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公开(公告)号:US20140065540A1
公开(公告)日:2014-03-06
申请号:US14076724
申请日:2013-11-11
申请人: Deyan Wang , Chunyi Wu , Cong Liu , Gerhard Pohlers , Cheng-bai Xu , George G. Barclay
发明人: Deyan Wang , Chunyi Wu , Cong Liu , Gerhard Pohlers , Cheng-bai Xu , George G. Barclay
IPC分类号: G03F7/004
CPC分类号: G03F7/0397 , C08F220/18 , C08F220/24 , C08F220/32 , C08F220/34 , C08F220/36 , C08F220/38 , C08F220/58 , C08F226/06 , C08F2220/1833 , C08F2220/283 , G03F7/0045 , G03F7/0046 , G03F7/09 , G03F7/2041
摘要: A polymer includes the polymerized product of monomers including a nitrogen-containing monomer comprising formula (Ia), formula (Ib), or a combination of formulas (Ia) and (Ib), and an acid-deprotectable monomer having the formula (II): wherein a, L1, LN, Ra, Rb, Rc, and X are defined herein. The polymer is a useful component of a photoresist composition.
摘要翻译: 聚合物包括包含式(Ia),式(Ib)或式(Ia)和(Ib)的组合的含氮单体的单体的聚合产物和具有式(II)的酸可脱保护的单体, :其中a,L1,LN,Ra,Rb,Rc和X在本文中定义。 聚合物是光致抗蚀剂组合物的有用组分。
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2.
公开(公告)号:US08722825B2
公开(公告)日:2014-05-13
申请号:US13482574
申请日:2012-05-29
申请人: Deyan Wang , Chunyi Wu , Cong Liu , Gerhard Pohlers , Cheng-bai Xu , George G. Barclay
发明人: Deyan Wang , Chunyi Wu , Cong Liu , Gerhard Pohlers , Cheng-bai Xu , George G. Barclay
IPC分类号: C08F226/06 , C08F214/18 , C08F220/34
CPC分类号: G03F7/0397 , C08F220/18 , C08F220/24 , C08F220/32 , C08F220/34 , C08F220/36 , C08F220/38 , C08F220/58 , C08F226/06 , C08F2220/1833 , C08F2220/283 , G03F7/0045 , G03F7/0046 , G03F7/09 , G03F7/2041
摘要: A polymer comprises the polymerized product of monomers comprising a nitrogen-containing monomer comprising formula (Ia), formula (Ib), or a combination of formulas (Ia) and (Ib), and an acid-deprotectable monomer having the formula (II): wherein a is 0 or 1, each Ra is independently H, F, C1-10 alkyl, or C1-10 fluoroalkyl, L1 is a straight chain or branched C1-20 alkylene group, or a monocyclic, polycyclic, or fused polycyclic C3-20 cycloalkylene group, each Rb is independently H, C1-10 alkyl, C3-20 cycloalkyl, C3-20 heterocycloalkyl, an aliphatic C5-20 oxycarbonyl, or a C1-30 acyl group optionally including a heteroatom substituent group, where each Rb is separate or at least one Rb is attached to an adjacent Rb; LN is a nitrogen-containing monocyclic, polycyclic, or fused polycyclic C3-20 heterocycloalkylene group, and X is H, C1-10 alkyl, aliphatic C5-20 oxycarbonyl, or a C1-30 acyl group optionally including a heteroatom substituent group; and each Rc is independently C1-10 alkyl, C3-20 cycloalkyl, or C3-20 heterocycloalkyl, wherein each Rc is separate or at least one Rc is attached to an adjacent Rc.
