Methods for sulfate removal in liquid-phase catalytic hydrothermal gasification of biomass
    1.
    发明授权
    Methods for sulfate removal in liquid-phase catalytic hydrothermal gasification of biomass 有权
    生物质液相催化水热气化硫酸盐去除方法

    公开(公告)号:US08608981B2

    公开(公告)日:2013-12-17

    申请号:US13541003

    申请日:2012-07-03

    IPC分类号: C01B3/38 C01B3/24

    摘要: Processing of wet biomass feedstock by liquid-phase catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a pre-treatment temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent removal of soluble sulfate contaminants, or combinations thereof. Processing further includes reacting the soluble sulfate contaminants with cations present in the feedstock material to yield a sulfate-containing precipitate and separating the inorganic precipitates and/or the sulfate-containing precipitates out of the wet feedstock. Having removed much of the inorganic wastes and the sulfate contaminants that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogeneous catalyst for gasification.

    摘要翻译: 通过液相催化水热气化处理湿生物质原料必须解决催化剂污染和中毒问题。 一种解决方案可以包括用加热单元将湿生物质加热到足以使原料中的有机成分分解的预处理温度,用于沉淀无机废物以形成,用于预热湿原料以备后续除去可溶性硫酸盐污染物 ,或其组合。 处理进一步包括使可溶性硫酸盐污染物与原料中存在的阳离子反应以产生含硫酸盐的沉淀物,并将无机沉淀物和/或硫酸盐沉淀物从湿原料中分离出来。 除去大量无机废物和可能引起中毒和结垢的硫酸盐污染物,湿生物质原料可暴露于非均相催化剂进行气化。