摘要:
Water-repellent plaster compositions comprising the constituents(A) 100 parts by weight of gypsum plaster,(B) from 0.05 to 50 parts by weight of oxide or hydroxide of alkali or alkaline earth metals or a mixture thereof, and(C) from 0.05 to 20 parts by weight of an organopolysiloxane which has hydroxyl and/or alkoxy groups bonded to silicon atoms.
摘要:
Coating compositions based on water-redispersible powders comprising water-soluble polymer and organosilicon compounds, wherein the organosilicon compounds comprise at least one low molecular weight organosilicon compound having a viscosity of not more than 5,000 mm.sup.2 /s at 25.degree. C. and at least one high molecular weight organopolysiloxane resin which has a viscosity of at least 100,000 mm.sup.2 /s at 25.degree. C. or is solid at room temperature.
摘要:
Alkoxysilyl-terminated prepolymers in which the alkoxysilyl group is linked to a tertiary nitrogen group through a Cl carbon spacer exhibit excellent moisture curing reactivity and yet are easily prepared. The tertiary nitrogen group-containing α-aminoalkoxysilyl group is introduced into the prepolymer by reacting a tertiary nitrogen group-containing α-aminoalkoxysilane with an isocyanate-terminated prepolymer or isocyanate-functional precursor thereof.
摘要:
A process for preparing organosilazane and ammonium chloride, by reaction of an organochlorosilane with ammonia in the presence of organosilazane as solvent, wherein ammonium chloride is removed from the resulting organosilazane and ammonium chloride-containing mixture, the improvement comprising adding an antiblocking agent to the mixture before removal, or to the ammonium chloride after its removal, such that a non-blocking, reusable ammonium chloride product is obtained.
摘要:
A process for preparing an organopolysiloxane resin, which comprises reacting in a first stage at least one silane of the formulaR.sub.a Si(OR.sup.1).sub.4-a (I)in which a is 0, 1, 2 or 3, R is a monovalent organic radical, and/or a partial hydrolyzate thereof, with the proviso that at least one silane of formula (I) in which a is equal to 0 or 1, and/or a partial hydrolyzate thereof, is employed, and, if appropriate, an organo(poly) siloxane with water in the presence of acid and, if appropriate, other substances, in a second stage reacting the reaction mixture obtained from the first stage in the presence of base and, if appropriate, other substances, and in a third stage adding with stirring, the reaction mixture obtained in the second stage into water, and if appropriate mixed with additives.
摘要翻译:一种制备有机聚硅氧烷树脂的方法,其包括在第一阶段使至少一种式R a Si(OR 1)4-a(I)的硅烷,其中a是0,1,2或3,R是一价有机基团 ,和/或其部分水解产物,条件是使用至少一种其中a等于0或1的式(I)的硅烷和/或其部分水解产物,并且如果合适,使用有机物 (多)硅氧烷在酸的存在下,如果合适的话,在适当的情况下,在其它物质的存在下,在第二阶段中,在碱的存在下,如果合适的话,在第三阶段使第一阶段获得的反应混合物反应,并在第三阶段 搅拌下加入第二阶段得到的反应混合物,并加入添加剂。
摘要:
Silicone foams having good foam structure and rapid cure are produced from foamable mixtures containing a physical blowing agent and an organically modified organopolysiloxane containing at least one urea or urethane group and an alkoxy(alkyl)siloxy unit.
摘要:
Particles of metal and non-metal oxides may be readily functionalized with organosilyl groups, even in the absence of catalysts, when methylene-spaced alkoxysilanes are used for functionalizing. When an excess of alkoxy groups relative to metal-OH groups are present, the resulting functionalized particles exhibit high reactivity, particularly upon exposure to moisture. Functionalization is particularly useful with particles of organopolysiloxane resins.
摘要:
α-aminoalkoxysilanes wherein the α-amino group is a tertiary amino group, and which also contains a further reactive group, display excellent reactivity of the alkoxy groups while remaining stable with respect to decomposition and byproduct formation, particularly through cleavage of the Si-C bond. The α-aminosilanes are particularly useful for preparing alkoxysilyl-terminated prepolymers which exhibit high cure rates in the presence of moisture, and for functionalizing particles reactive therewith.
摘要:
Alkoxysilyl-terminated preopolymers prepared by reacting an alkoxysilane with a prepolymer prepared by reacting a di- or polyisocyanate with both a low molecular weight diol or polyol and a high molecular weight polyol, the respective polyol components present within a specific ratio range, and giving rise to an increased content of urethane groups, and an inhomogenous distribution thereof exhibit high tensile strength and elongation, even without the use of fillers.
摘要:
Organopolysiloxane resin powders having a mean particle diameter (median value d.sub.50,3) of from 70 to 300 .mu.m and a proportion of resin particles having a diameter