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公开(公告)号：US4927869A
公开(公告)日：1990-05-22
申请号：US245099
申请日：1988-09-15
申请人： David E. Dana , Steven J. Morris
发明人： David E. Dana , Steven J. Morris
摘要： Chemically treated glass fibers of the present invention provide good processing properties in reinforcing thermosetting polymers while resulting in fiber reinforced thermosetting materials having good strength properties. The chemically treated glass fibers have a dried residue of an aqueous chemical treating composition having: two film forming polymers, at least an acryloxy alkyl trialkoxysilane, a fiber lubricant and polyester curing agent and water. One film forming polymer is a polyvinylacetate copolymer having a low solubility in acetone and the other film forming polymer is unsaturated, curable, essentially linear polyester polymer. The fiber lubricant is a nonionic polyethylene-containing polymer or a cationic lubricant like polyalkylene polyamine polyamino amide, and partially amidated polyalkylenimines and mixtures thereof present in an effective lubricating amount. The nonionic lubricant may be used and the cationic lubricant is used in conjunction with a fuzz reducing agent such as silylated polyazamide. Additional components which may be present include: an amino organofunctional silane coupling agent, and a polyoxyethylene polymer having a molecular weight in the range of 100,000 to 5 million. The dried residue is present on the fibers in the strand in an amount in the range of around 1.5 to 3 percent LOI. Also, the dried strands have a post treatment with an antistatic agent before the strands are utilized as reinforcement for thermosetting materials.
摘要翻译： 本发明的化学处理玻璃纤维在增强热固性聚合物中提供良好的加工性能，同时产生具有良好强度性能的纤维增强热固性材料。 化学处理的玻璃纤维具有水性化学处理组合物的干燥残余物，其具有两种成膜聚合物，至少丙烯酰氧基烷基三烷氧基硅烷，纤维润滑剂和聚酯固化剂和水。 一种成膜聚合物是在丙酮中溶解度低的聚乙酸乙烯酯共聚物，另一种成膜聚合物是不饱和的，可固化的，基本上为线性的聚酯聚合物。 纤维润滑剂是含有非离子聚乙烯的聚合物或阳离子润滑剂，如聚亚烷基多胺聚氨基酰胺，部分酰胺化的聚亚烷基亚胺及其混合物以有效的润滑量存在。 可以使用非离子润滑剂，并且阳离子润滑剂与绒毛还原剂如甲硅烷基化的叠氮烷一起使用。 可能存在的其它组分包括：氨基有机官能硅烷偶联剂和分子量在100,000至500万范围内的聚氧乙烯聚合物。 干燥的残余物在链中的纤维上以约1.5-3％LOI的量存在。 此外，干燥的股线在用作热固性材料的增强剂之前，使用抗静电剂进行后处理。
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2.发明授权
公开(公告)号：US4808478A
公开(公告)日：1989-02-28
申请号：US904728
申请日：1986-09-05
CPC分类号： C08J5/08 , C03C25/26 , C08K9/08 , Y10T428/2933 , Y10T428/2938 , Y10T428/2962 , Y10T428/2964
摘要： Chemically treated glass fiber reinforcement for thermosetting polymers having a moisture reduced residue of an aqueous chemical treating composition consisting essentially of a vinyl acetate-organosilane copolymer, a vinyl silane coupling agent, an amino-organo silane coupling agent, at least one cationic lubricant, polyoxyethylene, an antistatic agent, an aqueous dispersible or emulsifiable wax with a surfactant and water.
