公开(公告)号：US20100298475A1

公开(公告)日：2010-11-25

申请号：US12747108

申请日：2009-01-08

申请人： David R. Wilson ,  Ravi B. Shankar ,  Ashwin R. Bharadwaj ,  Bruce A. King

发明人： David R. Wilson ,  Ravi B. Shankar ,  Ashwin R. Bharadwaj ,  Bruce A. King

IPC分类号： C08K5/5317

CPC分类号： C08L69/005 ,  C08K5/5357 ,  C08L9/06 ,  C08L25/02 ,  C08L27/12 ,  C08L51/04 ,  C08L55/02 ,  C08L69/00 ,  C08L2666/02

摘要： The present invention relates to flame resistance additives for organic polymers, and in particular polyphosphonate-type flame resistance additives in a polycarbonate or a polyester carbonate and/or in blends of polycarbonate or a polyester carbonate with an acrylonitrile, butadiene, and styrene terpolymer. The aromatic polyphosphonate compounds of the present invention are represented by the structure, wherein a and b are each from 0 to 6, with a+b being from 2 to 6, each R is independently hydrogen, unsubstituted or inertly substituted alkyl having up to 6 carbon atoms, —NO2, —NR12, —C≡N, —OR1, —C(O)OR1, or —C(O)NR12 (wherein R1 is hydrocarbyl or hydrogen), each R2 is independently hydrogen, alkyl or inertly substituted alkyl, each R3 is a covalent bond or a divalent linking group, and each R4 is independently an alkyl, aryl, inertly substituted alkyl or inertly substituted aryl group.

摘要翻译： 本发明涉及有机聚合物的阻燃添加剂，特别是聚碳酸酯或聚酯碳酸酯中的/或聚碳酸酯或聚碳酸酯与丙烯腈，丁二烯和苯乙烯三元共聚物的共混物中的聚磷酸酯型阻燃添加剂。 本发明的芳族聚膦酸酯化合物由结构表示，其中a和b各自为0至6，其中+ b为2-6，每个R独立地为氢，未取代或惰性取代的烷基，其具有至多6个 碳原子，-NO 2，-NR 12，-C≡N，-OR 1，-C（O）OR 1或-C（O）NR 12（其中R 1是烃基或氢），每个R 2独立地是氢，烷基或惰性取代的 烷基，每个R 3是共价键或二价连接基团，并且每个R 4独立地是烷基，芳基，惰性取代的烷基或惰性取代的芳基。

公开(公告)号：US08058332B2

公开(公告)日：2011-11-15

申请号：US12906203

申请日：2010-10-18

申请人： Ravi B. Shankar ,  David R. Wilson ,  William J. Kruper ,  Bruce A. King ,  Michelle L. Hudack ,  Chun Wang ,  Ted A. Morgan ,  Inken Beulich ,  Daniel J. Murray ,  William Gerald Stobby ,  Mark W. Beach ,  Ing Feng Hu

发明人： Ravi B. Shankar ,  David R. Wilson ,  William J. Kruper ,  Bruce A. King ,  Michelle L. Hudack ,  Chun Wang ,  Ted A. Morgan ,  Inken Beulich ,  Daniel J. Murray ,  William Gerald Stobby ,  Mark W. Beach ,  Ing Feng Hu

IPC分类号： C07F9/6574 ,  C07F9/02 ,  C08K5/49 ,  C08J9/32

CPC分类号： C07F9/1653 ,  C07F9/173 ,  C07F9/657136 ,  C07F9/657154 ,  C07F9/657181 ,  C08K5/5398

摘要： Phosphorus-sulfur compounds have flame retardant activity in organic polymer systems. The phosphorus-sulfur compounds can be represented by the structure: wherein X is oxygen or sulfur, T is a covalent bond, oxygen, sulfur or nitrogen, provided that at least one of X and T is sulfur, each X′ is independently oxygen or sulfur, each m is independently zero or 1 when X′ is oxygen and zero, 1 or 2 when X′ is sulfur, n is at least 1 and preferably at least 2, each R is independently an unsubstituted or inertly substituted hydrocarbyl group or the R groups together form an unsubstituted or inertly substituted divalent organic group and A is an organic linking group.