摘要翻译: 聚合物包含包含式(Ia),式(Ib)或式(Ia)和(Ib)的组合的含氮单体的单体的聚合产物和具有式(II)的酸可去保护的单体, :其中a为0或1,每个R a独立地为H,F,C 1-10烷基或C 1-10氟烷基,L 1为直链或支链C 1-20亚烷基,或单环,多环或稠合多环C3 -20个亚环烷基,每个R b独立地为H,C 1-10烷基,C 3-20环烷基,C 3-20杂环烷基,脂族C 5-20氧羰基或任选地包含杂原子取代基的C1-30酰基,其中每个R b 是分开的或至少一个Rb连接到相邻的Rb; LN是含氮单环,多环或稠合多环C 3-20杂环亚烷基,X是H,C 1-10烷基,脂肪族C 5-20氧羰基或任选包含杂原子取代基的C 1-3酰基; 并且每个R c独立地为C 1-10烷基,C 3-20环烷基或C 3-20杂环烷基,其中每个R c是分开的或至少一个R c连接到相邻的Rc。
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3.
公开(公告)号:US20130137035A1
公开(公告)日:2013-05-30
申请号:US13482574
申请日:2012-05-29
申请人: Deyan Wang , Chunyi Wu , Cong Liu , Gerhard Pohlers , Cheng-bai Xu , George G. Barclay
发明人: Deyan Wang , Chunyi Wu , Cong Liu , Gerhard Pohlers , Cheng-bai Xu , George G. Barclay
IPC分类号: C08F220/34 , C08F226/06
CPC分类号: G03F7/0397 , C08F220/18 , C08F220/24 , C08F220/32 , C08F220/34 , C08F220/36 , C08F220/38 , C08F220/58 , C08F226/06 , C08F2220/1833 , C08F2220/283 , G03F7/0045 , G03F7/0046 , G03F7/09 , G03F7/2041
摘要: A polymer comprises the polymerized product of monomers comprising a nitrogen-containing monomer comprising formula (Ia), formula (Ib), or a combination of formulas (Ia) and (Ib), and an acid-deprotectable monomer having the formula (II): wherein a is 0 or 1, each Ra is independently H, F, C1-10 alkyl, or C1-10 fluoroalkyl, L1 is a straight chain or branched C1-20 alkylene group, or a monocyclic, polycyclic, or fused polycyclic C3-20 cycloalkylene group, each Rb is independently H, C1-10 alkyl, C3-20 cycloalkyl, C3-20 heterocycloalkyl, an aliphatic C5-20 oxycarbonyl, or a C1-30 acyl group optionally including a heteroatom substituent group, where each Rb is separate or at least one Rb is attached to an adjacent Rb; LN is a nitrogen-containing monocyclic, polycyclic, or fused polycyclic C3-20 heterocycloalkylene group, and X is H, C1-10 alkyl, aliphatic C5-20 oxycarbonyl, or a C1-30 acyl group optionally including a heteroatom substituent group; and each Rc is independently C1-10 alkyl, C3-20 cycloalkyl, or C3-20 heterocycloalkyl, wherein each Rc is separate or at least one Rc is attached to an adjacent Rc.
