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公开(公告)号：US5091489A
公开(公告)日：1992-02-25
申请号：US734925
申请日：1991-07-24
申请人： Steven M. Heilmann , Dean M. Moren , Jerald K. Rasmussen , Larry R. Krepski , Sadanand V. Pathre
发明人： Steven M. Heilmann , Dean M. Moren , Jerald K. Rasmussen , Larry R. Krepski , Sadanand V. Pathre
IPC分类号： C07D263/42 , C07D498/04 , C07D498/14 , C08F4/20
CPC分类号： C07D263/42
摘要： This invention provides novel azlactone-functional oligomers of 2-alkenyl azlactones in which oligomerization has occurred predominantly via the 2-alkenyl group. Oligomerization of the 2-alkenyl group provides oligomers having 2 to 15 mer units with predominantly carbon-carbon backbone segments. Oligomerized in this fashion, the novel compositions possess azlactone groups which can be reacted with nucleophiles in the normal ring-opening sense. The oligomers are prepared by a novel process in which both Lewis and Bronsted acidic catalysts are effective. The reactive oligomers find utility as crosslinking agents for polymers containing azlactone-reactable nucleophilic groups.
摘要翻译： 本发明提供2-链烯基吖内酯的新型吖内酯官能低聚物，其中低聚主要通过2-链烯基发生。 2-烯基的低聚提供了具有主要为碳 - 碳骨架链段的2至15个mer单元的低聚物。 以这种方式低聚，新型组合物具有吖内酯基团，其可以以正常的开环方式与亲核试剂反应。 低聚物通过其中Lewis和Bronsted酸性催化剂都有效的新方法制备。 反应性低聚物可用作用于含有吖内酯可反应的亲核基团的聚合物的交联剂。
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公开(公告)号：US5210248A
公开(公告)日：1993-05-11
申请号：US749926
申请日：1991-08-26
申请人： Stefan A. Babirad , Dean M. Moren , Steven M. Heilmann , Larry R. Krepski , Jerald K. Rasmussen
发明人： Stefan A. Babirad , Dean M. Moren , Steven M. Heilmann , Larry R. Krepski , Jerald K. Rasmussen
IPC分类号： C07F7/10 , C07F7/18 , C08F30/08 , C08F130/08 , C08F230/08
CPC分类号： C08F30/08 , C07F7/1836
摘要： The present invention provides novel fluorinated acrylamide silane monomers which are useful as adhesion promoting agents in optical fiber cladding compositions. Polymerization of the novel monomers, optionally in the presence compatible ethylenically-unsaturated monomers, provides homopolymers and copolymers which are useful as non-wetting agents.
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公开(公告)号：US4931582A
公开(公告)日：1990-06-05
申请号：US267186
申请日：1988-11-04
申请人： Steven M. Heilmann , Larry R. Krepski , Dean M. Moren , Jerald K. Rasmussen , Howell K. Smith, II
发明人： Steven M. Heilmann , Larry R. Krepski , Dean M. Moren , Jerald K. Rasmussen , Howell K. Smith, II
IPC分类号： B01J31/02 , C07B61/00 , C07C231/10 , C07C233/49 , C07C311/03 , C08F20/00 , C08F20/58
CPC分类号： C07C311/03 , C07C233/49 , C08F20/58 , C07C2101/14
摘要： Novel fluorinated, acrylamide monomers are prepared from 2-alkenyl azlactones reacted with fluorinated alcohols. The novel monomers have the formula ##STR1## wherein R.sup.1 and R.sup.6 are independently hydrogen or methyl;R.sup.2 and R.sup.3 independently can be an alkyl, cycloalkyl, or aryl group, or R.sup.2 and R.sup.3 taken together with the carbon to which they are joined can form a carbocyclic ring containing 4 to 12 ring atoms;R.sup.4 and R.sup.5 are independently hydrogen or lower alkyl;a is 0 or 1;b is 1 or 2;X is a single bond, CH.sub.2, CH.sub.2 OCH.sub.2, and CH.sub.2 CH.sub.2 OCH.sub.2 ; andR.sub.F is a substantially perfluorinated alkyl, cycloalkyl, or aryl group when b is 1 and perfluorinated alkylene when b is 2.Novel polymers and copolymers can be prepared from the monomers of the invention.
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公开(公告)号：US4906792A
公开(公告)日：1990-03-06
申请号：US267035
申请日：1988-11-04
IPC分类号： B01J27/08 , B01J27/232 , B01J31/04 , C07B61/00 , C07C41/16 , C07C43/13 , C07C43/178
CPC分类号： C07C41/16
摘要： Mono O-hydroxyalkylated derivatives of 1,1-dihydroperfluorinated alcohols are prepared by reaction the alcohols with alkylene carbonates. The O-hydroxyalkylated derivatives are useful non-ionic surfactants and emulsifiable compounds for fire extinguishing systems.
