物或其与二羟基或二巯基化合物的混合物与碱金属氢氧化物和各种胺的反应来制备环状聚碳酸酯（或硫醇类似物）低聚物混合物。 低聚物混合物可以通过特别适用于与聚碳酸酯加工操作整合的方法转化为聚碳酸酯或其硫醇类似物。
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公开(公告)号：US4980453A
公开(公告)日：1990-12-25
申请号：US146154
申请日：1988-01-20
申请人： Daniel J. Brunelle , Thomas L. Guggenheim , James A. Cella , Thomas L. Evans , Luca P. Fontana , Gary R. Faler , James M. Fukuyama , Eugene P. Boden , Jonathan D. Rich , Thomas G. Shannon , Sharon J. McCormick , Philip J. McDermott , Alice M. Colley , Joseph W. Guiles
发明人： Daniel J. Brunelle , Thomas L. Guggenheim , James A. Cella , Thomas L. Evans , Luca P. Fontana , Gary R. Faler , James M. Fukuyama , Eugene P. Boden , Jonathan D. Rich , Thomas G. Shannon , Sharon J. McCormick , Philip J. McDermott , Alice M. Colley , Joseph W. Guiles
CPC分类号： C08G75/23 , C08G64/06 , C08G65/4081
摘要： Macrocyclic oligomers, including polycarbonates, polyesters, polyamides, polyimides, polyetherketones and polyethersulfones, are conveniently prepared from various spiro(bis)indane compounds, especially the 6,6'-difunctional 3,3',3'-tetramethylspiro(bis)indanes. The macrocyclic oligomers may be conveniently converted to linear polymers.
摘要翻译： 大环低聚物，包括聚碳酸酯，聚酯，聚酰胺，聚酰亚胺，聚醚酮和聚醚砜，可以方便地由各种螺（双）二氢化茚化合物，特别是6,6'-二官能3,3'，3'-四甲基螺（双）二氢化茚制备。 大环低聚物可以方便地转化为线性聚合物。
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公开(公告)号：US4736016A
公开(公告)日：1988-04-05
申请号：US887503
申请日：1986-07-21
IPC分类号： C08G64/08 , C08G64/00 , C08G64/02 , C08G64/06 , C08G64/10 , C08G64/16 , C08G64/20 , C08G64/26 , C08G65/40 , C08G75/28 , C08J5/04 , C08G63/62
CPC分类号： C08G64/0208 , C08G64/06 , C08G64/1608 , C08G64/26 , C08G65/4081 , C08G75/28 , C08J5/04 , C08J2369/00
摘要： Cyclic polycarbonate mixtures containing units derived from spirobiindane bisphenols, preferably 6,6'-dihydroxy-3,3,3',3'-tetramethylspirobiindane, are prepared from the corresponding bischloroformates or mixtures thereof with bisphenols. They may be homopolymeric or copolymeric; cyclic oligomer mixtures are preferred. Such oligomers may be converted to linear polycarbonates having high glass transition temperatures.
摘要翻译： 含有衍生自螺二茚满双酚的单元，优选6,6'-二羟基-3,3,3'，3'-四甲基螺二茚满的环状聚碳酸酯混合物由相应的双氯甲酸酯或其与双酚的混合物制备。 它们可以是均聚或共聚的; 环状低聚物混合物是优选的。 这样的低聚物可以转化为具有高玻璃化转变温度的直链聚碳酸酯。
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公开(公告)号：USRE34431E
公开(公告)日：1993-11-02
申请号：US915381
申请日：1992-05-08
申请人： Daniel J. Brunelle , Thomas L. Guggenheim , James A. Cella , Thomas L. Evans , Luca P. Fontana , Gary R. Faler , James M. Fukuyama , Eugene P. Boden , Jonathan D. Rich , Thomas G. Shannon , Sharon J. McCormick , Philip J. McDermott , Alice M. Colley , Joseph W. Guiles
发明人： Daniel J. Brunelle , Thomas L. Guggenheim , James A. Cella , Thomas L. Evans , Luca P. Fontana , Gary R. Faler , James M. Fukuyama , Eugene P. Boden , Jonathan D. Rich , Thomas G. Shannon , Sharon J. McCormick , Philip J. McDermott , Alice M. Colley , Joseph W. Guiles
IPC分类号： C08G63/193 , C08G64/06 , C08G64/18 , C08G65/40 , C08G65/48 , C08G69/26 , C08G73/10 , C08G75/23 , C08G63/00 , C07D231/00 , C07F7/04 , C08G69/42
CPC分类号： C08G63/193 , C08G64/06 , C08G64/183 , C08G65/4081 , C08G65/48 , C08G69/26 , C08G73/10 , C08G75/23
摘要： Macrocyclic oligomers, including polycarbonates, polyesters, polyamides, polyimides, polyetherketones and polyethersulfones, are conveniently prepared from various spiro(bis)indane compounds, especially the 6,6'-difunctional 3,3',3'-tetramethylspiro(bis)indanes. The macrocyclic oligomers may be conveniently converted to linear polymers.
