Emulsion polymers and stain resistant coating compositions made therefrom

    公开(公告)号:US11059980B2

    公开(公告)日:2021-07-13

    申请号:US15777696

    申请日:2016-11-30

    申请人: Arkema Inc.

    发明人: Wenjun Wu

    摘要: Emulsion polymers and coating compositions made therefrom that exhibit exceptional stain resistance to both hydrophilic and hydrophobic stains. The emulsion polymers include, as polymerized units: a) at least one ethylenically unsaturated nonionic monomer in an amount ranging between about 85 wt. % to less than 100 wt. % based on the overall weight of the polymer composition; b) a first acid monomer in an amount ranging from about 0.1 to 2 wt. %, the first monomer being a strong acid monomer selected as a phosphorus-based acid monomer, a sulfur-based acid monomer, or a mixture thereof, and c) a second acid monomer in an amount ranging from about 0.1 to 2 wt. %, the second monomer being one or more ethylenically unsaturated monomers having at least one carboxyl or carboxylic anhydride functional group. The relative amounts of the first and second acid monomers are such that the ratio of b/c is greater than 0.7.

    Simple coacervates and methods of use thereof
    9.
    发明授权
    Simple coacervates and methods of use thereof 有权
    简单的凝聚及其使用方法

    公开(公告)号:US09421300B2

    公开(公告)日:2016-08-23

    申请号:US14874854

    申请日:2015-10-05

    摘要: Described herein is the synthesis of adhesive from simple adhesive coacervates and their uses thereof. The adhesives are produced by (a) preparing a solution comprising (1) a polyelectrolyte, wherein the polyelectrolyte comprises a polyanion or polycation but not a combination thereof, the polyeletrolyte comprises at least one crosslinking group, and (2) a sufficient amount of a complimentary counterion to produce a simple adhesive coacervate; and (b) crosslinking the simple adhesive coacervate to produce the adhesive. The adhesives have numerous medical and non-medical applications.

    摘要翻译: 这里描述的是从简单的粘合剂凝聚层合成粘合剂及其用途。 粘合剂通过(a)制备包含(1)聚电解质的溶液来制备,其中聚电解质包含聚阴离子或聚阳离子而不是它们的组合,所述多聚乙烯醚包含至少一个交联基团,和(2)足量的 免费的抗衡离子生产简单的粘合剂凝聚层; 和(b)使简单的粘合剂凝聚层交联以产生粘合剂。 粘合剂具有许多医疗和非医疗应用。

    Novel phosphinyl-containing ethylenically unsaturated compounds
    10.
    发明授权
    Novel phosphinyl-containing ethylenically unsaturated compounds 失效
    新型含膦基的烯属不饱和化合物

    公开(公告)号:US4658003A

    公开(公告)日:1987-04-14

    申请号:US854275

    申请日:1986-04-21

    摘要: The invention is (hydroxy)-phosphinylalkyl acrylate, (hydroxy)-phosphinylalkyl methacrylate or an alkali metal, alkaline earth metal or ammonium salt thereof.In another aspect, the invention is a polymeric composition which comprises the reaction product of:(a) between about 0.5 and 100 percent by weight of a (hydroxy)-phosphinylalkyl acrylate, (hydroxy)-phosphinylalkyl methacrylate or an alkali metal, alkaline earth metal or ammonium salt thereof; and(b) between about 0 and 99.5 weight percent of a compound containing a polymerizable 1,2-ethylenically unsaturated moiety.

    摘要翻译: 本发明是丙烯酸(羟基) - 氧膦基烷基酯,甲基丙烯酸(羟基) - 氧膦基烷基酯或其碱金属,碱土金属或铵盐。 另一方面,本发明是一种聚合物组合物,其包含以下反应产物:(a)约0.5至100重量%的丙烯酸(羟基) - 氧膦基烷基酯,甲基丙烯酸(羟基) - 氧膦基烷基酯或碱金属碱土 金属或铵盐; 和(b)约0至99.5重量%的含有可聚合的1,2-烯属不饱和部分的化合物。