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1.发明授权Platelet-shaped, copper-containing, metallic effect pigments, process for preparing them and use thereof 有权血小板形，含铜金属效应颜料，其制备方法和用途公开(公告)号：US08163079B2
公开(公告)日：2012-04-24
申请号：US12992911
申请日：2009-05-28
申请人： Dieter Proelss , Ralf Deinzer , Wolfgang Herzing , Andreas Kroell , Stefan Trummer , Michael Becker , Katrin Wczasek
发明人： Dieter Proelss , Ralf Deinzer , Wolfgang Herzing , Andreas Kroell , Stefan Trummer , Michael Becker , Katrin Wczasek
CPC分类号： C09C1/66 , A61K8/11 , A61K8/19 , A61K2800/412 , A61K2800/413 , A61K2800/43 , A61K2800/436 , A61Q1/02 , B82Y5/00 , C01P2004/03 , C01P2004/54 , C01P2004/61 , C01P2004/86 , C09C1/622 , C09C1/627 , C09D11/02 , C09D11/037 , Y10T428/2982 , Y10T428/2991 , Y10T428/31678
摘要： Platelet-shaped, copper-containing, metallic effect pigments which have a copper content of 60% to 100% by weight, based on the total metal content, the metal pigments having a thickness distribution as determined via thickness counting by scanning electron microscopy (SEM) and represented as cumulative undersize distribution, a) with an h50 of 10 to 50 nm, and b) with an h90 of 20 to 70 nm, the platelet-shaped, copper-containing, metallic effect pigments being produced by milling a copper-containing metal powder with lubricant. The disclosure further relates to a process for producing these pigments, and also to their use, to a printing ink comprising the pigments of the invention, and to a coated article comprising these pigments.
摘要翻译： 基于总金属含量，铜含量为60〜100重量％的片状铜，金属效果颜料，金属颜料具有通过扫描电子显微镜（SEM）的厚度计数确定的厚度分布 ），并且表示为累积尺寸分布，a）具有10至50nm的h 50，以及b）具有20至70nm的h90，所述片状，含铜金属效应颜料通过研磨铜 - 含有润滑剂的金属粉末。 本公开进一步涉及一种生产这些颜料的方法，以及它们用于包含本发明颜料的印刷油墨和包含这些颜料的涂布制品。
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2.发明申请PLATELET-SHAPED, COPPER-CONTAINING, METALLIC EFFECT PIGMENTS, PROCESS FOR PREPARING THEM AND USE THEREOF 有权板形，含铜，金属效应颜料，其制备方法及其用途公开(公告)号：US20110179971A1
公开(公告)日：2011-07-28
申请号：US12992911
申请日：2009-05-28
申请人： Dieter Proelss , Ralf Deinzer , Wolfgang Herzing , Andreas Kroell , Stefan Trummer , Michael Becker , Katrin Wczasek
发明人： Dieter Proelss , Ralf Deinzer , Wolfgang Herzing , Andreas Kroell , Stefan Trummer , Michael Becker , Katrin Wczasek
CPC分类号： C09C1/66 , A61K8/11 , A61K8/19 , A61K2800/412 , A61K2800/413 , A61K2800/43 , A61K2800/436 , A61Q1/02 , B82Y5/00 , C01P2004/03 , C01P2004/54 , C01P2004/61 , C01P2004/86 , C09C1/622 , C09C1/627 , C09D11/02 , C09D11/037 , Y10T428/2982 , Y10T428/2991 , Y10T428/31678
摘要： Platelet-shaped, copper-containing, metallic effect pigments which have a copper content of 60% to 100% by weight, based on the total metal content, the metal pigments having a thickness distribution as determined via thickness counting by scanning electron microscopy (SEM) and represented as cumulative undersize distribution, a) with an h50 of 10 to 50 nm, and b) with an h90 of 20 to 70 nm, the platelet-shaped, copper-containing, metallic effect pigments being produced by milling a copper-containing metal powder with lubricant. The disclosure further relates to a process for producing these pigments, and also to their use, to a printing ink comprising the pigments of the invention, and to a coated article comprising these pigments.
