Method for preparing high molecular weight random polyhydroxypolyamides
    1.
    发明授权
    Method for preparing high molecular weight random polyhydroxypolyamides 有权
    制备高分子量无规多羟基聚酰胺的方法

    公开(公告)号:US06894135B2

    公开(公告)日:2005-05-17

    申请号:US10734418

    申请日:2003-12-10

    摘要: High molecular weight random polyhydroxypolyamides (PHPAs) are produced by creating prepolymers which are further polymerized. Random prepolymers are formed from a stoichiometrically molar balance (1:1) starting material. The starting material is a 1:1 stoichiometrically balanced esterified aldaric acid:alkylene or alkylene derived diammonium salt. Alternatively, the starting material is an esterified stoichiometrically balanced diacid:diamine salt and a N′-ammoniumalkyl (or alkyl derived)-D-aldaramic acid terminal carboxylate zwitterionic salt mixture. The starting materials are polymerized in a basic alcohol using a second amine. The polymerized material, or the random prepolymers, are isolated and then further polymerized in a solvent, typically a mixed solvent of an alcohol and non-alcohol, to obtain the high molecular weight PHPAs.

    摘要翻译: 通过产生进一步聚合的预聚物制备高分子量无规多羟基聚酰胺(PHPAs)。 随机预聚物由化学计量摩尔平衡(1:1)原料形成。 原料是1:1化学计量平衡的酯化醛酸:亚烷基或亚烷基衍生的二铵盐。 或者,原料是酯化的化学计量平衡的二酸:二胺盐和N'-烷基(或烷基衍生的)-D-阿拉斯加酸末端羧酸酯两性离子盐混合物。 使用第二种胺将原料在碱性醇中聚合。 分离聚合的材料或无规预聚物,然后在溶剂(通常为醇和非醇的混合溶剂)中进一步聚合,得到高分子量的PTA。

    High molecular weight stereoregular head-tail poly(glucaramides)
    3.
    发明授权
    High molecular weight stereoregular head-tail poly(glucaramides) 有权
    高分子立体定向头尾聚(glucaramides)

    公开(公告)号:US07314906B2

    公开(公告)日:2008-01-01

    申请号:US10734417

    申请日:2003-12-10

    IPC分类号: C08G69/04 C08G69/10

    摘要: A method of producing high molecular weight stereoregular head, tail-poly(alkylene D-glucaramides) is described. Amidoamino acids are esterified in cold alcohol and then polymerized in a protic solvent to form steroregular prepolymers. The prepolymers are then further polymerized by dissolving them in a solvent to form larger, purer postpolymers. Compositions of matter prepared using the subject method are also described.

    摘要翻译: 描述了一种生产高分子量立构规整头,尾 - 聚(亚烷基D-葡糖酰胺)的方法。 氨基氨基酸在冷乙醇中酯化,然后在质子溶剂中聚合以形成有限元素的预聚物。 然后通过将预聚物溶解在溶剂中以形成更大,更纯的后聚合物进一步聚合。 还描述了使用本发明方法制备的物质的组成。

    Nitric acid removal from oxidation products
    9.
    发明授权
    Nitric acid removal from oxidation products 有权
    从氧化产物中除去硝酸

    公开(公告)号:US6049004A

    公开(公告)日:2000-04-11

    申请号:US209285

    申请日:1998-12-11

    摘要: A method for synthesizing and isolating an oxidation product is disclosed wherein nitric acid is reacted with an oxidizable reactant and the desired oxidized product is extracted using an organic solvent such as a dialkyl ether. The method permits the direct crystallization of aldaric acids such as glucaric acid and mannaric acid and eliminates the necessity of employing complicated, time consuming and wasteful neutralization/acidification steps.

    摘要翻译: 公开了一种用于合成和分离氧化产物的方法,其中将硝酸与可氧化的反应物反应,并使用有机溶剂如二烷基醚萃取所需的氧化产物。 该方法允许醛糖酸如葡糖二酸和甘露糖酸的直接结晶,并且消除了使用复杂,耗时和浪费的中和/酸化步骤的必要性。