摘要翻译： 用于热塑性聚合物的化学处理玻璃纤维增强剂，其具有基本上由乙酸乙烯酯 - 有机硅烷共聚物，乙烯基硅烷偶联剂，氨基有机硅烷偶联剂，至少一种阳离子润滑剂，聚氧乙烯 抗静电剂，具有表面活性剂和水的水分散性或可乳化蜡。
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3.发明授权Glass fiber strand mats, thermosetting composites reinforced with the same and methods for making the same 失效玻璃纤维丝网，热固性复合材料与其相同的加固方法和制造方法
公开(公告)号：US5908689A
公开(公告)日：1999-06-01
申请号：US787735
申请日：1997-01-24
CPC分类号： B32B5/28 , B29C70/081 , D04H1/498 , D04H3/004 , D04H3/105 , D04H5/02 , D04H5/12 , Y10T442/604 , Y10T442/667 , Y10T442/67 , Y10T442/682
摘要： The present invention provides a mat adapted to reinforce a thermosetting matrix material to form a composite, composites formed therefrom, and methods related thereto. The mat includes a primary, supporting layer having a plurality of randomly oriented essentially continuous glass fiber strands. The primary layer has about 1 to about 10 weight percent of the mat on a total solids basis. The mat also includes a secondary layer positioned upon and supported by a surface of the primary layer, the secondary layer including a plurality of glass fiber strands. The mean average length of the glass fiber strands of the secondary layer ranges from about 20 to about 125 millimeters. The strands of the primary layer are entangled with the strands of the secondary layer by needling the primary layer and the secondary layer together.
摘要翻译： 本发明提供了一种适于加强热固性基质材料以形成复合材料，由其形成的复合材料的垫及其相关方法。 垫包括具有多个随机取向的基本上连续的玻璃纤维束的主要支撑层。 主层在总固体的基础上具有约1至约10重量％的垫。 垫还包括位于主层的表面上并由其支撑的第二层，第二层包括多个玻璃纤维束。 次级层的玻璃纤维束的平均长度范围为约20至约125毫米。 主层的股线通过将主层和次级层一起进行针刺而与次级层的股线缠结。
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公开(公告)号：US5091465A
公开(公告)日：1992-02-25
申请号：US450065
申请日：1989-12-13
IPC分类号： C03C25/10 , C03C25/32 , C08G63/52 , C08G63/676 , C08G63/695 , C08G63/91 , C08J5/08 , C08K9/08 , D06M15/507 , D06M15/555 , D06M101/00
CPC分类号： C08J5/08 , C03C25/323 , C08G63/676 , C08G63/6958 , C08G63/918 , C08K9/08 , C08J2367/06
摘要： Silylated polyester resins comprising the acid salt of a Michael addition adduct of an aminoorganosilane and a conjugated unsaturated polyester resin containing a polyethylene oxide chain segment useful for sizing glass fiber reinforcement of polyester molding composites.
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5.发明授权Aqueous dispersion, internally silylated and dispersed polyurethane resins, and surfaces containing same 失效水分散体，内部甲硅烷基化和分散的聚氨酯树脂，以及含有它们的表面
公开(公告)号：US4567228A
公开(公告)日：1986-01-28
申请号：US612207
申请日：1984-05-21
申请人： Peter C. Gaa , David E. Dana
发明人： Peter C. Gaa , David E. Dana
CPC分类号： C08G18/4833 , C08G18/0804 , C08G18/0823 , C08G18/289 , C08G18/3893
摘要： An aqueous dispersible, isocyanate-containing polymer or prepolymer or chain extended polymer is provided which has internal pendant, reactable silane groups and which can also have internal dispersing aids. The aqueous dispersible, isocyanate-containing polymer, prepolymer, or chain extended polymer produces an aqueous dispersion of a polyurethane polymer having pendant reactable siliconate anions. The isocyanate-containing polymer is prepared from polyisocyanates, organic compounds with at least 2 active hydrogens, and organosilane which is at least monofunctional in reaction with isocyanate groups on at least one organic moiety of the organosilane. The organosilane also may have hydrolyzed or hydrolyzable groups associated with the silicone atom. The prepolymer is formed at temperatures less than 200.degree. C. at atmospheric pressure in a one shot or two step process. The polymer is combined with water to form an oil-in-water dispersion, and, if it is a prepolymer, the molecular weight is increased through chain extension. The pH of the aqueous dispersion of the polyurethane is maintained at least around 7 when the silyl concentration of the polymer is greater than 0.1 weight percent of the water in the dispersion. The aqueous dispersion can also be prepared from a prepolymer that is devoid of any organosilane used as a comonomer and where the prepolymer is dispersed and chain-extended with the difunctional organo silane. The aqueous dispersion of the polyurethane resin is used in coating myriad substrates such as inorganic oxide substrates.