摘要翻译： 磷 - 硫化合物在有机聚合物体系中具有阻燃活性。 磷硫化合物可以由以下结构表示：其中X是氧或硫，T是共价键，氧，硫或氮，条件是X和T中的至少一个是硫，每个X'独立地是氧或 硫，当X'为氧时，每个m独立为0或1，当X'为硫时为0,1或2，n为至少1，优选为至少2，每个R独立地为未取代或惰性取代的烃基或 R基团一起形成未取代或惰性取代的二价有机基团，A是有机连接基团。

公开(公告)号：US20110034573A1

公开(公告)日：2011-02-10

申请号：US12906203

申请日：2010-10-18

申请人： Ravi B. Shankar ,  David R. Wilson ,  William J. Kruper ,  Bruce A. King ,  Michelle L. Hudack ,  Chun Wang ,  Ted A. Morgan ,  Inken Beulich ,  Daniel J. Murray ,  William Gerald Stobby ,  Mark W. Beach ,  Ing Feng Hu

发明人： Ravi B. Shankar ,  David R. Wilson ,  William J. Kruper ,  Bruce A. King ,  Michelle L. Hudack ,  Chun Wang ,  Ted A. Morgan ,  Inken Beulich ,  Daniel J. Murray ,  William Gerald Stobby ,  Mark W. Beach ,  Ing Feng Hu

IPC分类号： C08J9/00 ,  C08K5/5398 ,  C07F9/06 ,  C08K5/3462

CPC分类号： C07F9/1653 ,  C07F9/173 ,  C07F9/657136 ,  C07F9/657154 ,  C07F9/657181 ,  C08K5/5398

摘要： Phosphorus-sulfur compounds have flame retardant activity in organic polymer systems. The phosphorus-sulfur compounds can be represented by the structure: wherein X is oxygen or sulfur, T is a covalent bond, oxygen, sulfur or nitrogen, provided that at least one of X and T is sulfur, each X′ is independently oxygen or sulfur, each m is independently zero or 1 when X′ is oxygen and zero, 1 or 2 when X′ is sulfur, n is at least 1 and preferably at least 2, each R is independently an unsubstituted or inertly substituted hydrocarbyl group or the R groups together form an unsubstituted or inertly substituted divalent organic group and A is an organic linking group.

摘要翻译： 磷 - 硫化合物在有机聚合物体系中具有阻燃活性。 磷硫化合物可以由以下结构表示：其中X是氧或硫，T是共价键，氧，硫或氮，条件是X和T中的至少一个是硫，每个X'独立地是氧或 硫，当X'为氧时，每个m独立为0或1，当X'为硫时为0,1或2，n为至少1，优选为至少2，每个R独立地为未取代或惰性取代的烃基或 R基团一起形成未取代或惰性取代的二价有机基团，A是有机连接基团。

公开(公告)号：US20080153950A1

公开(公告)日：2008-06-26

申请号：US12004345

申请日：2007-12-20

申请人： Ravi B. Shankar ,  William J. Kruper ,  David R. Wilson ,  Bruce A. King ,  Michelle L. Hudack ,  Daniel J. Murray ,  Chun Wang ,  William Gerald Stobby ,  Ted A. Morgan ,  Mark W. Beach ,  Inken Beulich ,  Ing Feng Hu

发明人： Ravi B. Shankar ,  William J. Kruper ,  David R. Wilson ,  Bruce A. King ,  Michelle L. Hudack ,  Daniel J. Murray ,  Chun Wang ,  William Gerald Stobby ,  Ted A. Morgan ,  Mark W. Beach ,  Inken Beulich ,  Ing Feng Hu

IPC分类号： C08K5/5398 ,  C08K5/51 ,  C07F9/6571

CPC分类号： C07F9/1653 ,  C07F9/173 ,  C07F9/657136 ,  C07F9/657154 ,  C07F9/657181 ,  C08K5/5398

摘要： Phosphorus-sulfur compounds have flame retardant activity in organic polymer systems. The phosphorus-sulfur compounds can be represented by the structure: wherein X is oxygen or sulfur, T is a covalent bond, oxygen, sulfur or nitrogen, provided that at least one of X and T is sulfur, each X′ is independently oxygen or sulfur, each m is independently zero or 1 when X′ is oxygen and zero, 1 or 2 when X′ is sulfur, n is at least 1 and preferably at least 2, each R is independently an unsubstituted or inertly substituted hydrocarbyl group or the R groups together form an unsubstituted or inertly substituted divalent organic group and A is an organic linking group.

摘要翻译： 磷 - 硫化合物在有机聚合物体系中具有阻燃活性。 磷硫化合物可以由以下结构表示：其中X是氧或硫，T是共价键，氧，硫或氮，条件是X和T中的至少一个是硫，每个X'独立地是氧或 硫，当X'为氧时，每个m独立为0或1，当X'为硫时为0,1或2，n为至少1，优选为至少2，每个R独立地为未取代或惰性取代的烃基或 R基团一起形成未取代或惰性取代的二价有机基团，A是有机连接基团。

公开(公告)号：US09472813B2

公开(公告)日：2016-10-18

申请号：US13990387

申请日：2011-12-13

申请人： Oktay Uzun ,  Dean M. Welsh ,  David R. Wilson ,  Ravi B. Shankar ,  David J. Brennan

发明人： Oktay Uzun ,  Dean M. Welsh ,  David R. Wilson ,  Ravi B. Shankar ,  David J. Brennan

IPC分类号： H01M10/056 ,  H01M6/16 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569

CPC分类号： H01M6/164 ,  H01M10/052 ,  H01M10/056 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0025 ,  Y02E60/122 ,  Y02T10/7011

摘要： Battery electrolyte solutions contain certain ester solvents, a lithium salt and vinylene carbonate, vinyl ethylene carbonate or fluoroethylene carbonate. Batteries containing these solvents have excellent specific discharge capacities and reduced weight compared to batteries in which the electrolyte is based on ethylene carbonate.

