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公开(公告)号：US5047578A
公开(公告)日：1991-09-10
申请号：US183853
申请日：1988-04-20
CPC分类号： C07F9/4015 , C07F9/3826 , C08F30/02
摘要： Novel phosphonic acid-containing compounds such as (2-(4-ethenylphenyl)ethenyl)-phosphonic acid and esters thereof are disclosed. A method of preparation of the phosphonic acids comprising contacting a diethylenically unsaturated aromatic compound and phosphorus pentachloride in the presence of sulfur dioxide is also disclosed.The compounds of this invention are useful as monomers for the preparation of polymers having enhanced anti-corrosive properties.
摘要翻译： 公开了新的含膦酸化合物如（2-（4-乙烯基苯基）乙烯基）膦酸及其酯。 还公开了制备膦酸的方法，包括在二氧化硫存在下使二烯属不饱和芳族化合物和五氯化磷接触。 本发明的化合物可用作制备具有增强的抗腐蚀性能的聚合物的单体。
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公开(公告)号：US4758384A
公开(公告)日：1988-07-19
申请号：US82758
申请日：1987-08-07
CPC分类号： C08F30/02 , C07F9/3826 , C07F9/4015
摘要： Novel phosphonic acid-containing compounds such as (2-(4-ethenylphenyl)ethenyl)-phosphonic acid and esters thereof are disclosed. A method of preparation of the phosphonic acids comprising contacting a diethylenically unsaturated aromatic compound and phosphorus pentachloride in the presence of sulfur dioxide is also disclosed.The compounds of this invention are useful as monomers for the preparation of polymers having enhanced anti-corrosive properties.
摘要翻译： 公开了新的含膦酸化合物如（2-（4-乙烯基苯基）乙烯基）膦酸及其酯。 还公开了制备膦酸的方法，包括在二氧化硫存在下使二烯属不饱和芳族化合物和五氯化磷接触。 本发明的化合物可用作制备具有增强的抗腐蚀性能的聚合物的单体。
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公开(公告)号：US4733005A
公开(公告)日：1988-03-22
申请号：US936685
申请日：1986-12-01
IPC分类号： C08F230/02 , C09D143/02 , C09J143/02 , C07F9/32
CPC分类号： C09J143/02 , C08F230/02 , C09D143/02
摘要： The invention is (hydroxy)-phosphinylalkyl acrylate, (hydroxy)-phosphinylalkyl methacrylate or an alkali metal, alkaline earth metal or ammonium salt thereof.In another aspect, the invention is a polymeric composition which comprises the reaction product of:(a) between about 0.5 and 100 percent by weight of a (hydroxy)-phosphinylalkyl acrylate, (hydroxy)-phosphinylalkyl methacrylate or an alkali metal, alkaline earth metal or ammonium salt thereof; and(b) between about 0 and 99.5 weight percent of a compound containing a polymerizable 1,2-ethylenically unsaturated moiety.
摘要翻译： 本发明是丙烯酸（羟基） - 氧膦基烷基酯，甲基丙烯酸（羟基） - 氧膦基烷基酯或其碱金属，碱土金属或铵盐。 另一方面，本发明是一种聚合物组合物，其包含以下反应产物：（a）约0.5至100重量％的丙烯酸（羟基） - 氧膦基烷基酯，甲基丙烯酸（羟基） - 氧膦基烷基酯或碱金属碱土 金属或铵盐; 和（b）约0至99.5重量％的含有可聚合的1,2-烯属不饱和部分的化合物。
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公开(公告)号：US5077366A
公开(公告)日：1991-12-31
申请号：US661757
申请日：1991-02-27
CPC分类号： C07F9/4015 , C07F9/3826 , C08F30/02
摘要： Novel phosphonic acid-containing compounds such as (2-(4-ethylphenyl)ethenyl)-phosphonic acid and esters thereof are disclosed. A method preparation of the phosphonic acids comprising contacting a diethylenically unsaturated aromatic compound and phosphorus pentachloride in the present of sulfur dioxide is also disclosed. The compounds of this invention are useful as monomers for the preparation of polymers having enhanced anti-corrosive properties.
摘要翻译： 公开了新的含膦酸化合物如（2-（4-乙基苯基）乙烯基）膦酸及其酯。 还公开了膦酸的方法制备方法，其包括在二氧化硫存在下使二烯属不饱和芳族化合物和五氯化磷接触。 本发明的化合物可用作制备具有增强的抗腐蚀性能的聚合物的单体。
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公开(公告)号：US4658003A
公开(公告)日：1987-04-14
申请号：US854275
申请日：1986-04-21
IPC分类号： C08F230/02 , C09D143/02 , C09J143/02 , C08F30/02
CPC分类号： C08F230/02 , C09D143/02 , C09J143/02
摘要： The invention is (hydroxy)-phosphinylalkyl acrylate, (hydroxy)-phosphinylalkyl methacrylate or an alkali metal, alkaline earth metal or ammonium salt thereof.In another aspect, the invention is a polymeric composition which comprises the reaction product of:(a) between about 0.5 and 100 percent by weight of a (hydroxy)-phosphinylalkyl acrylate, (hydroxy)-phosphinylalkyl methacrylate or an alkali metal, alkaline earth metal or ammonium salt thereof; and(b) between about 0 and 99.5 weight percent of a compound containing a polymerizable 1,2-ethylenically unsaturated moiety.
