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公开(公告)号：US09096747B2
公开(公告)日：2015-08-04
申请号：US12013183
申请日：2008-01-11
申请人： Derek Thurman , Sudhin Datta , Wen Li , Charles L. Sims
发明人： Derek Thurman , Sudhin Datta , Wen Li , Charles L. Sims
CPC分类号： C08L23/10 , C08L23/12 , C08L23/142 , C08L2205/02 , C08L2666/06
摘要： Low molecular weight semicrystalline propylene-alpha olefin copolymers containing propylene crystallinity are used as a nucleating agent in crystalline polypropylene and polypropylene copolymers. The nucleating copolymers are propylene-alpha olefin copolymers having a percent crystallinity of 5-75%, a melting point of 45° C.-105° C., and an MFR between 300 and 5000 g/10 min. Nucleated polypropylene compositions comprise a nucleating amount of the copolymer blended in a matrix of polypropylene homopolymer, or 0.01 to 9 wt % α-olefin copolymer, having a melting point greater than 110° C. The nucleating copolymer improves processing time with little or no effect on the crystallinity-associated characteristics of the matrix. The invention also provides methods of crystallizing polypropylene with the nucleating agent and of forming articles with the composition, and also provides articles formed from the composition and/or by the method.
摘要翻译： 含有丙烯结晶度的低分子量半结晶丙烯-α烯烃共聚物用作结晶聚丙烯和聚丙烯共聚物中的成核剂。 成核共聚物是结晶度为5-75％，熔点为45℃-105℃，MFR为300-5000g / 10min的丙烯-α-烯烃共聚物。 成核聚丙烯组合物包含在聚丙烯均聚物基质中混合的成核量的共聚物，或熔点大于110℃的0.01至9重量％的α-烯烃共聚物。成核共聚物改善处理时间，几乎没有或没有效果 关于基质的结晶性相关特征。 本发明还提供了使聚丙烯与成核剂结晶并形成具有该组合物的制品的方法，还提供了由该组合物和/或该方法形成的制品。
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公开(公告)号：US20080249248A1
公开(公告)日：2008-10-09
申请号：US12013183
申请日：2008-01-11
申请人： Derek Thurman , Sudhin Datta , Wen Li , Charles L. Sims
发明人： Derek Thurman , Sudhin Datta , Wen Li , Charles L. Sims
IPC分类号： C08L23/02
CPC分类号： C08L23/10 , C08L23/12 , C08L23/142 , C08L2205/02 , C08L2666/06
摘要： Low molecular weight semicrystalline propylene-alpha olefin copolymers containing propylene crystallinity are used as a nucleating agent in crystalline polypropylene and polypropylene copolymers. The nucleating copolymers are propylene-alpha olefin copolymers having a percent crystallinity of 5-75%, a melting point of 45° C.-105° C., and an MFR between 300 and 5000 g/10 min. Nucleated polypropylene compositions comprise a nucleating amount of the copolymer blended in a matrix of polypropylene homopolymer, or 0.01 to 9 wt % α-olefin copolymer, having a melting point greater than 110° C. The nucleating copolymer improves processing time with little or no effect on the crystallinity-associated characteristics of the matrix. The invention also provides methods of crystallizing polypropylene with the nucleating agent and of forming articles with the composition, and also provides articles formed from the composition and/or by the method.
摘要翻译： 含有丙烯结晶度的低分子量半结晶丙烯-α烯烃共聚物用作结晶聚丙烯和聚丙烯共聚物中的成核剂。 成核共聚物是结晶度为5-75％，熔点为45℃-105℃，MFR为300-5000g / 10min的丙烯-α-烯烃共聚物。 成核聚丙烯组合物包含在聚丙烯均聚物基质中共混的成核量的共聚物，或0.01至9重量％的熔点大于110℃的α-烯烃共聚物。成核共聚物改善处理时间，几乎没有或没有影响 关于基质的结晶性相关特征。 本发明还提供了使聚丙烯与成核剂结晶并形成具有该组合物的制品的方法，还提供了由该组合物和/或该方法形成的制品。
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公开(公告)号：US20080249231A1
公开(公告)日：2008-10-09
申请号：US12080486
申请日：2008-04-03
CPC分类号： C08L23/10 , C08L23/12 , C08L23/142 , C08L2205/02 , C08L2666/06
摘要： The present invention also discloses a homogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR @ 230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min. b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C., wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent.
