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    Cocatalysts for metallocene-based olefin polymerization catalyst systems
    4.
    发明授权
    Cocatalysts for metallocene-based olefin polymerization catalyst systems 失效
    用于茂金属的烯烃聚合催化剂体系的助催化剂

    公开(公告)号：US06245705B1

    公开(公告)日：2001-06-12

    申请号：US08786014

    申请日：1997-01-21

    申请人： Yury V. Kissin

    发明人： Yury V. Kissin

    IPC分类号： B01J3100

    CPC分类号： B01J31/143 ,  B01J21/08 ,  B01J31/1616 ,  B01J31/2295 ,  B01J31/26 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65922 ,  C08F10/00 ,  C08F210/16 ,  Y10S526/943 ,  C08F210/14 ,  C08F2500/12

    摘要： The invention relates to unsupported or supported catalyst compositions for alpha-olefin (ethylene and/or propylene) polymerization which comprises (1) a metallocene compound, (2) an inorganic aluminum compound Al(OH)xOy, wherein x is a number from 0 to 3, wherein x+2 y=3, (3) trimethylaluminum, wherein Al(OH)xOy is used in an amount sufficient to provide an Al(OH)xOy:metallocene molar ratio of 5 to 10,000, wherein trimethylaluminum is used in an amount sufficient to provide a trimethylaluminum:metallocene molar ratio of 50 to 10,000, and wherein the two aluminum compounds, (2) and (3), are used in amounts to provide a molar ratio of trimethylaluminum to Al(OH)xOy in the range of from 0.1 to 100.

    摘要翻译： 本发明涉及用于α-烯烃（乙烯和/或丙烯）聚合的未负载或负载的催化剂组合物，其包含（1）茂金属化合物，（2）无机铝化合物Al（OH）x O y，其中x是0 至3，其中x + 2y = 3，（3）三甲基铝，其中Al（OH）x O y的用量足以提供Al至（OH）xOy：茂金属摩尔比为5至10,000，其中三甲基铝用于 足以提供三甲基铝：金属茂摩尔比为50至10,000的量，并且其中两种铝化合物（2）和（3）中的两种铝化合物的用量可提供三甲基铝与Al（OH）x O y的摩尔比在该范围内 为0.1〜100。

    Multi-component catalyst systems for olefin polymerization
    5.
    发明授权
    Multi-component catalyst systems for olefin polymerization 失效
    用于烯烃聚合的多组分催化剂体系

    公开(公告)号：US5869585A

    公开(公告)日：1999-02-09

    申请号：US550258

    申请日：1995-10-30

    申请人： Robert I. Mink ,  Yury V. Kissin

    发明人： Robert I. Mink ,  Yury V. Kissin

    IPC分类号： C08F4/18 ,  C08F4/646 ,  C08F10/00 ,  C08F210/16

    CPC分类号： C08F10/00 ,  C08F210/16

    摘要： Multi-component catalyst systems for polymerization and copolymerization of olefins consist of at least one transition metal complex containing a multidentate ligand and a three-component cocatalyst. The transition metal complexes with bidentate ligands L have empirical formulasLMX.sub.2, LMXY or L.sub.2 Mwhere M is Ti, V, Zr or Hf atom; X is an alkoxy group, an aryloxy group, or a halogen atom; Y is a mono- or double-bonded ligand different from X. Complexes with tridentate ligands L' have empirical formulas L'MX where M is Ti, V, Zr or Hf; X is an alkoxy group, an aryloxy group, or a halogen atom. Examples of L and L' are alkyldioxy, alkyldiamino, alkyldicarboxy, biaryldioxy, or alkylaminodioxy ligands; particular examples of X are the isopropoxy group or Cl; a particular example of Y is an oxygen atom. The preferred substitution types in the multidentate ligands L and L' are such which afford their unimpeded coordination to the metal atom M in tri-, tetra- or pentacoordinated complexes. The transition metal complexes can be used in pure state or supported on an inert carrier.