摘要翻译: 聚合物包含包含式(Ia),式(Ib)或式(Ia)和(Ib)的组合的含氮单体的单体的聚合产物和具有式(II)的酸可去保护的单体, :其中a为0或1,每个R a独立地为H,F,C 1-10烷基或C 1-10氟烷基,L 1为直链或支链C 1-20亚烷基,或单环,多环或稠合多环C3 -20个亚环烷基,每个R b独立地为H,C 1-10烷基,C 3-20环烷基,C 3-20杂环烷基,脂族C 5-20氧羰基或任选地包含杂原子取代基的C1-30酰基,其中每个R b 是分开的或至少一个Rb连接到相邻的Rb; LN是含氮单环,多环或稠合多环C 3-20杂环亚烷基,X是H,C 1-10烷基,脂肪族C 5-20氧羰基或任选包含杂原子取代基的C 1-3酰基; 并且每个R c独立地为C 1-10烷基,C 3-20环烷基或C 3-20杂环烷基,其中每个R c是分开的或至少一个R c连接到相邻的Rc。
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公开(公告)号:US20120301823A1
公开(公告)日:2012-11-29
申请号:US13482559
申请日:2012-05-29
申请人: Gregory P. Prokopowicz , Gerhard Pohlers , Mingqi Li , Chunyi Wu , Cong Liu , Cheng-bai Xu
发明人: Gregory P. Prokopowicz , Gerhard Pohlers , Mingqi Li , Chunyi Wu , Cong Liu , Cheng-bai Xu
IPC分类号: C08F224/00 , G03F7/004
CPC分类号: C08F214/186 , C08F214/18 , C08F220/28 , G03F7/0046 , G03F7/0397 , C08F2220/283 , C08F2220/185 , C08F220/32
摘要: A copolymer comprises the polymerized product of a base-soluble monomer of formula (I): wherein Ra is H, F, C1-10 alkyl, or C1-10 fluoroalkyl, L1 is an m valent C2-30 alkylene, C3-30 cycloalkylene, C6-30 arylene, C7-30 aralkylene group, X1 is independently a base-soluble organic group comprising β-diketone, β-ester-ketone, β-di-ester, or a combination comprising at least one of the foregoing; and an additional monomer copolymerizable with the base-soluble monomer of formula (I).
摘要翻译: 共聚物包含式(I)的可溶于碱的单体的聚合产物:其中R a是H,F,C 1-10烷基或C 1-10氟烷基,L 1是m价的C 2-30亚烷基,C 3-30亚环烷基 ,C 6-30亚芳基,C 3-30亚烷基,X 1独立地为包含二 - 二酮,二酯 - 酮,二 - 二酯的基础可溶性有机基团,或包含至少一种 前面的; 和可与式(I)的碱溶性单体共聚的另外的单体。
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公开(公告)号:US08603728B2
公开(公告)日:2013-12-10
申请号:US13482559
申请日:2012-05-29
申请人: Gregory P. Prokopowicz , Gerhard Polhers , Mingqi Li , Chunyi Wu , Cong Liu , Cheng-bai Xu
发明人: Gregory P. Prokopowicz , Gerhard Polhers , Mingqi Li , Chunyi Wu , Cong Liu , Cheng-bai Xu
IPC分类号: G03F7/039 , C08F214/18 , C08F218/14 , C08F22/14
CPC分类号: C08F214/186 , C08F214/18 , C08F220/28 , G03F7/0046 , G03F7/0397 , C08F2220/283 , C08F2220/185 , C08F220/32
摘要: A copolymer comprises the polymerized product of a base-soluble monomer of formula (I): wherein Ra is H, F, C1-10 alkyl, or C1-10 fluoroalkyl, L1 is an m valent C2-30 alkylene, C3-30 cycloalkylene, C6-30 arylene, C7-30 aralkylene group, X1 is independently a base-soluble organic group comprising β-diketone, β-ester-ketone, β-di-ester, or a combination comprising at least one of the foregoing; and an additional monomer copolymerizable with the base-soluble monomer of formula (I).