摘要翻译： 本发明还公开了一种均匀的共混组合物，其包含： a）1重量％至99重量％的第一聚合物组分的共混物，其包含5重量％至35重量％的主要由α-烯烃衍生单元组成的第一聚合物组分和65重量％至95重量％ 来自全同立构聚丙烯序列的结晶度为0.1％至约25％的丙烯衍生单元的第一聚合物组分，熔点为45℃至105℃，并且其中熔体流动速率（MFR @ 230℃ 。）的第一聚合物组分在300g / 10min至5000g / 10min之间。 b）1重量％至99重量％的包含全同立构聚丙烯的第二聚合物组分和全同立构丙烯的无规共聚物的共混物的共混物，其中共聚物中共聚α-烯烃的百分比为0.0-9重量％ 所述第二聚合物组分并且其中所述第二聚合物组分具有大于约110℃的熔点，其中所述第一聚合物组分具有小于1000ppm的由分子降解剂的化学反应产生的反应产物。
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公开(公告)号：US08263707B2
公开(公告)日：2012-09-11
申请号：US12080495
申请日：2008-04-03
CPC分类号： C08L23/10 , C08L23/16 , C08L2205/02 , C08L2205/03 , C08L2666/02
摘要： The present invention also discloses a heterogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR@230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C., wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent.
摘要翻译： 本发明还公开了一种非均相共混组合物，其包含： a）1重量％至99重量％的第一聚合物组分的共混物，其包含5重量％至35重量％的主要由α-烯烃衍生单元组成的第一聚合物组分和65重量％至95重量％ 来自全同立构聚丙烯序列的结晶度为0.1％至约25％的丙烯衍生单元的第一聚合物组分，熔点为45℃至105℃，并且其中熔体流动速率（MFR @ 230℃ 第一聚合物组分的重量比在300g / 10min至5000g / 10min之间b）1重量％至99重量％的包含全同立构聚丙烯的第二聚合物组分和全同立构丙烯的无规共聚物的共混物，其中 共聚物中的共聚α-烯烃的百分比为第二聚合物组分的0.0％至9％，其中第二聚合物组分的熔点大于约110℃，其中第一聚合物组分的含量小于 产生1000ppm的反应产物 来自分子降解剂的化学反应。
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5.发明授权Blends of low crystallinity, low molecular weight propylene copolymers and styrenic block copolymers 有权低结晶度的共混物，低分子量丙烯共聚物和苯乙烯嵌段共聚物公开(公告)号：US08052822B2
公开(公告)日：2011-11-08
申请号：US12032060
申请日：2008-02-15
IPC分类号： B32B27/00 , B32B37/24 , B32B37/00 , B32B38/00 , B29C65/00 , C08L53/00 , C08L9/00 , C08L47/00
CPC分类号： C08L23/142 , C08L23/14 , C08L53/00 , C08L53/02 , C08L91/005 , C08L2666/24 , C08L2666/04
摘要： Styrenic block copolymers are blended with propylene copolymers to provide polymeric compositions with an improved balance between processability and elasticity. The compositions have improved processability by facilitating the ease with which a rubbery material, usually difficult to melt process, can be processed at high line speeds, which in turn improves the formation of the composition into films or other articles, assisted by a desired level of melt elasticity, i.e., a high elastic extension and recovery.
摘要翻译： 苯乙烯嵌段共聚物与丙烯共聚物共混以提供加工性和弹性之间改进的平衡的聚合物组合物。 组合物通过促进通常难以熔融加工的橡胶材料易于以高线速度加工的方便性而改进了加工性能，这进而改进了组合物形成薄膜或其它制品，由所需水平的 熔体弹性，即高弹性延伸和恢复。
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公开(公告)号：US07858701B2
公开(公告)日：2010-12-28
申请号：US12080486
申请日：2008-04-03
IPC分类号： C08L23/10
CPC分类号： C08L23/10 , C08L23/12 , C08L23/142 , C08L2205/02 , C08L2666/06
摘要： The present invention also discloses a homogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR @ 230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min. b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C., wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent.
摘要翻译： 本发明还公开了一种均匀的共混组合物，其包含： a）1重量％至99重量％的第一聚合物组分的共混物，其包含5重量％至35重量％的主要由α-烯烃衍生单元组成的第一聚合物组分和65重量％至95重量％ 来自全同立构聚丙烯序列的结晶度为0.1％至约25％的丙烯衍生单元的第一聚合物组分，熔点为45℃至105℃，并且其中熔体流动速率（MFR @ 230℃ 。）的第一聚合物组分在300g / 10min至5000g / 10min之间。 b）1重量％至99重量％的包含全同立构聚丙烯的第二聚合物组分和全同立构丙烯的无规共聚物的共混物的共混物，其中共聚物中共聚α-烯烃的百分比为0.0-9重量％ 所述第二聚合物组分并且其中所述第二聚合物组分具有大于约110℃的熔点，其中所述第一聚合物组分具有小于1000ppm的由分子降解剂的化学反应产生的反应产物。
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公开(公告)号：US20080249232A1
公开(公告)日：2008-10-09
申请号：US12080495
申请日：2008-04-03
CPC分类号： C08L23/10 , C08L23/16 , C08L2205/02 , C08L2205/03 , C08L2666/02
摘要： The present invention also discloses a heterogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR@230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C., wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent.