摘要翻译： 电池电解质溶液含有某些酯溶剂，锂盐和碳酸亚乙烯酯，乙烯基碳酸亚乙酯或氟代碳酸亚乙酯。 含有这些溶剂的电池与电解质基于碳酸亚乙酯的电池相比具有优异的比放电容量和重量。

公开(公告)号：US20130260229A1

公开(公告)日：2013-10-03

申请号：US13990387

申请日：2011-12-13

申请人： Oktay Uzun ,  Dean M. Welsh ,  David R. Wilson ,  Ravi B. Shankar ,  David J. Brennan

发明人： Oktay Uzun ,  Dean M. Welsh ,  David R. Wilson ,  Ravi B. Shankar ,  David J. Brennan

IPC分类号： H01M6/16 ,  H01M10/056

CPC分类号： H01M6/164 ,  H01M10/052 ,  H01M10/056 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0025 ,  Y02E60/122 ,  Y02T10/7011

摘要： Battery electrolyte solutions contain certain ester solvents, a lithium salt and vinylene carbonate, vinyl ethylene carbonate or fluoroethylene carbonate. Batteries containing these solvents have excellent specific discharge capacities and reduced weight compared to batteries in which the electrolyte is based on ethylene carbonate.

摘要翻译： 电池电解质溶液含有某些酯溶剂，锂盐和碳酸亚乙烯酯，乙烯基碳酸亚乙酯或氟代碳酸亚乙酯。 含有这些溶剂的电池与电解质基于碳酸亚乙酯的电池相比具有优异的比放电容量和重量。

公开(公告)号：US20110250503A1

公开(公告)日：2011-10-13

申请号：US13132374

申请日：2009-11-16

申请人： David R. Wilson ,  Ravi B. Shankar ,  Houxiang Tang ,  Andrew J. Pasztor, JR. ,  Peter M. Margl ,  William J. Kruper, JR. ,  Mark D. Newsham ,  Jing Jin ,  Matthew M. Yonkey ,  Deidre A. Strand ,  Thomas D. Gregory ,  Jamie L. Cohen ,  Jeremy R. Stajdl

发明人： David R. Wilson ,  Ravi B. Shankar ,  Houxiang Tang ,  Andrew J. Pasztor, JR. ,  Peter M. Margl ,  William J. Kruper, JR. ,  Mark D. Newsham ,  Jing Jin ,  Matthew M. Yonkey ,  Deidre A. Strand ,  Thomas D. Gregory ,  Jamie L. Cohen ,  Jeremy R. Stajdl

IPC分类号： H01M10/0567 ,  H01M10/052

CPC分类号： H01M10/0567 ,  H01M6/168 ,  H01M10/052 ,  H01M10/4235 ,  H01M2300/0025 ,  Y02T10/7011

摘要： A battery electrolyte solution contains from 0.01 to 80% by weight of an aromatic phosphorus compound. The aromatic phosphorus compound provides increased thermal stability for the electrolyte, helping to reduce thermal degradation, thermal runaway reactions and the possibility of burning. The aromatic phosphorus compound has little adverse impact on the electrical properties of the battery, and in some cases actually improves battery performance.

摘要翻译： 电池电解液含有0.01〜80重量％的芳香族磷化合物。 芳族磷化合物为电解质提供了增加的热稳定性，有助于减少热降解，热失控反应和燃烧的可能性。 芳香族磷化合物对电池的电气性能几乎没有不利影响，在某些情况下实际上提高了电池性能。

公开(公告)号：US08574773B2

公开(公告)日：2013-11-05

申请号：US13132374

申请日：2009-11-16

申请人： David R. Wilson ,  Ravi B. Shankar ,  Houxiang Tang ,  Andrew J. Pasztor, Jr. ,  Peter M. Margl ,  William J. Kruper, Jr. ,  Mark D. Newsham ,  Jing Jin ,  Matthew M. Yonkey ,  Deidre A. Strand ,  Thomas D. Gregory ,  Jamie L. Cohen ,  Jeremy R. Stajdl

