摘要:
A method of producing an active material for a lithium secondary battery, by which impurities causing problems in synthesizing an active material for a lithium secondary battery, including a lithium transition metal oxyanion compound are removed efficiently and enhancement of an energy density is realized, is provided. By cleaning the active material for a lithium secondary battery, including a lithium transition metal oxyanion compound, with a pH buffer solution, for example, it is possible to efficiently remove just only impurities such as Li3PO4 or Li2CO3, or a substance, other than LiFePO4, in which the valence of Fe is bivalent such as FeSO4, FeO or Fe3(PO4)2 without dissolving Fe of LiFePO4.
摘要翻译:提供一种生产用于锂二次电池的活性材料的方法,其中提供了有效地除去包含锂过渡金属氧阴离子化合物的锂二次电池的活性材料合成的问题的杂质并实现能量密度的提高 。 通过例如利用pH缓冲溶液清洗包含锂过渡金属氧阴离子化合物的锂二次电池的活性物质,可以仅仅有效地除去Li 3 PO 4或Li 2 CO 3等杂质,或除了LiFePO 4以外的物质 ,其中铁的价数是二价的,如FeSO 4,FeO或Fe 3(PO 4)2,而不溶解LiFePO 4的Fe。
摘要:
An object of the invention is to improve the safety of nonaqueous electrolyte secondary batteries in the event of overcharging. The invention is directed to a nonaqueous electrolyte secondary battery including a positive electrode containing a positive electrode active material, a negative electrode, a nonaqueous electrolyte, a separator and a current interrupting element, the positive electrode active material including a first compound represented by the general formula LiCoxM1-xO2 (wherein 0.1≦x≦1 and M is one or more metal elements including at least Ni or Mn) and a second compound generating a gas when the positive electrode potential becomes not less than 4.5 V versus lithium metal, the current interrupting element being a pressure-sensitive current interrupting element.
摘要:
A nonaqueous electrolyte secondary battery includes a positive electrode containing a positive electrode active material, a negative electrode containing a negative electrode active material, and a nonaqueous electrolyte solution containing a nonaqueous solvent. The positive electrode active material contains a lithium-containing transition metal oxide represented by general formula (1), Li1+xMnyMzO2 (where x, y, and z satisfy 0