摘要:
In a process for quench-cooled, vapor-phase polymerization of olefin monomer comprising (a) contacting an olefin monomer, or mixture of olefin monomers, with a polymerization catalyst in the presence of hydrogen in a reactor vessel to form polymer product, and (b) removing, condensing and recycling off-gas from such reactor, an improvement comprises separating entrained polymerizing solid fines from said off-gas and recycling such solids directly to the reactor without substantial continued polymerization of such solids while in the presence of a substantially different concentration of hydrogen than in the reactor.
摘要:
This invention relates to an apparatus and process for feeding powder or dry solids catalyst into a flowing liquid stream. More particularly, the invention includes an apparatus which includes a novel purging device and means for isolating a metering means from a liquid stream, and process for injecting finely divided flowable powder or catalyst into a flowing liquid stream, which in turn is fed into a reactor utilized for the production of polypropylene or polyolefins.
摘要:
In a gas phase olefin polymerization using a transition metal compound/aluminum alkyl catalyst system, polymerization can be terminated rapidly by injecting an amount of carbon oxide and then restarting efficiently by addition of an amount of aluminum alkyl.