Liquid phase carbon monoxide shift process
    2.
    发明授权
    Liquid phase carbon monoxide shift process 失效
    液相一氧化碳转移过程

    公开(公告)号:US4980145A

    公开(公告)日:1990-12-25

    申请号:US461956

    申请日:1990-01-08

    IPC分类号: C01B3/12

    CPC分类号: C01B3/12

    摘要: The present invention relates to a water-gas shift process which is carried out in a non-aqueous, high boiling liquid medium, either in an ebullated or slurry mode. The function of the liquid is to provide a heat sink for the exothermic reaction thereby allowing for better performance and longer catalyst life. The process, termed "liquid phase shift" (LPS) preferably uses commercially available vapor-phase low temperature shift (LTS) catalysts to accomplish the shift reaction. Because of the isothermality of the LPS process and its ability therefore to take advantage of higher catalyst activity, the average operating temperature is typically 260.degree. C. (500.degree. F.). This compares favorably to the lower average operating temperature for the conventional vapor-phase LTS process, which is typically 240.degree. C. (465.degree. F.). In addition, the LPS process can handle high carbon monoxide content feeds, e.g. 75 vol % carbon monoxide on a dry basis, without experiencing excessive catalyst deactivation. High carbon monoxide content feeds cannot be handled by convention LTS processing.

    摘要翻译: 本发明涉及一种在非水,高沸点液体介质中以沸腾或浆液模式进行的水煤气变换方法。 液体的功能是为放热反应提供散热器,从而实现更好的性能和更长的催化剂寿命。 称为“液相移”(LPS)的方法优选使用市售的气相低温位移(LTS)催化剂来实现转移反应。 由于LPS过程的等温性及其因此能够利用较高催化剂活性的能力,平均操作温度通常为260℃(500°F)。 这相对于常规气相LTS工艺的较低的平均工作温度,其通常为240℃(465°F)。 此外,LPS过程可以处理高一氧化碳含量的进料,例如 75体积%的一氧化碳在干燥的基础上,没有经历过度的催化剂失活。 一氧化碳含量高的饲料不能通过常规的LTS处理来处理。

    Two stage pressure swing adsorption process for producing the less
strongly adsorbed component of a feed gas mixture
    3.
    发明授权
    Two stage pressure swing adsorption process for producing the less strongly adsorbed component of a feed gas mixture 失效
    用于产生进料气体混合物较弱吸附组分的两级变压吸附方法

    公开(公告)号:US5382280A

    公开(公告)日:1995-01-17

    申请号:US153387

    申请日:1993-11-16

    摘要: A two stage pressure swing adsorption process is set forth for producing the less strongly adsorbed component of a feed gas mixture wherein the first stage utilizes a first adsorbent for bulk removal of the more strongly adsorbed component and wherein the second stage utilizes a second adsorbent for trace removal of the more strongly adsorbed component. A further feature of the present invention is that the desorbed gas from the second stage's depressurization step (consisting primarily of the desired less strongly adsorbed component) is recycled to the first stage in order to improve its performance. In a preferred embodiment of the present invention, high purity nitrogen (less than 1000 ppm oxygen, preferably less than 100 ppm oxygen) is produced from an air feed using a kinetically controlled carbon molecular sieve adsorbent in the first stage and an equilibrium controlled metal complex-based adsorbent in the second stage.

    摘要翻译: 介绍了两阶段变压吸附方法,用于生产进料气体混合物的较弱吸附组分,其中第一阶段利用第一吸附剂来大量去除较强吸附组分,其中第二阶段利用第二吸附剂进行痕量 去除较强吸附组分。 本发明的另一个特征是,来自第二阶段的减压步骤(主要由所需的较不强吸附组分组成的)的解吸气体被再循环到第一阶段以便改进其性能。 在本发明的优选实施方案中,使用第一阶段中的动力学控制的碳分子筛吸附剂和平衡控制的金属络合物从空气进料产生高纯度氮(小于1000ppm氧,优选小于100ppm氧) 的吸附剂在第二阶段。