摘要翻译: 共聚物包含式(I)的可溶于碱的单体的聚合产物:其中R a是H,F,C 1-10烷基或C 1-10氟代烷基,L 1是m价C 2-30亚烷基,C 3-30亚环烷基 ,C 6-30亚芳基,C 3-30亚烷基,X 1独立地是包含β-二酮,β-酯 - 酮,β-二酯或包含前述的至少一种的组合的基础可溶性有机基团; 和可与式(I)的碱溶性单体共聚的另外的单体。
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公开(公告)号:US09507259B2
公开(公告)日:2016-11-29
申请号:US13482595
申请日:2012-05-29
申请人: Mingqi Li , Emad Aqad , Cong Liu , Ching-Lung Chen , Shintaro Yamada , Cheng-bai Xu , Joseph Mattia
发明人: Mingqi Li , Emad Aqad , Cong Liu , Ching-Lung Chen , Shintaro Yamada , Cheng-bai Xu , Joseph Mattia
CPC分类号: G03F7/004 , G03F7/0045 , G03F7/0397
摘要: A photoresist composition comprises an acid-sensitive polymer, and a cyclic sulfonium compound having the formula: (Ra)1—(Ar)—S+(—CH2—)m·−O3S—(CRb2)n-(L)p-X wherein each Ra is independently a substituted or unsubstituted C1-30 alkyl group, C6-30 aryl group, C7-30 aralkyl group, or combination comprising at least one of the foregoing, Ar is a monocyclic, polycyclic, or fused polycyclic C6-30 aryl group, each Rb is independently H, F, a linear or branched C1-10 fluoroalkyl or a linear or branched heteroatom-containing C1-10 fluoroalkyl, L is a C1-30 linking group optionally comprising a heteroatom comprising O, S, N, F, or a combination comprising at least one of the foregoing heteroatoms, X is a substituted or unsubstituted, C5 or greater monocyclic, polycyclic or fused polycyclic cycloaliphatic group, optionally comprising a heteroatom comprising O, S, N, F, or a combination comprising at least one of the foregoing, and 1 is an integer of 0 to 4, m is an integer of 3 to 20, n is an integer of 0 to 4, and p is an integer of 0 to 2.
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公开(公告)号:US20130137038A1
公开(公告)日:2013-05-30
申请号:US13482595
申请日:2012-05-29
申请人: Mingqi Li , Amad Aqad , Cong Liu , Ching-Lung Chen , Shintaro Yamada , Cheng-bai Xu , Joseph Mattia
发明人: Mingqi Li , Amad Aqad , Cong Liu , Ching-Lung Chen , Shintaro Yamada , Cheng-bai Xu , Joseph Mattia
IPC分类号: G03F7/004
CPC分类号: G03F7/004 , G03F7/0045 , G03F7/0397
摘要: A photoresist composition comprises an acid-sensitive polymer, and a cyclic sulfonium compound having the formula: (Ra)1—(Ar)—S+(—CH2—)m·−O3S—(CRb2)n-(L)p-X wherein each Ra is independently a substituted or unsubstituted C1-30 alkyl group, C6-30 aryl group, C7-30 aralkyl group, or combination comprising at least one of the foregoing, Ar is a monocyclic, polycyclic, or fused polycyclic C6-30 aryl group, each Rb is independently H, F, a linear or branched C1-10 fluoroalkyl or a linear or branched heteroatom-containing C1-10 fluoroalkyl, L is a C1-30 linking group optionally comprising a heteroatom comprising O, S, N, F, or a combination comprising at least one of the foregoing heteroatoms, X is a substituted or unsubstituted, C5 or greater monocyclic, polycyclic or fused polycyclic cycloaliphatic group, optionally comprising a heteroatom comprising O, S, N, F, or a combination comprising at least one of the foregoing, and 1 is an integer of 0 to 4, m is an integer of 3 to 20, n is an integer of 0 to 4, and p is an integer of 0 to 2.
摘要翻译: 光致抗蚀剂组合物包含酸敏感性聚合物和具有下式的环状锍化合物:(Ra)1-(Ar)-S +( - CH2-)m·-O3S-(CRb2)n-(L) R a独立地是取代或未取代的C 1-30烷基,C 6-30芳基,C 3-30芳烷基或包含至少一个前述的组合,Ar是单环,多环或稠合多环C 6-30芳基 ,每个R b独立地是H,F,直链或支链C 1-10氟代烷基或含有直链或支链含杂原子的C 1-10氟代烷基,L是任选地包含O,S,N,F 或包含至少一个前述杂原子的组合,X是取代或未取代的C5或更大单环,多环或稠合的多环脂环族基团,任选地包含包含O,S,N,F的杂原子,或包含在 上述中的至少一个,1为0〜4的整数,m为3〜20的整数,n为In 0〜4的整数,p为0〜2的整数。
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