Phosphorous-containing compounds as adjuvant for positive electrostatic
liquid developers
    1.
    发明授权
    Phosphorous-containing compounds as adjuvant for positive electrostatic liquid developers 失效
    含磷化合物作为阳性静电液体显影剂的佐剂

    公开(公告)号:US4917986A

    公开(公告)日:1990-04-17

    申请号:US292191

    申请日:1988-12-30

    IPC分类号: G03G9/12 G03G9/135

    CPC分类号: G03G9/135 G03G9/1355

    摘要: A positive, liquid electrostatic developer consisting essentially of(A) a nonpolar liquid having a Kauri-butanol value of less than 30, present in a major amount,(B) thermoplastic resin particles having dispersed therein a phosphorous-containing compound defined herein which is substantially insoluble or immiscible in the nonpolar liquid at ambient temperatures, the resin particles having an average by area particle size of less than 10 .mu.m, and(C) a nonpolar liquid soluble ionic or zwitterionic charge director compound, and process for preparation. The liquid developer is useful in copying, color proofing including digital color proofing, lithographic printing plates and resists.

    Organic sulfur-containing compounds as adjuvants for positive
electrostatic liquid developers
    3.
    发明授权
    Organic sulfur-containing compounds as adjuvants for positive electrostatic liquid developers 失效
    有机含硫化合物作为正静电液体显影剂的佐剂

    公开(公告)号:US4917985A

    公开(公告)日:1990-04-17

    申请号:US292291

    申请日:1988-12-30

    IPC分类号: G03G9/12 G03G9/135

    CPC分类号: G03G9/1355 G03G9/135

    摘要: Positive electrostatic liquid developer consisting essentially of(A) nonpolar liquid having Kauri-butanol value less than 30, present in major amount,(B) thermoplastic resin particles having an organic sulfur-containing compound which is substantially insoluble in the nonpolar liquid at ambient temperatures, as defined dispersed therein and average particle size by area being less than 10 .mu.m, and(C) nonpolar liquid soluble ionic or zwitterionic charge director compound. Optionally a colorant and charge adjuvant are present. The electrostatic liquid developer is useful in copying, making proofs including digital color proofs, lithographic printing plates, and resists.

    Process for preparation of liquid electrostatic developer
    4.
    发明授权
    Process for preparation of liquid electrostatic developer 失效
    液体静电显影剂的制备方法

    公开(公告)号:US4794066A

    公开(公告)日:1988-12-27

    申请号:US116657

    申请日:1987-11-04

    IPC分类号: G03G9/13 G03G9/12

    CPC分类号: G03G9/12

    摘要: Improved liquid electrostatic developer containing electrostatic toner particles is prepared by a process wherein an aqueous, e.g., water-wet pigment cake is flushed with a water insoluble vehicle, water is removed, and the developer is formed from the flushed pigment dispersion, thermoplastic resin, dispersant nonpolar liquid having a Kauri-butanol value of less than 30, in a vessel at elevated temperature under high shear, and the dispersion is cooled. The liquid electrostatic developer is useful in copying, making proofs including digital color proofs, lithographic printing plates, and resists.

    Mineral acids as charge adjuvants for positive liquid electrostatic
developers
    5.
    发明授权
    Mineral acids as charge adjuvants for positive liquid electrostatic developers 失效
    矿物酸作为阳性液体静电显影剂的电荷佐剂

    公开(公告)号:US5034299A

    公开(公告)日:1991-07-23

    申请号:US522277

    申请日:1990-05-11

    IPC分类号: G03G9/12 G03G9/135

    CPC分类号: G03G9/135

    摘要: A positive charged electrostatic liquid developer consisting essentially of(A) a non-polar liquid having a Kauri-butanol value of less than 30,(B) thermoplastic resin particles, average by area particle size of less than 10 .mu.m,(C) a charge director compound, and(D) at least one inorganic acid having a solubility of at least 0.5% based on the weight of charge director compound in a mixture of (A) and (C) and represented by the formula:H.sub.x Y wherein x is an integer from 1-4 and is equal to the negative charge on the anion,Y is a moiety selected from the group consisting of Cl.sup.-, F.sup.-, NO.sub.3.sup.-, NO.sub.2.sup.-, PO.sub.4.sup.-3, SO.sub.4.sup.-2, SO.sub.3.sup.-2, ClO.sub.4.sup.-, and IO.sub.4.sup.-.The liquid developer is useful in copying, color proofing, digital color proofing, making lithographic printing plates, and resists.

    Bipolar liquid electrostatic developer
    6.
    发明授权
    Bipolar liquid electrostatic developer 失效
    双极液体静电显影剂

    公开(公告)号:US4985329A

    公开(公告)日:1991-01-15

    申请号:US292573

    申请日:1988-12-30

    IPC分类号: G03G9/12

    CPC分类号: G03G9/12

    摘要: Bipolar liquid electrostatic developer consisting essentially of at least one charge director in a nonpolar liquid having dispersed therein two toner particles having opposite charge polarity which comprise at least one thermoplastic copolymer resin. The particle average by area size is less than 10 .mu.m. The ratio of the two toner particles is 5 to 95 and 95 to 5. A process of simultaneous transfer of such developer is included. The developer is useful in copying.