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公开(公告)号：US4874822A
公开(公告)日：1989-10-17
申请号：US178507
申请日：1988-04-07
IPC分类号： C08J3/24 , C07C231/14 , C07C233/49 , C08F8/00 , C08F8/30 , C08F20/00 , C08F20/52 , C08F20/58 , C08F290/00 , C08F299/02 , C08G63/08 , C08G63/68 , C08G65/32
CPC分类号： C07C231/14 , C08F8/30
摘要： The present invention provides a dramatically improved process for the preparation of acrylamide and methacrylamide functional monomers, oligomers, and polymers that avoids the use of acidic catalysts which can cause undesired side reactions. The present invention process involves reacting an alkenyl azlactone with a hydroxy functional compound in the presence of a catalytic amount of either a bicyclic amidine or a trivalent phosphorus compound. These efficient basic catalysts provide unexpectedly increased reaction rates under mild conditions.
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公开(公告)号：US5314975A
公开(公告)日：1994-05-24
申请号：US10492
申请日：1993-01-28
申请人： Stefan A. Babirad , Dean M. Moren , Steven M. Heilmann , Larry R. Krepski , Jerald K. Rasmussen
发明人： Stefan A. Babirad , Dean M. Moren , Steven M. Heilmann , Larry R. Krepski , Jerald K. Rasmussen
IPC分类号： C07F7/10 , C07F7/18 , C08F30/08 , C08F130/08 , C08F230/08 , C08F26/00
CPC分类号： C08F30/08 , C07F7/1836
摘要： The present invention provides novel fluorinated acrylamide silane monomers which are useful as adhesion promoting agents in optical fiber cladding compositions. Polymerization of the novel monomers, optionally in the presence compatible ethylenically-unsaturated monomers, provides homopolymers and copolymers which are useful as non-wetting agents.
摘要翻译： 本发明提供了新颖的氟化丙烯酰胺硅烷单体，其可用作光纤包层组合物中的粘合促进剂。 新型单体的聚合，任选地在相容的烯键式不饱和单体存在下，提供可用作非润湿剂的均聚物和共聚物。
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公开(公告)号：US5268473A
公开(公告)日：1993-12-07
申请号：US905286
申请日：1992-06-26
IPC分类号： C07D263/42 , C07D265/06
CPC分类号： C07D263/42 , C07D265/06
摘要： Azlactone-functional Michael adducts are disclosed which are the Michael reaction products of 2-alkenyl azlactones and Michael donors selected from carbon and nitrogen nucleophiles. Reaction products which contain a plurality of azlactone groups are useful as step growth monomers in adhesives, sealants, and coatings.
摘要翻译： 公开了作为选自碳和氮亲核试剂的2-烯基吖内酯和迈克尔供体的迈克尔反应产物的吖内酮官能的迈克尔加合物。 含有多个吖内酯基团的反应产物可用作粘合剂，密封剂和涂料中的步骤生长单体。
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公开(公告)号：USRE34348E
公开(公告)日：1993-08-17
申请号：US969462
申请日：1992-10-30
申请人： Steven M. Heilmann , Larry R. Krepski , Dean M. Moren , Jerald K. Rasmussen , Howell K. Smith, II
发明人： Steven M. Heilmann , Larry R. Krepski , Dean M. Moren , Jerald K. Rasmussen , Howell K. Smith, II
IPC分类号： C07C233/49 , C08F20/58
CPC分类号： C07C233/49 , C08F20/58
摘要： Novel fluorinated, acrylamide monomers are prepared from 2-alkenyl azlactones reacted with fluorinated alcohols. The novel monomers have the formula ##STR1## wherein R.sup.1 and R.sup.6 are independently hydrogen or methyl; R.sup.2 and R.sup.3 independently can be an alkyl, cycloalkyl, or aryl group, or R.sup.2 and R.sup.3 taken together with the carbon to which they are joined can form a carbocyclic ring containing 4 to 12 ring atoms;R.sup.4 and R.sup.5 are independently hydrogen or lower alkyl;a is 0 or 1;b is 1 or 2;X is a single bond, CH.sub.2, CH.sub.2 OCH.sub.2, and CH.sub.2 CH.sub.2 OCH.sub.2 ; andR.sub.f is a substantially perfluorinated alkyl, cycloalkyl, or aryl group when b is 1 and perfluorinated alkylene when b is 2.Novel polymers and copolymers can be prepared from the monomers of the invention.
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公开(公告)号：US5157108A
公开(公告)日：1992-10-20
申请号：US449719
申请日：1989-12-12
IPC分类号： C07D263/42 , C07D263/52 , C07D265/06 , C07D265/10 , C07D265/12 , C08F8/00 , C08G59/40 , C08G59/50 , C08G73/00
CPC分类号： C07D265/10 , C07D263/42 , C08G59/4014 , C08G59/5046 , C08G73/00
摘要： Compounds containing alpha-amidoacetyle linkages are described that are thermally labile and yield nucleophilic and azlactone products. Nucleophiles are useful as curing agents for epoxy resin sealants and adhesives and azlactones are useful in crosslinking systems for polymers.
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公开(公告)号：US5149806A
公开(公告)日：1992-09-22
申请号：US500768
申请日：1990-03-28
IPC分类号： C07D263/42 , C07D265/06 , C07D413/12 , C08G18/30 , C08G73/06 , C09D7/12 , C09D11/06 , C09J11/06
CPC分类号： C07D265/06 , C07D263/42
摘要： Azlactone-functional Michael adducts are disclosed which are the Michael reaction products of 2-alkenyl azlactones and Michael donors selected from carbon and nitrogen nucleophiles. Reaction products which contain a plurality of azlactone groups are useful as step growth monomers in adhesives, sealants, and coatings.
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