    摘要翻译： 用于烯烃聚合和共聚的多组分催化剂体系由至少一种含有多齿配体和三组分助催化剂的过渡金属络合物组成。 具有二齿配位体L的过渡金属络合物具有经验式L MX2，LMXY或L2M，其中M为Ti，V，Zr或Hf原子; X是烷氧基，芳氧基或卤素原子; Y是不同于X的单键或双键配体。具有三齿配体L'的络合物具有经验公式L'MX，其中M是Ti，V，Zr或Hf; X是烷氧基，芳氧基或卤素原子。 L和L'的实例是烷基二氧基，烷基二氨基，烷基二羧基，联芳基二氧基或烷基氨基氧基配体; X的具体实例是异丙氧基或Cl; Y的具体实例是氧原子。 在多齿配位体L和L'中优选的取代类型是这样的，它们在三，四或五配位络合物中提供了与金属原子M无阻碍的配位。 过渡金属络合物可以以纯态使用或负载在惰性载体上。

    Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution
    8.
    发明授权
    Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution 失效
    用于乙烯聚合反应的双金属催化剂具有均匀的组分分布

    公开(公告)号：US06486089B1

    公开(公告)日：2002-11-26

    申请号：US08555816

    申请日：1995-11-09

    申请人： Yury V. Kissin ,  Robert I. Mink ,  Thomas E. Nowlin ,  Pradeep P. Shirodkar ,  Sandra D. Schregenberger ,  Grace O. Tsien

    发明人： Yury V. Kissin ,  Robert I. Mink ,  Thomas E. Nowlin ,  Pradeep P. Shirodkar ,  Sandra D. Schregenberger ,  Grace O. Tsien

    IPC分类号： C08F402

    CPC分类号： B01J31/1616 ,  B01J31/122 ,  B01J31/143 ,  B01J31/2295 ,  B01J37/0203 ,  B01J37/0205 ,  B01J2531/48 ,  C08F4/61904 ,  C08F4/61912 ,  C08F4/61916 ,  C08F10/00 ,  Y10S526/943

    摘要： The invention relates to a process for uniformly dispersing a transition metal metallocene complex on a carrier comprising (1) providing silica which is porous and has a particle size of 1 to 250 microns, having pores which have an average diameter of 50 to 500 Angstroms and having a pore volume of 0.5 to 5.0 cc/g; (2) slurrying the silica in an aliphatic solvent having a boiling point less than 110° C.; (3) providing a volume of a solution comprising metallocene and alumoxane wherein the volume of solution is less than that required to form a slurry of the silica, wherein the concentration of alumoxane, expressed as Al weight percent, is 5 to 20; (4) contacting the silica slurry (2) with said volume of said solution (3) and allowing the solution to impregnate the pores of silica and, to disperse the metallocene in and on the carrier; (5) evaporating the solvents from the contacted and impregnated silica to recover dry free-flowing catalyst particles.

    摘要翻译： 本发明涉及一种将过渡金属茂金属络合物均匀分散在载体上的方法，包括（1）提供多孔的，具有1至250微米的粒径的二氧化硅，具有平均直径为50至500埃的孔， 孔体积为0.5-5.0cc / g;（2）将二氧化硅在沸点小于110℃的脂族溶剂中制浆;（3）提供体积的包含茂金属和铝氧烷的溶液，其中体积为 溶液小于形成二氧化硅浆料所需的溶液，其中铝氧烷的浓度以Al重量百分比表示为5至20; （4）使二氧化硅浆料（2）与所述体积的所述溶液（3）接触，并使所述溶液浸渍二氧化硅的孔隙，并将所述茂金属分散在所述载体上和载体上; （5）从接触和浸渍的二氧化硅蒸发溶剂以回收干燥的自由流动的催化剂颗粒。

    Olefin polymerization catalyst system
    9.
    发明授权
    Olefin polymerization catalyst system 失效
    烯烃聚合催化剂体系

    公开(公告)号：US5506184A

    公开(公告)日：1996-04-09

    申请号：US264206

    申请日：1994-06-22

    申请人： Yury V. Kissin ,  Robert I. Mink

    发明人： Yury V. Kissin ,  Robert I. Mink

    IPC分类号： B01J31/22 ,  B01J31/12 ,  B01J31/14 ,  B01J31/16 ,  C08F4/625 ,  C08F4/631 ,  C08F4/642 ,  C08F10/00 ,  B01J31/38

    CPC分类号： C08F10/00 ,  B01J31/122 ,  B01J31/128 ,  B01J31/143 ,  B01J31/16 ,  B01J31/182 ,  B01J31/223 ,  B01J31/2243 ,  B01J2231/12 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  B01J2531/56 ,  C08F2410/04

