Polyhalide high energy density cells
    2.
    发明授权
    Polyhalide high energy density cells 失效
    多卤素高能密度电池

    公开(公告)号:US3997362A

    公开(公告)日:1976-12-14

    申请号:US621761

    申请日:1975-10-14

    IPC分类号: H01M4/58 H01M6/16 H01M35/02

    CPC分类号: H01M6/16 H01M4/582

    摘要: An improved electrochemical cell comprises an alkali metal anode, a cathode, an oxidant of at least one quaternary ammonium polyhalide salt, and a dipolar aprotic electrolyte containing an ionizable salt of an alkali metal. A specific example includes a lithium anode, a carbon cathode, a tetraalkylammonium tribromide salt and an electrolyte of one mole lithium hexafluoride dissolved in propylene carbonate, which cell provides an open circuit voltage of about 3.6 volts. The oxidant can be incorporated in the cathode structure or be added independently to the cell, e.g., by use of a circulating electrolyte.

    摘要翻译: 改进的电化学电池包括碱金属阳极,阴极,至少一种季铵多卤化物盐的氧化剂和含有碱金属的可电离盐的偶极非质子电解质。 具体实例包括锂阳极,碳阴极,四烷基三溴化铵盐和溶解在碳酸亚丙酯中的1摩尔六氟化锂的电解质,该电池提供约3.6伏的开路电压。 氧化剂可以并入阴极结构中,或者独立地加入到电池中,例如通过使用循环电解质。

    Metal-Halogenelectrochemical cell
    4.
    发明授权
    Metal-Halogenelectrochemical cell 失效
    金属 - 卤化电池

    公开(公告)号:US4064324A

    公开(公告)日:1977-12-20

    申请号:US674584

    申请日:1976-04-07

    申请人: Daniel J. Eustace

    发明人: Daniel J. Eustace

    CPC分类号: H01M10/365

    摘要: An improved metal-halogen electrochemical cell particularly a zinc bromide cell, contains a water soluble organo substituted amino acid salt in the electrolyte which forms a substantially water insoluble liquid complex with cathodic halogen thereby reducing self-discharge of the cell.

    摘要翻译: 改进的金属 - 卤素电化学电池,特别是溴化锌电池,在电解质中含有水溶性有机取代的氨基酸盐,其与阴极卤素形成基本上不溶于水的液体络合物,从而减少电池的自放电。

    Li/TiS.sub.2 Current producing system
    5.
    发明授权
    Li/TiS.sub.2 Current producing system 失效
    Li / TiS2电流生产系统

    公开(公告)号:US4416960A

    公开(公告)日:1983-11-22

    申请号:US184772

    申请日:1980-09-08

    IPC分类号: H01M6/16 H01M10/05 H01M6/14

    CPC分类号: H01M10/05 H01M6/164

    摘要: An improved electrolyte for an Li/TiS.sub.2 current producing system, such as a battery, features at least one lithium solute of the general formula LiXF.sub.a, where X is selected from a group consisting of B, P, Sb, and As, and wherein a is 4 for B and 6 for P, Sb, and As. The solute(s) are supported in a solvent consisting of at least 1,3 dioxolane, and more particularly in a mixture of 1,3 dioxolane (DIOX) and 1,2 dimethoxyethane (DME) ranging in percent ratios of (DIOX:DME) from 100/0 to 40/60 by weight.

    摘要翻译: 用于Li / TiS 2电流产生系统的改进的电解质如电池具有至少一种通式LiXFa的锂溶质,其中X选自由B,P,Sb和As组成的组,其中a B为4,P为Sb,As为6。 溶质在由至少1,3-二氧戊环组成的溶剂中负载,更特别是1,3-二氧戊环(DIOX)和1,2-二甲氧基乙烷(DME)的混合物中,其比例为(DIOX:DME )从100/0至40/60重量比。

    Recovery, manipulation and storage of bromine
    6.
    发明授权
    Recovery, manipulation and storage of bromine 失效
    溴的回收,操作和储存

    公开(公告)号:US4124693A

    公开(公告)日:1978-11-07

    申请号:US833132

    申请日:1977-09-14

    CPC分类号: C01B7/096 B01D53/68

    摘要: An improved method of removing bromine from fluid streams comprises contacting the fluid stream with an aqueous solution of certain asymmetrical quaternary ammonium bromides whereby a liquid, water immiscible bromine complex is formed that can be stored, manipulated and readily handled and which complex can be dissociated to liberate molecular bromine.

    摘要翻译: 从流体流中除去溴的改进方法包括使流体流与某些不对称的季铵溴化物的水溶液接触,由此形成液体,水不混溶的溴络合物,其可以被储存,操纵和容易地处理,并且哪些络合物可以分解成 释放分子溴。

    Metal halogen electrochemical cell
    7.
    发明授权
    Metal halogen electrochemical cell 失效
    金属卤素电化学电池

    公开(公告)号:US4068046A

    公开(公告)日:1978-01-10

    申请号:US792247

    申请日:1977-04-29

    CPC分类号: H01M10/365

    摘要: An improved aqueous metal-halogen electrochemical cell, particularly a zinc bromide cell, contains a water soluble tetraorgano-substituted ammonium salt in the electrolyte which forms a substantially water insoluble liquid complex with cathodic halogen thereby reducing self-discharge of the cell. Particularly preferred as the ammonium salt is N-ethyl, N-methyl morpholinium bromide.

    摘要翻译: 改进的金属 - 卤化物电化学电池,特别是溴化锌电池在电解质中含有水溶性四有机取代的铵盐,其与阴极卤素形成基本上不溶于水的液体络合物,从而减少电池的自放电。 作为铵盐,特别优选N-乙基,N-甲基吗啉鎓溴化物。