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6.发明授权Preparation of resin composition from cyclic polycarbonate oligomers from spirobiindane bisphenol 失效由螺二茚双酚的环状聚碳酸酯低聚物制备树脂组合物
公开(公告)号：US4775741A
公开(公告)日：1988-10-04
申请号：US59297
申请日：1987-06-08
CPC分类号： C08G64/06 , C08G65/4081
摘要： Cyclic polycarbonate mixtures containing units derived from spirobiindane bisphenols, preferably 6,6'-dihydroxy-3,3,3',3'-tetramethylspirobiindane are prepared from the corresponding bischloroformates or mixtures thereof with bisphenols. They may be homopolymeric or copolymeric; cyclic oligomer mixtures are preferred. Such oligomers may be converted to linear polycarbonates having high glass transition temperatures.
摘要翻译： 含有衍生自螺二茚满双酚的单元的环状聚碳酸酯混合物，优选为6,6'-二羟基-3,3,3'，3'-四甲基螺茚二茚，由相应的双氯甲酸酯或其与双酚的混合物制备。 它们可以是均聚或共聚的; 环状低聚物混合物是优选的。 这样的低聚物可以转化为具有高玻璃化转变温度的直链聚碳酸酯。
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公开(公告)号：US4994595A
公开(公告)日：1991-02-19
申请号：US926685
申请日：1986-11-04
CPC分类号： C07C68/02 , C07C2103/94
摘要： Bischloroformate compositions are prepared from spirobiindane bisphenols by phosgenation in a substantially inert organic liquid in a two-step reaction. The pH during the first step is maintained in the range of about 8-14 by addition of aqueous base. In the second step, the pH is in the range of about 2-6. This method produces compositions containing a substantial amount of monomeric bischloroformate and avoids gelling problems.
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公开(公告)号：US4921975A
公开(公告)日：1990-05-01
申请号：US356156
申请日：1989-05-24
摘要： Cyclic monocarbonate bischloroformates are prepared by the reaction of a carbonyl halide such as phosgene with a bridged substituted resorcinol or hydroquinone such as bis(2,4-dihydroxy-3-methylphenyl)methane or bis(2,5-dihydroxy-3,4,6-trimethylphenyl)methane in the presence of aqueous alkali metal hydroxide. The cyclic monocarbonate bischloroformates may be used for the preparation of linear or cyclic polycarbonates containing cyclic carbonate structural units, which may in turn be converted to crosslinked polycarbonates.
摘要翻译： 通过羰基卤化物如光气与桥连取代的间苯二酚或氢醌例如双（2,4-二羟基-3-甲基苯基）甲烷或双（2,5-二羟基-3,4-二甲基苯基）甲烷的反应制备环状单碳酸酯双氯甲酸酯， 6-三甲基苯基）甲烷在碱金属氢氧化物水溶液存在下进行。 环状单碳酸酯双氯甲酸酯可用于制备含有环状碳酸酯结构单元的线性或环状聚碳酸酯，其可以转化为交联的聚碳酸酯。
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9.发明授权Crosslinkable polycyclic polycarbonate oligomer and methods for their preparation and use 失效可交联的多环聚碳酸酯低聚物及其制备和使用方法
公开(公告)号：US4888411A
公开(公告)日：1989-12-19
申请号：US208515
申请日：1988-06-20
摘要： Polycyclic polycarbonate (or thiol analog) oligomers are prepared from a mixture of at least one bishaloformate with at least one tetraphenol, or thio analogs thereof. Such mixture may also contain at least one dihydroxy or dimercapto compound. The oligomers are formed by the reaction of such mixtures with alkali metal hydroxides and various amines. The polycyclic oligomer mixtures may be converted to crosslinked polycarbonates or their thiol analogs.
摘要翻译： 多环状聚碳酸酯（或硫醇类似物）低聚物由至少一种双卤代甲酸酯与至少一种四酚或其硫代类似物的混合物制备。 这种混合物还可含有至少一种二羟基或二巯基化合物。 低聚物通过这些混合物与碱金属氢氧化物和各种胺的反应而形成。 多环低聚物混合物可以转化为交联聚碳酸酯或其硫醇类似物。
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公开(公告)号：US4814420A
公开(公告)日：1989-03-21
申请号：US125432
申请日：1987-11-25
CPC分类号： C08G64/22
摘要： A method is provided for determining the stoichiometric end point of phosgenation reactions which produce polycarbonates and chloroformates, respectively, by monitoring the rate of heat generated by the reaction mixture per unit of phosgene utilized.
摘要翻译： 提供了一种方法，用于通过监测每单位所用光气的反应混合物产生的热量来分别确定产生聚碳酸酯和氯甲酸酯的光气化反应的化学计算终点。
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