公开(公告)号：US20160009610A1

公开(公告)日：2016-01-14

申请号：US14771676

申请日：2014-03-12

申请人： E.I.DU PONT DE NEMOURS AND COMPANY

发明人： Annalisa Hargis ,  Manish S. Kelkar ,  Kenneth Chad Manning ,  Joachim C. Ritter ,  Sourav Kumar Sengupta

IPC分类号： C07C1/22 ,  B01J27/188 ,  B01J23/652

CPC分类号： C07C1/22 ,  B01J23/6527 ,  B01J27/188 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/18 ,  C07C2523/04 ,  C07C2523/30 ,  C07C2523/42 ,  C07C2527/188 ,  C10G3/47 ,  C10G3/48 ,  C10G3/50 ,  C10G2300/1081 ,  Y02P30/20 ,  C07C9/15 ,  C07C9/22

摘要： A hydrodeoxygenation process for producing a linear alkane from a feedstock comprising a saturated or unsaturated C10-18 oxygenate that comprises an ester group, carboxylic acid group, carbonyl group and/or alcohol group is disclosed. This process comprises contacting the feedstock with (i) a catalyst comprising about 0.1% to about 10% by weight of a metal selected from Group IB, VIB, or VIII of the Periodic Table, and (ii) a heteropolyacid or heteropolyacid salt, at a temperature between about 150° C. to about 250° C. and a hydrogen gas pressure of at least about 300 psig. By contacting the feedstock with the catalyst and heteropolyacid or heteropolyacid salt under these temperature and pressure conditions, the C10-18 oxygenate is hydrodeoxygenated to a linear alkane that has the same carbon chain length as the C10-18 oxygenate.

摘要翻译： 公开了用于从包含酯基，羧酸基，羰基和/或醇基的饱和或不饱和的C 10-18含氧化合物的原料生产线性烷烃的加氢脱氧方法。 该方法包括使原料与（i）包含约0.1％至约10％重量的选自元素周期表IB，VIB或VIII族的金属的催化剂接触，和（ii）杂多酸或杂多酸盐， 约150℃至约250℃的温度和至少约300psig的氢气压力。 通过在这些温度和压力条件下使原料与催化剂和杂多酸或杂多酸盐接触，将C10-18含氧化合物加氢脱氧至与C10-18含氧化合物具有相同碳链长度的直链烷烃。