    Metal alkoxide modified resins for negative-working electrostatic liquid
developers
    7.
    发明授权
    Metal alkoxide modified resins for negative-working electrostatic liquid developers 失效
    用于负性静电液体显影剂的金属醇盐改性树脂

    公开(公告)号:US4971883A

    公开(公告)日:1990-11-20

    申请号:US412327

    申请日:1989-09-25

    IPC分类号: G03G9/12 G03G9/13 G03G9/135

    CPC分类号: G03G9/131 G03G9/135

    摘要: Negative-working electrostatic liquid developer consisting essentially of(A) nonpolar liquid having Kauri-butanol value less than 30, present in major amount,(B) particles, average by area particle size of less than 10 .mu.m, of a polymer prepared from the reaction product of polymeric resin having free carboxyl groups and a metal alkoxide as defined, and(C) nonpolar liquid soluble ionic or zwitterionic charge director compound.Optionally a colorant and an adjuvant compound are present. Process of preparation of electrostatic liquid developers is described. The developer is useful in copying, making proofs including digital color proofs, Lithographic printing plates, and resists.

    Monofunctional amines as adjuvant for liquid electrostatic developers
    8.
    发明授权
    Monofunctional amines as adjuvant for liquid electrostatic developers 失效
    单官能胺作为液体静电显影剂的佐剂

    公开(公告)号:US4935328A

    公开(公告)日:1990-06-19

    申请号:US178962

    申请日:1988-04-07

    IPC分类号: G03G9/13 G03G9/135

    摘要: Electrostatic liquid developer having improved negative charging characteristics consisting essentially of(A) nonpolar liquid having a Kauri-butanol value of less than 30, present in a major amount,(B) thermoplastic resin particles having an average by area particle size of less than 10 .mu.m,(C) charge director compound, and(D) at least one soluble solid or liquid organic monofunctional amine compound of the formula: R.sub.n NH.sub.3-n wherein R is alkyl, cycloalkyl or alkylene, or substituted alkyl, the alkyl, cycloalkyl, alkylene or substituted alkyl group being of 1 to 50 carbon atoms, and n is an integer of 1 to 3.Optionally, a colorant, e.g., a pigment; metallic soap, adjuvant can be present. The electrostatic liquid developer is useful in copying, making proofs including digital color proofs, lithographic printing plates, and resists.

    Liquid electrostatic developers containing modified resin particles
    9.
    发明授权
    Liquid electrostatic developers containing modified resin particles 失效
    含有改性树脂颗粒的液体静电显影剂

    公开(公告)号:US4798778A

    公开(公告)日:1989-01-17

    申请号:US80669

    申请日:1987-08-03

    IPC分类号: G03G9/13 G03G9/12

    CPC分类号: G03G9/131

    摘要: A positive-working liquid electrostatic developer consisting essentially of(A) nonpolar liquid having a Kauri-butanol value of less than 30, present in major amount;(B) thermoplastic resin of an ethylene homopolymer or copolymer of ethylene and at least one other monomer, the resin having as a substituent thereon an ester, ester having substitutents, e.g., hydroxyl, carboxyl, amine, alkyl; an amide, amide having substituents, e.g., hydroxyl, carboxyl, amine, alkyl; or acid halide of a carboxylic acid, the resin being in particulate form having an average particle size by area of less than 10 .mu.m; and(C) nonpolar liquid soluble ionic or zwitterionic compound.Several procedures can be used to prepare the developer, e.g., using toner concentrate, modifying a thermoplastic resin before developer is prepared. Pigments and adjuvants can be present in the developer which is useful in copying, making proofs including digital proofs, lithographic printing plates and resists.

    Process for preparation of liquid electrostatic developers
    10.
    发明授权
    Process for preparation of liquid electrostatic developers 失效
    液体静电显影剂的制备方法

    公开(公告)号:US4783389A

    公开(公告)日:1988-11-08

    申请号:US30993

    申请日:1987-03-27

    IPC分类号: G03G9/12

    CPC分类号: G03G9/12

    摘要: Process for the preparation of toner particles for liquid electrostatic imaging comprising(A) mixing a thermoplastic resin and a nonpolar liquid at a temperature sufficient to plasticize and liquify the resin and below that at which the nonpolar liquid boils and the resin decomposes,(B) cooling the mixture to form resin particles in the nonpolar liquid,(C) reducing the size of the resin particles to below about 30 .mu.m by passing the product of step (B) through at least one liquid jet interaction chamber at a liquid pressure of at least 1000 p.s.i., e.g., a Microfluidizer.RTM..The process produces liquid electrostatic developer quicker than other known processes, the developer being useful in copying, making proofs, including digital proofs, etc.