Graft polymers of .epsilon.-caprolactam
    3.
    发明授权
    Graft polymers of .epsilon.-caprolactam 失效
    ε-己内酰胺接枝聚合物

    公开(公告)号:US5342894A

    公开(公告)日:1994-08-30

    申请号:US852366

    申请日:1992-03-13

    CPC分类号: C08G69/14 C08G69/20

    摘要: Graft copolymers of .epsilon.-caprolactam are made by a process in which .epsilon.-caprolactam is polymerized in the presence of a copolymer of an aliphatic acrylate and an ethylenically unsaturated carboxylic acid, such as n-butylacrylate and acrylic acid. Such grafted polymers which have nylon-6 side chains grafted onto the acrylate polymer backbone are useful as hot melt adhesives. In the process for preparing these polymers, the backbone polymer is formed initially by solution polymerization at a moderate temperature and the .epsilon.-caprolactam is then added and the temperature increased in the presence of an acidic catalyst. .epsilon.-Caprolactam can be used as the solvent in the polymerization of the backbone polymer.

    摘要翻译: ε-己内酰胺的接枝共聚物通过其中ε-己内酰胺在脂族丙烯酸酯和烯键式不饱和羧酸的共聚物如丙烯酸正丁酯和丙烯酸的共聚物存在下聚合的方法制备。 具有接枝到丙烯酸酯聚合物主链上的尼龙-6侧链的这种接枝聚合物可用作热熔粘合剂。 在制备这些聚合物的方法中,主要聚合物最初通过在中等温度下的溶液聚合形成,然后加入ε-己内酰胺并在酸性催化剂存在下升高温度。 ε-己内酰胺可用作主链聚合物聚合中的溶剂。