摘要翻译： 本发明还公开了一种非均相共混组合物，其包含： a）1重量％至99重量％的第一聚合物组分的共混物，其包含5重量％至35重量％的主要由α-烯烃衍生单元组成的第一聚合物组分和65重量％至95重量％ 来自全同立构聚丙烯序列的结晶度为0.1％至约25％的丙烯衍生单元的第一聚合物组分，熔点为45℃至105℃，并且其中熔体流动速率（MFR @ 230℃ ）第一聚合物组分的量为300g / 10min至5000g / 10min，b）1重量％至99重量％的包含全同立构聚丙烯的第二聚合物组分和全同立构丙烯的无规共聚物的共混物，其中 共聚物中的共聚α-烯烃的百分比为第二聚合物组分的0.0％至9％，其中第二聚合物组分的熔点大于约110℃，其中第一聚合物组分的含量小于 产生1000ppm的反应产物 来自分子降解剂的化学反应。
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公开(公告)号：US07906588B2
公开(公告)日：2011-03-15
申请号：US12246302
申请日：2008-10-06
CPC分类号： C08L23/10 , C08L23/142 , C08L23/145 , C08L2205/02 , C08L2666/06
摘要： Provided are heterogeneous blend compositions comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR@230 C) of the first polymer component is between 300 g/10 min to 5000 g/10 min b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C., wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent. The provided compositions are useful in high temperature applications.
摘要翻译： 提供了非均相共混组合物，其包含： a）1重量％至99重量％的第一聚合物组分的共混物，其包含5重量％至35重量％的主要由α-烯烃衍生单元组成的第一聚合物组分和65重量％至95重量％ 来自全同立构聚丙烯序列的结晶度为0.1％至约25％的丙烯衍生单元的第一聚合物组分，熔点为45℃至105℃，其中熔体流动速率（MFR @ 230℃） 的第一聚合物组分的量为300g / 10min至5000g / 10min，b）1重量％至99重量％的包含全同立构聚丙烯的第二聚合物组分和全同立构丙烯的无规共聚物的共混物，其中百分比 共聚物中共聚的α-烯烃的含量为第二聚合物组分的0.0％至9％，其中第二聚合物组分的熔点大于约110℃，其中第一聚合物组分的含量小于1000ppm 的反应产物出现 这是分子降解剂的化学反应。 所提供的组合物可用于高温应用。
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公开(公告)号：US09938400B2
公开(公告)日：2018-04-10
申请号：US12108336
申请日：2008-04-23
申请人： Abdelhadi Sahnoune , Sudhin Datta , Mun Fu Tse , Charles L. Sims , James N. Coffey , Peijun Jiang
发明人： Abdelhadi Sahnoune , Sudhin Datta , Mun Fu Tse , Charles L. Sims , James N. Coffey , Peijun Jiang
CPC分类号： C08L23/10 , C08L23/14 , C08L23/142 , C08L2666/04
摘要： Thermoplastic polyolefins (TPOs) and/or thermoplastic vulcanizates (TPVs) are blended with low molecular weight propylene-dominated copolymers to provide polymeric compositions with an improved balance between processability and toughness. The compositions have improved processability by facilitating the ease with which a TPO or TPV, usually difficult to melt process, can be processed at high line speeds, which in turn improves the formation of the composition into articles.
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公开(公告)号：US20090270545A1
公开(公告)日：2009-10-29
申请号：US12108336
申请日：2008-04-23
申请人： Abdelhadi Sahnoune , Sudhin Datta , Mun Fu Tse , Charles L. Sims , James N. Coffey , Peijun Jiang
发明人： Abdelhadi Sahnoune , Sudhin Datta , Mun Fu Tse , Charles L. Sims , James N. Coffey , Peijun Jiang
IPC分类号： C08K5/01
CPC分类号： C08L23/10 , C08L23/14 , C08L23/142 , C08L2666/04
摘要： Thermoplastic polyolefins (TPOs) and/or thermoplastic vulcanizates (TPVs) are blended with low molecular weight propylene-dominated copolymers to provide polymeric compositions with an improved balance between processability and toughness. The compositions have improved processability by facilitating the ease with which a TPO or TPV, usually difficult to melt process, can be processed at high line speeds, which in turn improves the formation of the composition into articles.
摘要翻译： 将热塑性聚烯烃（TPO）和/或热塑性硫化橡胶（TPV）与低分子量丙烯主导的共聚物共混以提供加工性和韧性之间改善的平衡的聚合物组合物。 组合物通过促进TPO或TPV通常难以熔融加工的容易性，可以以高线速度加工，从而改进了组合物形成制品，从而改进了加工性能。
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