摘要翻译： 基于总金属含量，铜含量为60〜100重量％的片状铜，金属效果颜料，金属颜料具有通过扫描电子显微镜（SEM）的厚度计数确定的厚度分布 ），并且表示为累积尺寸分布，a）具有10至50nm的h 50，以及b）具有20至70nm的h90，所述片状，含铜金属效应颜料通过研磨铜 - 含有润滑剂的金属粉末。 本公开进一步涉及一种生产这些颜料的方法，以及它们用于包含本发明颜料的印刷油墨和包含这些颜料的涂布制品。
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公开(公告)号：US20100279083A1
公开(公告)日：2010-11-04
申请号：US12810916
申请日：2008-12-19
申请人： Stefan Trummer , Andreas Kroell , Dieter Proelss , Stefan Engel , Werner Pieper , Joerg Maening
发明人： Stefan Trummer , Andreas Kroell , Dieter Proelss , Stefan Engel , Werner Pieper , Joerg Maening
CPC分类号： C09D11/322 , B41J2/01 , C01P2004/20 , C01P2004/51 , C01P2004/52 , C01P2004/54 , C01P2004/61 , C09C1/642 , C09D11/101 , C09D17/006 , Y10T428/24802
摘要： The present disclosure is directed to a pigment preparation comprising aluminum effect pigments, a solvent and at least one additive, wherein the aluminium effect pigments have a d98 value of the volume averaged particle size distribution curve of less than 15 μm, the at least one additive is a phosphorous containing additive, and the solvent has a viscosity equal to or more than 1.8 mPa·s at 25° C. The disclosure is further directed to an ink jet printing ink as well the use thereof.
摘要翻译： 本公开涉及包含铝效应颜料，溶剂和至少一种添加剂的颜料制剂，其中铝效应颜料具有小于15μm的体积平均粒度分布曲线的d98值，所述至少一种添加剂 是含磷添加剂，并且溶剂在25℃下的粘度等于或大于1.8mPa·s。本发明还涉及喷墨印刷油墨及其用途。
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公开(公告)号：US08333832B2
公开(公告)日：2012-12-18
申请号：US12810916
申请日：2008-12-19
申请人： Joerg Maennig , Stefan Trummer , Andreas Kroell , Dieter Proelss , Stefan Engel , Werner Pieper
发明人： Joerg Maennig , Stefan Trummer , Andreas Kroell , Dieter Proelss , Stefan Engel , Werner Pieper
CPC分类号： C09D11/322 , B41J2/01 , C01P2004/20 , C01P2004/51 , C01P2004/52 , C01P2004/54 , C01P2004/61 , C09C1/642 , C09D11/101 , C09D17/006 , Y10T428/24802
摘要： The present disclosure is directed to a pigment preparation comprising aluminum effect pigments, a solvent and at least one additive, wherein the aluminum effect pigments have a d98 value of the volume averaged particle size distribution curve of less than 15 μm, the at least one additive is a phosphorous containing additive, and the solvent has a viscosity equal to or more than 1.8 mPa's at 25° C. The disclosure is further directed to an ink jet printing ink as well the use thereof.