    摘要： A catalyst composition for olefin polymerization and copolymerization which contains a transition metal complex with a bidentate or a tridentate ligand and a cocatalyst mixture containing dialkylaluminum halide and dialkylmagnesium.The transition metal complexes with bidentate ligands L have the empirical formula LMX.sub.2, LMXY or L.sub.2 M where M is Ti, V, Zr or Hf; X is an alkoxy group, an aryloxy group, or a halogen atom; Y is a mono- or double-bonded ligand different from X.The bidentate L ligands are described by general formulasZ--R--Z OR Z--R--W--R--Zwhere R is an alkylene group, a cycloalkylene group, an arylene group (unsubstituted or alkyl-substituted) or an alkylarylene group; W is CH.sub.2, O, S, N--R', or SiR'.sub.2 where R' is an alkyl or an aryl group; and Z is an oxygen atom, a sulfur atom, an N--H group or a C(.dbd.O)--O group.The transition metal complexes with tridentate ligands L' have the empirical formula L'MX where M is Ti, V, Zr or Hf; X is an alkoxy group, an aryloxy group, or a halogen atom.The tridentate L' ligands are described by general formulas ##STR1## where R is an alkylene group or an arylene group; and Z and U are different and are an oxygen atom, a sulfur atom, an N--H group or a C(.dbd.O)--O-- group.

    摘要翻译： 用于烯烃聚合和共聚的催化剂组合物，其包含与二齿配位体或三齿配位体的过渡金属络合物和含有二烷基卤化铝和二烷基镁的助催化剂混合物。 具有二齿配位体L的过渡金属络合物具有经验式LMX2，LMXY或L2M，其中M为Ti，V，Zr或Hf; X是烷氧基，芳氧基或卤素原子; Y是与X不同的单键或双键配体。双齿配体L由通式ZRZ或ZRWRZ描述，其中R是亚烷基，亚环烷基，亚芳基（未取代或烷基取代的）或烷基亚芳基 组; W是CH 2，O，S，N-R'或SiR'2，其中R'是烷基或芳基; Z为氧原子，硫原子，N-H基或C（= O）-O基。 具有三齿配体L'的过渡金属络合物具有经验公式L'MX，其中M是Ti，V，Zr或Hf; X是烷氧基，芳氧基或卤素原子。 三齿L'配体由通式“IMAGE”描述，其中R是亚烷基或亚芳基; Z和U不同，为氧原子，硫原子，N-H基或C（= O）-O-基。

    Catalyst systems for syndiospecific polymerization of styrenes
    10.
    发明授权
    Catalyst systems for syndiospecific polymerization of styrenes 失效
    用于苯乙烯间同立构聚合的催化剂体系

    公开(公告)号：US5326837A

    公开(公告)日：1994-07-05

    申请号：US979693

    申请日：1992-11-20

    申请人： Yury V. Kissin

    发明人： Yury V. Kissin

    IPC分类号： C08F4/622 ,  C08F12/08

    CPC分类号： C08F12/08 ,  C08F2410/01 ,  C08F4/6592 ,  Y10S526/943

    摘要： Syndiotactic polystyrene is produced in the presence of a catalyst comprising:(i) trimethylaluminum,(ii) at least one of the organotin compounds with general formulae:R.sub.1 R.sub.2 R.sub.3 Sn--O--SnR.sub.4 R.sub.5 R.sub.6or R.sub.1 R.sub.2 R.sub.3 Sn--OHor R.sub.1 R.sub.2 SnOor R.sub.1 Sn(O)OH; wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are the same or different C.sub.1 -C.sub.20 alkyl groups or aryl groups or alkylaryl groups,(iii) one or several derivatives of transition metals having the formula Cp.sub.n MA.sub.m-n, wherein M is a metal selected from the group of titanium, zirconium and hafnium, Cp is a cyclopentadienyl or a substituted cyclopentadienyl group; n is 0, 1 or 2; m is 4 or 3; and A is selected from the group consisting of a halogen, hydrogen, or an oxyhydrocarbyl group OR', wherein R' is a C.sub.1 -C.sub.6 linear or branched alkyl group, a substituted or non-substituted aryl group, or an arylalkyl group.

    摘要翻译： 间同立构聚苯乙烯在催化剂的存在下生产，包括：（i）三甲基铝，（ii）至少一种具有以下通式的有机锡化合物：R1R2R3Sn-O-SnR4R5R6或R1R2R3Sn-OH或R1R2SnO或R1Sn（O）OH; 其中R 1，R 2，R 3，R 4，R 5和R 6是相同或不同的C 1 -C 20烷基或芳基或烷基芳基，（iii）一种或几种具有式CpnMAm-n的过渡金属衍生物，其中M是金属 选自钛，锆和铪组，Cp是环戊二烯基或取代的环戊二烯基; n为0,1或2; m为4或3; 并且A选自卤素，氢或羟基烃基OR'，其中R'为C1-C6直链或支链烷基，取代或未取代的芳基或芳基烷基。