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公开(公告)号：US4383977A
公开(公告)日：1983-05-17
申请号：US235484
申请日：1981-02-18
摘要： A apparatus for the catalytic alkylation of an isoparaffin with one or more olefins. Reactant hydrocarbons are passed in contact with a liquid catalyst such as hydrofluoric acid in a reaction zone. The hydrocarbon phase is allowed to separate from the catalyst phase in a settling zone, and a portion of the hydrocarbon phase is cooled and reintroduced to the reaction zone in a separate stream from that of the feed hydrocarbons. The alkylation apparatus by which the process is carried out includes a vertical reaction vessel, which in a preferred embodiment is 2 to 6 feet in height, a settling vessel, means for fluid flow from the reaction vessel to the settling vessel, a conduit for fluid flow between the upper part of the settling vessel and the reaction zone, and means for cooling fluid in this conduit.
摘要翻译： 一种用一种或多种烯烃催化烷基化异链烷烃的装置。 反应性烃在反应区中与液体催化剂如氢氟酸接触。 允许烃相在沉降区中与催化剂相分离，并且一部分烃相被冷却并以与进料烃的流分开的流重新引入反应区。 进行该方法的烷基化装置包括在优选实施方案中为高度为2至6英尺的垂直反应容器，沉降容器，用于从反应容器流向沉降容器的流体的装置，用于流体的导管 在沉降容器的上部和反应区之间的流动，以及用于在该导管中冷却流体的装置。
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2.发明授权Separation of acid-hydrocarbon emulsions and alkylation process utilizing said separation 失效使用所述分离分离酸 - 烃乳液和烷基化方法
公开(公告)号：US4056577A
公开(公告)日：1977-11-01
申请号：US741315
申请日：1976-11-11
CPC分类号： C07C9/16 , C07C2/62 , C07C7/00 , C07C2527/1206
摘要： The time for effecting separation of HF acid-hydrocarbon emulsions is substantially decreased by adding a finite amount of up to about 700 ppm of a tetraalkylammonium iodide coalescing promoter to the emulsion. The rapid separation of HF acid-hydrocarbon emulsions comprising reaction effluent obtained from alkylation processes is facilitated by the addition of a tetraalkylammonium iodide to the reaction effluent prior to phase separation.
摘要翻译： 通过向乳液中加入高达约700ppm的四烷基碘化铵聚结促进剂的有限量，实现HF酸 - 烃乳液分离的时间显着降低。 通过在相分离之前向反应流出物中加入四烷基碘化铵来促进包含由烷基化方法获得的包含反应流出物的HF酸 - 烃乳液的快速分离。
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公开(公告)号：US4276439A
公开(公告)日：1981-06-30
申请号：US81290
申请日：1979-10-02
摘要： A process and apparatus for the catalytic alkylation of an isoparaffin with one or more olefins. Reactant hydrocarbons are passed in contact with a liquid catalyst such as hydrofluoric acid in a reaction zone. The hydrocarbon phase is allowed to separate from the catalyst phase in a settling zone, and a portion of the hydrocarbon phase is cooled and reintroduced to the reaction zone in a separate stream from that of the feed hydrocarbons. The alkylation apparatus by which the process is carried out includes a vertical reaction vessel, which in a preferred embodiment is 2 to 6 feet in height, a settling vessel, means for fluid flow from the reaction vessel to the settling vessel, a conduit for fluid flow between the upper part of the settling vessel and the reaction zone, and means for cooling fluid in this conduit.
摘要翻译： 一种用一种或多种烯烃催化烷基化异链烷烃的方法和装置。 反应性烃在反应区中与液体催化剂如氢氟酸接触。 允许烃相在沉降区中与催化剂相分离，并且一部分烃相被冷却并以与进料烃的流分开的流重新引入反应区。 进行该方法的烷基化装置包括在优选实施方案中为高度为2至6英尺的垂直反应容器，沉降容器，用于从反应容器流向沉降容器的流体的装置，用于流体的导管 在沉降容器的上部和反应区之间的流动，以及用于在该导管中冷却流体的装置。
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公开(公告)号：US4214115A
公开(公告)日：1980-07-22
申请号：US904149
申请日：1978-05-09
CPC分类号： C07C2/62 , C07C2527/1206 , Y02P20/584
摘要： A cyclic system for the alkylation of an isoparaffin, e.g., isobutane, wherein a first olefinic reactant, e.g., butylene, is used to alkylate the isoparaffin for a first period of time in an alkylation reactor and then a second olefinic reactant, e.g., propylene, is used to alkylate the isoparaffin for a second period of time in the same alkylation reactor. During the period that the isoparaffin is alkylated with the first olefinic reactant, the reactor effluent stream is continuously separated into a liquid hydrocarbon phase comprising alkylation products and unreacted isoparaffin and a liquid acid alkylation catalyst phase. The acid catalyst is continuously recycled to the reactor and the hydrocarbon phase is passed to a first surge zone or holding tank. During the second period of time, the isoparaffin-rich hydrocarbon phase from the first surge zone and the second olefinic reactant, along with continuously recycled catalyst, are charged to the same alkylation reactor so that, preferably, feed to the reactor is continuously effected. The reactor effluent is continuously separated into a liquid hydrocarbon phase containing unreacted isoparaffin and a liquid catalyst phase. The hydrocarbon phase is charged in part to fractionation and in part to a second surge zone. During the first period of time, hydrocarbon from the second surge zone is charged to this fractionation so the fractionation is continuously in operation. Isoparaffin is continuously removed from the fractionation to a third surge zone. Isoparaffin can be charged from the third surge zone to the alkylation reactor.