    Process and apparatus for producing nitrogen and oxygen
    6.
    发明授权
    Process and apparatus for producing nitrogen and oxygen 失效
    用于生产氮和氧的方法和装置

    公开(公告)号:US5305610A

    公开(公告)日:1994-04-26

    申请号:US573922

    申请日:1990-08-28

    摘要: The present invention is a separation process for atmospheric gases. In the process, an atmospheric gas stream, for example air, is compressed and may be partly condensed prior to introduction into a vortex tube air separator. The performance of the tube separation can be upgraded, i.e. by improving the concentration and/or purity of the main oxygen stream, by enhancing the separator efficiency of the vortex tube (VT) apparatus. One approach is by selectively refrigerating the cold end of the tube with partial recycle of nitrogen gas waste stream, effecting a rectification section. Another approach is to increase the heat transfer between the outlet gas stream and the liquid film flowing along the curvilinear periphery of the separator means, by mechanical innovations in its configuration.

    摘要翻译: 本发明是用于大气气体的分离方法。 在此过程中,大气气流,例如空气,被压缩,并可在引入涡流管空气分离器之前部分冷凝。 可以通过提高涡流管(VT)装置的分离器效率来升级管分离的性能,即通过改善主氧流的浓度和/或纯度。 一种方法是通过选择性地冷却管的冷端,部分地再循环氮气废气流,从而实现整流段。 另一种方法是通过其结构中的机械创新来增加出口气体流和沿着分离器装置的曲线周边流动的液体膜之间的热传递。

    Split-flow regeneration in absorptive air separation
    7.
    发明授权
    Split-flow regeneration in absorptive air separation 失效
    吸收空气分离中的分流再生

    公开(公告)号:US4708860A

    公开(公告)日:1987-11-24

    申请号:US947165

    申请日:1986-12-29

    申请人: Robert F. Weimer

    发明人: Robert F. Weimer

    IPC分类号: B01D53/14 C01B13/02 C01B13/00

    摘要: A chemical absorptive separation of air in multiple stage of absorption and desorption is performed with partial recycle of absorbent between stages of desorption necessary to match equilibrium conditions in the various stages of absorption. This allows reduced absorbent flow, reduced energy demand and reduced capital costs.

    摘要翻译: 在吸收和解吸的多个阶段中进行空气的化学吸收分离,在吸附阶段之间进行部分循环,以便在不同的吸收阶段匹配平衡条件所需的解吸阶段。 这样可以减少吸收流量,减少能源需求并降低资本成本。

    Coal liquefaction with preasphaltene recycle
    8.
    发明授权
    Coal liquefaction with preasphaltene recycle 失效
    煤泥液化与沥青质再循环

    公开(公告)号:US4609455A

    公开(公告)日:1986-09-02

    申请号:US703858

    申请日:1985-02-21

    CPC分类号: C10G1/002 Y10S208/952

    摘要: A coal liquefaction system is disclosed with a novel preasphaltene recycle from a supercritical extraction unit to the slurry mix tank wherein the recycle stream contains at least 90% preasphaltenes (benzene insoluble, pyridine soluble organics) with other residual materials such as unconverted coal and ash. This subject process results in the production of asphaltene materials which can be subjected to hydrotreating to acquire a substitute for No. 6 fuel oil. The preasphaltene-predominant recycle reduces the hydrogen consumption for a process where asphaltene material is being sought.

    摘要翻译: 公开了一种从超临界萃取单元向淤浆混合槽再循环的新型预沥青烯再循环料流,其中再循环料流含有至少90%的预沥青质(苯不溶性,吡啶可溶性有机物)与其他残留物如未转化的煤和灰分。 该主题工艺可以生产可以进行加氢处理以获得6号燃料油替代品的沥青质材料。 预沥青烯主要的循环可以降低正在寻求沥青质材料的工艺中的氢消耗。