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公开(公告)号:US20050283032A1
公开(公告)日:2005-12-22
申请号:US10870514
申请日:2004-06-17
申请人: Dennis Curran , Masato Matsugi , Marvin Yu
发明人: Dennis Curran , Masato Matsugi , Marvin Yu
CPC分类号: C07C17/263 , C07B39/00 , C07C17/38 , C07C21/18 , C07C22/08 , C07C67/56 , Y10T436/13 , Y10T436/19 , C07C69/63
摘要: A method of separating at least a first non-fluorous compound from a mixture of compounds including at least the first non-fluorous compound and a second fluorous compound includes: charging the of compounds to a non-fluorous solid (stationary) phase and eluting with a fluorous eluting fluid (mobile phase). In one embodiment, the non-fluorous solid phase is polar in nature. The method can further include a second phase elution with a suitable organic solvent. A method conducting a chemical reaction, includes: mixing at least a first fluorous compound and a second compound, the first fluorous compound differing in fluorous nature from the second compound; exposing the first mixture to conditions to convert at least one of the first fluorous compound and the second compound to give a second mixture containing at least a third compound, charging the second mixture to a non-fluorous solid phase; and eluting with a fluorous fluid
摘要翻译: 从至少包含第一非氟化合物和第二氟化合物的化合物的混合物中分离至少第一非氟化合物的方法包括:将化合物装入非氟固体(固定)相,并用 氟洗脱液(流动相)。 在一个实施方案中,非氟固体本质上是极性的。 该方法还可以包括用合适的有机溶剂进行第二相洗脱。 进行化学反应的方法包括:将至少第一氟化合物和第二化合物混合,所述第一氟化合物与所述第二化合物不同; 将第一混合物暴露于转化至少一种第一种氟化合物和第二种化合物的条件以产生含有至少第三种化合物的第二混合物,将第二种混合物装入非氟固体; 并用氟液洗脱
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公开(公告)号:US07364908B2
公开(公告)日:2008-04-29
申请号:US10870514
申请日:2004-06-17
申请人: Dennis P. Curran , Masato Matsugi , Marvin S. Yu
发明人: Dennis P. Curran , Masato Matsugi , Marvin S. Yu
IPC分类号: G01N37/00 , G01N33/22 , C07C19/08 , C07C17/266
CPC分类号: C07C17/263 , C07B39/00 , C07C17/38 , C07C21/18 , C07C22/08 , C07C67/56 , Y10T436/13 , Y10T436/19 , C07C69/63
摘要: A method of separating at least a first non-fluorous compound from a mixture of compounds including at least the first non-fluorous compound and a second fluorous compound includes: charging the of compounds to a non-fluorous solid (stationary) phase and eluting with a fluorous eluting fluid (mobile phase). In one embodiment, the non-fluorous solid phase is polar in nature. The method can further include a second phase elution with a suitable organic solvent. A method conducting a chemical reaction, includes: mixing at least a first fluorous compound and a second compound, the first fluorous compound differing in fluorous nature from the second compound; exposing the first mixture to conditions to convert at least one of the first fluorous compound and the second compound to give a second mixture containing at least a third compound, charging the second mixture to a non-fluorous solid phase; and eluting with a fluorous fluid.
摘要翻译: 从至少包含第一非氟化合物和第二氟化合物的化合物的混合物中分离至少第一非氟化合物的方法包括:将化合物装入非氟固体(固定)相并用 氟洗脱液(流动相)。 在一个实施方案中,非氟固体本质上是极性的。 该方法还可以包括用合适的有机溶剂进行第二相洗脱。 进行化学反应的方法包括:将至少第一氟化合物和第二化合物混合,所述第一氟化合物与所述第二化合物不同; 将第一混合物暴露于转化至少一种第一种氟化合物和第二种化合物的条件以产生含有至少第三种化合物的第二混合物,将第二种混合物装入非氟固体; 并用氟液洗脱。
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公开(公告)号:US6013826A
公开(公告)日:2000-01-11
申请号:US63825
申请日:1998-04-22
申请人: Yasuyuki Kita , Atsunori Sano , Takahiro Yamaguchi , Masahisa Oka , Masato Matsugi , Kentoku Gotanda
发明人: Yasuyuki Kita , Atsunori Sano , Takahiro Yamaguchi , Masahisa Oka , Masato Matsugi , Kentoku Gotanda
IPC分类号: B01J31/02 , C07B37/02 , C07B39/00 , C07C253/30 , C07C255/00
CPC分类号: C07B39/00 , B01J31/0235 , C07B37/02 , C07C253/30 , B01J2231/323
摘要: A method for an addition reaction with the formation of an additional carbon--carbon bond comprising reacting an .alpha.-halogeno carboxylic acid derivative with an alkene in the presence of a catalyst shown by the general formula (1): ##STR1## wherein R.sub.1 is a lower alkyl group.
摘要翻译: 一种形成另外的碳 - 碳键的加成反应的方法,包括在由通式(1)表示的催化剂存在下使α-卤代羧酸衍生物与烯烃反应:其中R1是低级烷基 。
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