摘要翻译： 用于烷基化异链烷烃（例如异丁烷）的环状体系，其中第一烯烃反应物（例如丁烯）用于在烷基化反应器中将异链烷烃烷基化第一段时间，然后是第二烯烃反应物，例如丙烯 ，用于在同一烷基化反应器中将异链烷烃烷基化第二段时间。 在用第一烯属反应物烷基化异构烷烃的期间，将反应器流出物流连续分离成包含烷基化产物和未反应的异链烷烃和液体酸烷基化催化剂相的液体烃相。 酸催化剂连续地再循环到反应器中，烃相通过到第一冲击区或储罐。 在第二时间段内，将来自第一浪涌区和第二烯烃反应物的富含异构链烷烃的烃相以及连续循环的催化剂装入相同的烷基化反应器中，使得优选连续进料到反应器中。 将反应器流出物连续分离成含有未反应的异链烷烃和液体催化剂相的液体烃相。 烃相部分地进行分馏，部分地加入到第二浪涌区。 在第一时间段内，将来自第二喘振区的碳氢化合物加入到该分馏中，使分馏继续运行。 将异链烷烃从分馏物连续地除去至第三冲击区。 可以将异链烷烃从第三缓冲区带入烷基化反应器。
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5.发明授权HF alkylation introducing separate olefins in vertically extended reactor 失效在垂直延伸的反应器中引入单独的烯烃的HF烷基化
公开(公告)号：US4161497A
公开(公告)日：1979-07-17
申请号：US840424
申请日：1977-10-07
CPC分类号： C07C2/62 , C07C2527/1206
摘要： An improved HF alkylation process comprising, in series, HF and isoparaffin flow and parallel injection of at least two different olefins into a vertically extended reaction zone coupled with recycle of some of the alkylation hydrocarbon effluent to each point of olefin introduction into the alkylation zone. The improved alkylation system allows minimum sized fractionation and extremely high isoparaffin/olefin ratios with temperature control of the reaction at each olefin injection.
摘要翻译： 一种改进的HF烷基化方法，其包括串联的HF和异链烷烃流，并且将至少两种不同的烯烃平行注入到垂直延伸的反应区中，与一些烷基化烃流出物循环到每个烯烃引入到烷基化区中。 改进的烷基化系统允许在每种烯烃注入下温度控制反应的最小尺寸分馏和极高的异链烷烃/烯烃比例。
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公开(公告)号：US4454369A
公开(公告)日：1984-06-12
申请号：US376076
申请日：1982-05-07
申请人： Thomas Hutson, Jr. , Paul D. Hann
发明人： Thomas Hutson, Jr. , Paul D. Hann
CPC分类号： C07C2/62 , C07C9/16 , C07C2527/1206
摘要： In an HF alkylation process, ASO is separated from HF acid catalyst in a fractionation zone by heating the fractionation zone with a condensible stream comprising liquid and vaporous components. In the process of condensation, latent heat is evolved which is used to effectuate the separation of ASO and HF acid catalyst and dilution of the separated ASO is achieved with the use of the produced condensate.
摘要翻译： 在HF烷基化方法中，通过用包含液体和蒸汽组分的可冷凝流加热分馏区，在分馏区中将ASO与HF酸催化剂分离。 在冷凝过程中，产生潜热，用于实现ASO和HF酸催化剂的分离，并使用所生产的冷凝物实现分离的ASO的稀释。
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7.发明授权Production of high-octane, unleaded motor fuel by alkylation of isobutane with isoamylenes obtained by dehydrogenation of isopentane 失效通过用异戊烷脱氢获得的异戊烯烷基化异丁烷生产高辛烷值，无铅发动机燃料
公开(公告)号：US4429173A
公开(公告)日：1984-01-31
申请号：US356592
申请日：1982-03-09
申请人： Thomas Hutson, Jr. , Paul D. Hann
发明人： Thomas Hutson, Jr. , Paul D. Hann
摘要： A process combination, with inter-cooperation, for producing high-octane alkylates comprising(a) dehydrogenating isopentane to isopentenes (amylenes),(b) introducing the mixture of said amylenes and unconverted isopentane into an HF alkylation unit for reaction with fresh or recycled isobutane,(c) separating the alkylation products into high octane alkylates, isopentane (for recycling to the dehydrogenation reactor) and isobutane (for recycling to the alkylation reactor).