摘要翻译： 提供含水分散的，含异氰酸酯的聚合物或预聚物或链延长的聚合物，其具有内部侧链，可反应的硅烷基团，并且还可以具有内部分散助剂。 含水分散的含异氰酸酯的聚合物，预聚物或链延长的聚合物产生具有侧链可反应的硅酸盐阴离子的聚氨酯聚合物的水分散体。 含异氰酸酯的聚合物由多异氰酸酯，具有至少2个活性氢的有机化合物和与有机硅烷的至少一个有机部分上的异氰酸酯基团反应至少单官能的有机硅烷制备。 有机硅烷还可以具有与硅氧烷原子相关的水解或可水解的基团。 预聚物在大气压下以一步或两步的方式在低于200℃的温度下形成。 将聚合物与水结合以形成水包油分散体，如果是预聚物，则分子量通过链延长而增加。 当聚合物的甲硅烷基浓度大于分散体中的水的0.1重量％时，聚氨酯的水分散体的pH保持在至少约7。 水分散体也可以由没有用作共聚单体的任何有机硅烷的预聚物制备，并且预聚物用双功能有机硅烷分散和链延长。 聚氨酯树脂的水性分散体用于涂覆无数的基材如无机氧化物基材。
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公开(公告)号：US5032455A
公开(公告)日：1991-07-16
申请号：US586917
申请日：1990-09-24
IPC分类号： C08F8/12 , C08F230/08
CPC分类号： C08F230/08 , C08F8/42 , C08J5/18 , C08F2810/20 , C08F2810/50 , Y10T428/2967 , Y10T428/31612 , Y10T428/31645
摘要： Addition interpolymers with pendant ionic moieties and pendant reactable silane moieties are prepared by addition polymerization of ethylenically unsaturated monomers having ionic moieties with organofunctional silane compounds having ethylenic unsaturation in the organofunctional moiety of the silane where the silane also has reactable alkoxy and/or hydroxy group. The addition polymerization is performed in the presence of a free radical initiator at an elevated temperature up to around 90.degree. C. and in a nonoxidizing atmosphere. The amount of the ionic monomer is effective to result in the interpolymer having at least water dispersibility and most suitably water emulsifiability and the amount of the silane monomer is in the range of about 1 to about 15 weight percent of the interpolymer. The interpolymer may be prepared with one or more additional ethylenically unsaturated monomers where the amount does not decrease the ionic character of the interpolymer below that which renders the interpolymer water emulsifiable.
摘要翻译： 具有侧离子部分和侧链可反应硅烷部分的加成互聚物通过在硅烷的有机官能部分中具有离子部分的具有烯属不饱和键的有机官能硅烷化合物加成聚合来制备，其中硅烷还具有可反应的烷氧基和/或羟基。 加成聚合在自由基引发剂的存在下，在高达约90℃的高温和非氧化气氛下进行。 离子单体的量有效地导致互聚物具有至少水分散性和最合适的水乳化性，并且硅烷单体的量在互聚物的约1至约15重量％的范围内。 互聚物可以用一种或多种另外的烯键式不饱和单体制备，其中该量不降低互聚物的离子特性，使得互聚物水可乳化。
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公开(公告)号：US4983699A
公开(公告)日：1991-01-08
申请号：US292859
申请日：1989-01-03
IPC分类号： C08F8/12 , C08F20/52 , C08F30/08 , C08F212/00 , C08F212/08 , C08F220/58 , C08F230/08 , C08K7/14
CPC分类号： C08F230/08 , C08F8/42 , C08J5/18 , C08J7/14
摘要： Addition interpolymers with pendant ionic moieties and pendant reactable silane moieties are prepared by addition polymerization of ethylenically unsaturated monomers having ionic moieties with organofunctional silane compounds having ethylenic unsaturation in the organofunctional moiety of the silane where the silane also has a reactable alkoxy and/or hydroxy groups. The addition polymerization is performed in the presence of a free radical initiator at an elevated temperature up to around 90.degree. C. and in a nonoxidizing atmosphere. The amount of the ionic monomer is effective to result in the interpolymer having at least water dispersibility and most suitably water emulsifiability and the amount of the silane monomer is in the range of about 1 to about 15 weight percent of the interpolymer. The interpolymer may be prepared with one or more additional ethylenically unsaturated monomers where the amount does not decrease the ionic character of the interpolymer below that which renders the interpolymer water emulsifiable.