摘要翻译： 本公开涉及包含铝效应颜料，溶剂和至少一种添加剂的颜料制剂，其中铝效应颜料具有小于15μm的体积平均粒度分布曲线的d98值，所述至少一种添加剂 是含磷添加剂，并且溶剂在25℃下的粘度等于或大于1.8mPa·s。本发明还涉及喷墨印刷油墨及其用途。
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5.发明授权Mixture of copper-containing metal effect pigments and method for the production thereof 有权含铜金属效应颜料的混合物及其制造方法公开(公告)号：US08157909B2
公开(公告)日：2012-04-17
申请号：US12993128
申请日：2009-05-28
申请人： Katrin Wczasek , Michael Becker , Svea Heitmar , Dieter Proelss
发明人： Katrin Wczasek , Michael Becker , Svea Heitmar , Dieter Proelss
CPC分类号： C09C1/66 , A61K8/11 , A61K8/19 , A61K2800/412 , A61K2800/413 , A61K2800/43 , A61K2800/436 , A61Q1/02 , B82Y5/00 , C01P2004/03 , C01P2004/54 , C01P2004/61 , C01P2004/86 , C09C1/622 , C09C1/627 , C09D11/02 , C09D11/037 , Y10T428/2982 , Y10T428/2991 , Y10T428/31678
摘要： A mixture of platelet-shaped, copper-containing metallic effect pigments having a copper content of 60% to 100% by weight, based on the total metal content, with at least one further component, where the copper-containing metallic effect pigments have a thickness distribution, determined via thickness counting by scanning electron microscopy (SEM) and represented as cumulative undersize distribution, a) with an h50 of 10 to 100 nm, and b) with an h90 of 20 to 150 nm, and in that the at least one further component is a cellulose derivative selected from the group consisting of alkylcellulose, hydroxyalkylcellulose, alkyl(hydroxyalkyl)cellulose, and mixtures thereof, and/or is at least one additive having antioxidative and/or radical-inhibiting properties. The disclosure further relates to a method for producing this mixture, and to a coating composition.
摘要翻译： 含有金属含量的铜含量为60〜100重量％的含有铜的金属效应颜料与至少一种其他组分的混合物，其中含铜金属效应颜料具有 厚度分布，通过扫描电子显微镜（SEM）通过厚度计数确定并表示为累积尺寸分布，a）具有10至100nm的h 50，以及b）具有20至150nm的h90，并且至少 另一组分是选自烷基纤维素，羟烷基纤维素，烷基（羟烷基）纤维素及其混合物的纤维素衍生物，和/或至少一种具有抗氧化和/或自由基抑制性质的添加剂。 本公开进一步涉及一种生产该混合物的方法和一种涂料组合物。
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6.发明申请MIXTURE OF COPPER-CONTAINING METAL EFFECT PIGMENTS AND METHOD FOR THE PRODUCTION THEREOF 有权含铜金属效应颜料的混合物及其生产方法公开(公告)号：US20110139034A1
公开(公告)日：2011-06-16
申请号：US12993128
申请日：2009-05-28
申请人： Katrin Wczasek , Michael Becker , Svea Heitmar , Dieter Proelss
发明人： Katrin Wczasek , Michael Becker , Svea Heitmar , Dieter Proelss
CPC分类号： C09C1/66 , A61K8/11 , A61K8/19 , A61K2800/412 , A61K2800/413 , A61K2800/43 , A61K2800/436 , A61Q1/02 , B82Y5/00 , C01P2004/03 , C01P2004/54 , C01P2004/61 , C01P2004/86 , C09C1/622 , C09C1/627 , C09D11/02 , C09D11/037 , Y10T428/2982 , Y10T428/2991 , Y10T428/31678
摘要： A mixture of platelet-shaped, copper-containing metallic effect pigments having a copper content of 60% to 100% by weight, based on the total metal content, with at least one further component, where the copper-containing metallic effect pigments have a thickness distribution, determined via thickness counting by scanning electron microscopy (SEM) and represented as cumulative undersize distribution, a) with an h50 of 10 to 100 nm, and b) with an h90 of 20 to 150 nm, and in that the at least one further component is a cellulose derivative selected from the group consisting of alkylcellulose, hydroxyalkylcellulose, alkyl(hydroxyalkyl)cellulose, and mixtures thereof, and/or is at least one additive having antioxidative and/or radical-inhibiting properties. The disclosure further relates to a method for producing this mixture, and to a coating composition.