摘要翻译： 具有相互合作的用于生产高辛烷基烷基化物的方法组合，其包含（a）将异戊烷脱氢成异戊烯（戊烯），（b）将所述二聚戊烯和未转化的异戊烷的混合物引入HF烷基化单元中，以与新鲜或再循环 异丁烷，（c）将烷基化产物分离成高辛烷基烷基化物，异戊烷（用于再循环至脱氢反应器）和异丁烷（用于再循环至烷基化反应器）。
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8.发明授权Conversion of low octane number alkylate to high octane gasoline and aromatics 失效低辛烷值烷基化物转化为高辛烷值汽油和芳烃
公开(公告)号：US4179353A
公开(公告)日：1979-12-18
申请号：US813365
申请日：1977-07-06
摘要： An intentionally produced low octane value alkylate is reformed in the presence of steam, and in the absence of added hydrogen, to produce a high octane value, olefinic reformate containing aromatics. The reformate, upon fractionation to remove hydrogen and methane and C.sub.3 and C.sub.4 hydrocarbons, which can be recycled, is subjected to solvent extraction to produce a raffinate which can be used as high octane gasoline and which contains olefins, and an extract which, upon fractionation to remove xylenes therefrom as usable product, and which now contains benzene and toluene, can be combined with said raffinate.
摘要翻译： 有意产生的低辛烷值的烷基化物在蒸汽存在下重整，在没有加入氢气的情况下，产生高辛烷值，含有芳烃的烯烃重整产物。 将可再循环的分解除去氢气和甲烷的重整油和C3和C4烃进行溶剂萃取以产生可用作高辛烷值汽油并含有烯烃的萃余液，以及分馏时的提取物 从其中除去二甲苯作为可用的产物，并且其现在含有苯和甲苯可与所述残液相组合。
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公开(公告)号：US4579998A
公开(公告)日：1986-04-01
申请号：US587761
申请日：1984-03-09
申请人： Thomas Hutson, Jr.
发明人： Thomas Hutson, Jr.
CPC分类号： C07C2/62 , C07C2527/1206
摘要： A continuous method and apparatus for contact of olefin with paraffin in the presence of HF catalyst to produce alkylate in which about one half of the olefin feedstock is passed to each of two riser reactors with product effluent from both reactors entering a common settling vessel with return of settled HF catalyst proportioned between the two reactors and the paraffin feedstock provided as fresh or alkylate fractionator side stream recycle to one reactor and as reaction product recycle from the settler to the other reactor.
摘要翻译： 一种在HF催化剂存在下使烯烃与链烷烃接触以产生烷基化物的连续方法和装置，其中约一半的烯烃原料通过两个提升管反应器中的每一个，其中来自两个反应器的产物流出物进入共同的沉降容器 在两个反应器之间成比例的沉降的HF催化剂和作为新鲜或烷基化物分馏器侧流提供的石蜡原料再循环到一个反应器中，并且作为反应产物从沉降器循环到另一个反应器。
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公开(公告)号：US4528411A
公开(公告)日：1985-07-09
申请号：US423388
申请日：1982-09-24
申请人： Thomas Hutson, Jr.
发明人： Thomas Hutson, Jr.
摘要： Process for producing high quality gasoline and diesel fuel from C.sub.3 and C.sub.4 olefinic cuts, such as those obtained by dehydrogenation of lower alkanes, comprising the steps of (a) polymerizing a C.sub.3 olefinic cut to obtain a polymer gasoline fraction, (b) reacting a C.sub.4 olefinic cut with an alkanol such as methanol to form methyltertiarybutyl ether and unreacted C.sub.4 hydrocarbons, and (c) quenching the polymerization reaction in (a) with the unreacted C.sub.4 hydrocarbons obtained in (b). The polymer gasoline fraction in (a) can be subjected to fractionation and hydrogenation to obtain additional streams for recycle and diesel fuel product.
摘要翻译： 包括以下步骤：（a）使C3烯烃切割物聚合以获得聚合物汽油馏分，（b）使C 3 -C 4烯烃切段反应， 用链烷醇如甲醇进行C4烯烃切割以形成甲基叔丁基醚和未反应的C 4烃，（c）用（b）中得到的未反应的C 4烃淬灭（a）中的聚合反应。 （a）中的聚合物汽油馏分可进行分馏和氢化，以获得用于再循环和柴油燃料产物的附加流。
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