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8.发明授权Process for producing aqueous dispersions, internally silylated and dispersed polyurethane resins, and surfaces containing same 失效生产水性分散体，内部甲硅烷基化和分散的聚氨酯树脂的方法和含有它们的表面的方法
公开(公告)号：US4582873A
公开(公告)日：1986-04-15
申请号：US612116
申请日：1984-05-21
申请人： Peter C. Gaa , David E. Dana
发明人： Peter C. Gaa , David E. Dana
CPC分类号： C08G18/4833 , C08G18/0804 , C08G18/0823 , C08G18/289 , C08G18/3893 , Y10T428/31663
摘要： A process is provided for making an aqueous dispersible, polyurethane or poly(urethane-urea) polymer which has internal pendant, siliconate anions. The aqueous dispersion is prepared from a reaction product of polyisocyanates, organic compounds with at least 2 active hydrogens, and organosilane which is at least monofunctional in reaction with isocyanate groups on at least one organic moiety of the organo silane and also has at least one hydrolyzed or hydrolyzable groups associated with the silicone atom. Optionally, a hydrophilic additive may also be a comonomer in preparing the reaction product. The polymeric reaction product is formed at temperatures less than 200.degree. C. at atmospheric pressure. The polymeric reaction product is combined with water to form an oil-in-water dispersion and the pH of the aqueous dispersion is maintained at least about 7, when the silyl concentration on the reaction product is at least about 0.1 weight percent based on the water in the dispersion. The polymer can be a prepolymer that is chain extended in the aqueous dispersion. The aqueous dispersion can also be prepared from a prepolymer that is devoid of any organosilane used as a comonomer but where the prepolymer is dispersed and chain-extended with an organosilane that is difunctional in the isocyanate polyaddition reaction. The aqueous dispersion of the polyurethane resin is used in coating myriad substrates such as inorganic oxide substrates.
摘要翻译： 提供了一种制备具有内部侧链，硅酸盐阴离子的水分散性，聚氨酯或聚（氨基甲酸酯 - 脲）聚合物的方法。 水分散体由多异氰酸酯，至少有2个活性氢的有机化合物与有机硅烷的至少一个有机部分上的异氰酸酯基反应至少单官能的有机硅烷的反应产物制备，并且还具有至少一个水解的 或与硅氧烷原子相关的可水解基团。 任选地，在制备反应产物时亲水性添加剂也可以是共聚单体。 聚合反应产物在大气压下在低于200℃的温度下形成。 将聚合反应产物与水混合以形成水包油分散体，当反应产物上的甲硅烷基浓度为至少约0.1重量％时，水分散体的pH值保持在至少约7 在分散。 聚合物可以是在水分散体中链延伸的预聚物。 水分散体也可以由没有任何有机硅烷用作共聚单体的预聚物制备，但预聚物在异氰酸酯加聚反应中用双官能的有机硅烷分散和链延长。 聚氨酯树脂的水性分散体用于涂覆无数的基材如无机氧化物基材。
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