摘要翻译： 本发明是丙烯酸（羟基） - 氧膦基烷基酯，甲基丙烯酸（羟基） - 氧膦基烷基酯或其碱金属，碱土金属或铵盐。 另一方面，本发明是一种聚合物组合物，其包含以下反应产物：（a）约0.5至100重量％的丙烯酸（羟基） - 氧膦基烷基酯，甲基丙烯酸（羟基） - 氧膦基烷基酯或碱金属碱土 金属或铵盐; 和（b）约0至99.5重量％的含有可聚合的1,2-烯属不饱和部分的化合物。
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公开(公告)号：US4738870A
公开(公告)日：1988-04-19
申请号：US845292
申请日：1986-03-27
申请人： John G. Green , Gerald K. McEwen , David G. Hunt
发明人： John G. Green , Gerald K. McEwen , David G. Hunt
CPC分类号： C08F30/02
摘要： A highly adherent photopolymerizable composition comprises a (hydroxy)phosphinylalkyl monomer of the formula ##STR1## wherein R is hydrogen, methyl or ethyl and R' and R" are selected independently from hydrogen and alkyl of 1-10 carbon atoms; at least one copolymerizable ethylenically unsaturated monomer and a photoinitiator.
摘要翻译： 高粘附的可光聚合组合物包含式（IMAGE）的（羟基）亚磷酰基烷基单体，其中R是氢，甲基或乙基，R'和R“独立地选自氢和1-10个碳原子的烷基; 至少一种可共聚的烯属不饱和单体和光引发剂。
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公开(公告)号：US4316006A
公开(公告)日：1982-02-16
申请号：US125020
申请日：1980-02-27
申请人： Gerald K. McEwen
发明人： Gerald K. McEwen
IPC分类号： C08G18/50 , C08G79/04 , C08L101/00
CPC分类号： C08G79/04 , C08G18/5078 , C08L101/00
摘要： Phosphorus containing polymers are prepared by copolymerizing a cyclic phosphite and an epoxide in the presence of an acid catalyst. The resulting polymer can be incorporated within a thermoplastic or thermosettable resin to increase the flame resistivity thereof.
摘要翻译： 含磷聚合物通过在酸催化剂存在下共聚环状亚磷酸酯和环氧化物来制备。 所得聚合物可以结合在热塑性或热固性树脂中以增加其阻燃性。
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8.发明授权Radiation curable flame retardant compositions containing 2,2-dialkylpropane-1,3-diolbis[bis-(acryloyloxylkyl) phosphates] 失效含有2,2-二烷基丙烷-1,3-二醇双[双（丙烯酰氧基烷基）磷酸酯]的可辐射固化阻燃组合物]
公开(公告)号：US4269727A
公开(公告)日：1981-05-26
申请号：US82191
申请日：1979-10-05
摘要： Effective radiation curable flame retardant compositions include compounds of the formula: ##STR1## wherein A is hydrogen or methyl; A' is hydrogen, methyl, phenyl or halogen; n is 1 or 1.5 and when n is 1, B is hydrogen or methyl and when n is 1.5, B is hydrogen; Y is oxygen or sulfur; R and R' are hydrogen, methyl, chloromethyl or bromomethyl.
摘要翻译： 有效的可辐射固化阻燃组合物包括下式的化合物：其中A是氢或甲基; A'是氢，甲基，苯基或卤素; n为1或1.5，当n为1时，B为氢或甲基，当n为1.5时，B为氢; Y是氧或硫; R和R'是氢，甲基，氯甲基或溴甲基。
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9.发明授权
公开(公告)号：US4228108A
公开(公告)日：1980-10-14
申请号：US960383
申请日：1978-11-13
摘要： Effective reactive flame retardants are novel compounds of the formula: ##STR1## wherein A is hydrogen or methyl; A' is hydrogen, methyl, phenyl or halogen; n is 1 or 1.5 and when n is 1, B is hydrogen or methyl and when n is 1.5, B is hydrogen; Y is oxygen or sulfur; R and R' are hydrogen, methyl, chloromethyl or bromomethyl.
摘要翻译： 有效的反应性阻燃剂是下式的新化合物：其中A是氢或甲基; A'是氢，甲基，苯基或卤素; n为1或1.5，当n为1时，B为氢或甲基，当n为1.5时，B为氢; Y是氧或硫; R和R'是氢，甲基，氯甲基或溴甲基。
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10.发明授权
公开(公告)号：US4427813A
公开(公告)日：1984-01-24
申请号：US330752
申请日：1981-12-14
申请人： Gerald K. McEwen , Lowell S. Thomas
发明人： Gerald K. McEwen , Lowell S. Thomas
IPC分类号： C08L69/00 , C07F9/6571 , C07F9/6574 , C08K3/00 , C08K5/51 , C08K5/527 , C08K5/5398 , C08L67/00 , C08K5/52 , C07F9/15
CPC分类号： C08K5/527 , C07F9/657136 , C07F9/65746 , C08K5/5398
摘要： A polycarbonate such as a bisphenol-A homopolycarbonate containing a small amount of an aromatic bis(cyclic phosphate) such as 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxy-2,1-ethanediyloxy)]bis(5,5-dimethyl-2,2'-dioxo-1,3,2-dioxaphosphorinane) exhibits improved thermal stability.
摘要翻译： 含有少量芳香族双（环状磷酸酯）如2,2' - [（1-甲基亚乙基）双（4,1-亚苯基氧基-2,1-乙二基氧基）]二双酯的双酚-A均聚碳酸酯 （5,5-二甲基-2,2'-二氧代-1,3,2-二氧杂磷杂环戊烷）表现出改进的热稳定性。
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