发明人： David R. Wilson ,  Ravi B. Shankar ,  Houxiang Tang ,  Andrew J. Pasztor, Jr. ,  Peter M. Margl ,  William J. Kruper, Jr. ,  Mark D. Newsham ,  Jing Jin ,  Matthew M. Yonkey ,  Deidre A. Strand ,  Thomas D. Gregory ,  Jamie L. Cohen ,  Jeremy R. Stajdl

IPC分类号： H01M10/0567 ,  H01M10/052

CPC分类号： H01M10/0567 ,  H01M6/168 ,  H01M10/052 ,  H01M10/4235 ,  H01M2300/0025 ,  Y02T10/7011

摘要： A battery electrolyte solution contains from 0.01 to 80% by weight of an aromatic phosphorus compound. The aromatic phosphorus compound provides increased thermal stability for the electrolyte, helping to reduce thermal degradation, thermal runaway reactions and the possibility of burning. The aromatic phosphorus compound has little adverse impact on the electrical properties of the battery, and in some cases actually improves battery performance.

摘要翻译： 电池电解液含有0.01〜80重量％的芳香族磷化合物。 芳族磷化合物为电解质提供了增加的热稳定性，有助于减少热降解，热失控反应和燃烧的可能性。 芳香族磷化合物对电池的电气性能几乎没有不利影响，在某些情况下实际上提高了电池性能。

公开(公告)号：US09147906B2

公开(公告)日：2015-09-29

申请号：US13503369

申请日：2009-11-16

申请人： Houxiang Tang ,  William J. Kruper, Jr. ,  Ravi B. Shankar ,  Deidre A. Strand ,  Peter M. Margl ,  Andrew J. Pasztor, Jr. ,  David R. Wilson ,  Jeremy R. Stajdl

发明人： Houxiang Tang ,  William J. Kruper, Jr. ,  Ravi B. Shankar ,  Deidre A. Strand ,  Peter M. Margl ,  Andrew J. Pasztor, Jr. ,  David R. Wilson ,  Jeremy R. Stajdl

IPC分类号： H01M10/0567 ,  H01M6/16 ,  H01M10/052

CPC分类号： H01M10/0567 ,  H01M6/168 ,  H01M10/052 ,  H01M2300/0025 ,  Y02E60/122

摘要： A battery electrolyte solution contains from 0.001 to 20% by weight of certain phosphorus-sulfur compounds. The phosphorus-sulfur compound performs effectively as a solid-electrolyte interphase (SEI) forming material. The phosphorus-sulfur compound has little adverse impact on the electrical properties of the battery, and in some cases actually improves battery performance. Batteries containing the electrolyte solution form robust and stable SEIs even when charged at high rates during initial formation cycles.

摘要翻译： 电池电解液含有0.001〜20重量％的某些硫 - 硫化合物。 磷硫化合物作为固体 - 电解质间相（SEI）形成材料有效地进行。 磷硫化合物对电池的电气性能几乎没有不利影响，并且在某些情况下实际上提高了电池性能。 含有电解质溶液的电池即使在初始形成循环期间以高速率进行充电也能形成稳健且稳定的SEI。

公开(公告)号：US20120315549A1

公开(公告)日：2012-12-13

申请号：US13503369

申请日：2009-11-16

申请人： Houxiang Tang ,  William J. Kruper, JR. ,  Ravi B. Shankar ,  Deidre A. Strand ,  Peter M. Margl ,  Andrew J. Pasztor, JR. ,  David R. Wilson ,  Jerey R. Stajdi

发明人： Houxiang Tang ,  William J. Kruper, JR. ,  Ravi B. Shankar ,  Deidre A. Strand ,  Peter M. Margl ,  Andrew J. Pasztor, JR. ,  David R. Wilson ,  Jerey R. Stajdi

IPC分类号： H01M10/056 ,  H01M10/0567 ,  H01M10/0569 ,  H01M10/0566 ,  H01M10/052 ,  H01M10/0565

CPC分类号： H01M10/0567 ,  H01M6/168 ,  H01M10/052 ,  H01M2300/0025 ,  Y02E60/122

摘要： A battery electrolyte solution contains from 0.001 to 20% by weight of certain phosphorus-sulfur compounds. The phosphorus-sulfur compound performs effectively as a solid-electrolyte interphase (SEI) forming material. The phosphorus-sulfur compound has little adverse impact on the electrical properties of the battery, and in some cases actually improves battery performance. Batteries containing the electrolyte solution form robust and stable SEIs even when charged at high rates during initial formation cycles.

摘要翻译： 电池电解液含有0.001〜20重量％的某些硫 - 硫化合物。 磷硫化合物作为固体 - 电解质间相（SEI）形成材料有效地进行。 磷硫化合物对电池的电气性能几乎没有不利影响，并且在某些情况下实际上提高了电池性能。 含有电解质溶液的电池即使在初始形成循环期间以高速率进行充电也能形成稳健且稳定的SEI。