摘要翻译： 含有金属含量的铜含量为60〜100重量％的含有铜的金属效应颜料与至少一种其他组分的混合物，其中含铜金属效应颜料具有 厚度分布，通过扫描电子显微镜（SEM）通过厚度计数确定并表示为累积尺寸分布，a）具有10至100nm的h 50，以及b）具有20至150nm的h90，并且至少 另一组分是选自烷基纤维素，羟烷基纤维素，烷基（羟烷基）纤维素及其混合物的纤维素衍生物，和/或至少一种具有抗氧化和/或自由基抑制性质的添加剂。 本公开进一步涉及一种生产该混合物的方法和一种涂料组合物。
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公开(公告)号：US09931524B2
公开(公告)日：2018-04-03
申请号：US12994879
申请日：2009-05-28
申请人： Dieter Proelss , Stefan Trummer , Stephan Roth , Bärbel Gertzen , Wolfgang Pritschins , Jürgen Omeis
发明人： Dieter Proelss , Stefan Trummer , Stephan Roth , Bärbel Gertzen , Wolfgang Pritschins , Jürgen Omeis
IPC分类号： A61Q19/00 , A61K8/11 , A61K8/86 , C09D5/36 , C09C1/66 , C09C1/64 , A61K8/39 , C09C1/62 , C09D7/12 , C08K3/08 , C08K9/04
CPC分类号： A61Q19/00 , A61K8/11 , A61K8/39 , A61K8/86 , A61K2800/412 , A61K2800/413 , A61K2800/43 , C01P2004/54 , C01P2004/61 , C01P2004/86 , C01P2006/60 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C01P2006/65 , C01P2006/66 , C08K3/08 , C08K9/04 , C09C1/62 , C09C1/622 , C09C1/625 , C09C1/646 , C09C1/66 , C09D5/36 , C09D7/62
摘要： A metallic effect pigment with an additive, the additive being applied on at least a portion of the metallic effect pigment. The additive comprises, as structural units, at least one carboxylic acid having at least 4 carbon atoms and also at least one polyglycol ether. The carboxylic acid and the polyglycol ether are bonded covalently to one another. The disclosure is also directed to a method for producing these metallic effect pigments, and to the use thereof, as well as to a printing ink comprising the pigments.
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公开(公告)号：US20110094412A1
公开(公告)日：2011-04-28
申请号：US12994879
申请日：2009-05-28
申请人： Dieter Proelss , Stefan Trummer , Stephan Roth , Bärbel Gertzen , Wolfgang Pritschins , Jürgen Omeis
发明人： Dieter Proelss , Stefan Trummer , Stephan Roth , Bärbel Gertzen , Wolfgang Pritschins , Jürgen Omeis
CPC分类号： A61Q19/00 , A61K8/11 , A61K8/39 , A61K8/86 , A61K2800/412 , A61K2800/413 , A61K2800/43 , C01P2004/54 , C01P2004/61 , C01P2004/86 , C01P2006/60 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C01P2006/65 , C01P2006/66 , C08K3/08 , C08K9/04 , C09C1/62 , C09C1/622 , C09C1/625 , C09C1/646 , C09C1/66 , C09D5/36 , C09D7/62
摘要： A metallic effect pigment with an additive, the additive being applied on at least a portion of the metallic effect pigment. The additive comprises, as structural units, at least one carboxylic acid having at least 4 carbon atoms and also at least one polyglycol ether. The carboxylic acid and the polyglycol ether are bonded covalently to one another. The disclosure is also directed to a method for producing these metallic effect pigments, and to the use thereof, as well as to a printing ink comprising the pigments.
摘要翻译： 一种具有添加剂的金属效应颜料，该添加剂被施加在金属效应颜料的至少一部分上。 作为结构单元的添加剂包含至少一种具有至少4个碳原子的羧酸和至少一种聚乙二醇醚。 羧酸和聚乙二醇醚彼此共价键合。 本发明还涉及一种用于生产这些金属效应颜料的方法及其用途，以及包含颜料的印刷油墨。
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