公开(公告)号：US11946000B2

公开(公告)日：2024-04-02

申请号：US17595512

申请日：2020-05-22

Applicant: Eastman Chemical Company

Inventor： Daryl Bitting ,  Kenny Randolph Parker ,  Michael Gary Polasek ,  David Eugene Slivensky ,  Xianchun Wu ,  Jerome Leonard Stavinoha, Jr.

IPC: C10G1/10 ,  C10G3/00

CPC classification number: C10G3/40 ,  C10G1/10 ,  C10G2300/1003 ,  C10G2300/301 ,  C10G2400/20 ,  C10G2400/22

Abstract: A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. More specifically the-pyoil is present in said feedstock in an amount of not more than 20% by weight, based on the total weight of the feedstock.

公开(公告)号：US20220186124A1

公开(公告)日：2022-06-16

申请号：US17595510

申请日：2020-05-22

Applicant: Eastman Chemical Company

Inventor： Daryl Bitting ,  Kenny Randolph Parker ,  Michael Gary Polasek ,  David Eugene Slivensky ,  Xianchun Wu ,  Jerome Leonard Stavinoha, Jr.

IPC: C10G9/36

Abstract: A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. More specifically cracking the cracker feedstock in said cracker furnace to provide an olefin-containing effluent stream; wherein the hydrocarbon composition is predominantly ethane.

公开(公告)号：US09315485B2

公开(公告)日：2016-04-19

申请号：US14459875

申请日：2014-08-14

Applicant: Eastman Chemical Company

Inventor： Damon Ray Billodeaux ,  Robert Scott Huss ,  Daniel Latham Terrill ,  Jerome Leonard Stavinoha, Jr.

IPC: C07D319/06 ,  C07D317/12

CPC classification number: C07D319/06 ,  C07D317/12 ,  Y02P20/127

Abstract: Cyclic acetals can be produced in a reactive distillation apparatus by combining a polyhydroxyl compound and an aldehyde. High concentrations of cyclic acetals are removed as liquid products from the column while water is removed as an overhead vapor stream.

Abstract translation: 可以通过组合多羟基化合物和醛在反应蒸馏装置中制备环状缩醛。 高浓度的环状缩醛作为液体产物从塔中除去，而作为塔顶蒸气流除去水。

公开(公告)号：US09238603B1

公开(公告)日：2016-01-19

申请号：US14566245

申请日：2014-12-10

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： Jerome Leonard Stavinoha, Jr. ,  Carey Dan Ashcroft ,  Craig Alan Hoyme ,  Kelmara Khadene Kelly

IPC: C07C29/132 ,  C07C29/145 ,  C07C29/56

CPC classification number: C07C29/145 ,  C07B2200/09 ,  C07C29/56 ,  C07C2601/04 ,  C07C35/045

Abstract: This invention is generally directed to a batch process for the preparation of cis-2,2,4,4-tetramethylcyclobutane-1,3-diol comprising: (A) treatment of at least one monomer selected from 2,2,4,4-tetramethylcyclobutane-1,3-dione, 3-hydroxy-2,2,4,4-tetramethylcyclobutanone, and 2,2,4,4-tetramethylcyclobutane-1,3-diol said diol having a starting cis:trans molar ratio of 0:1 to about 2:1, or mixtures thereof by contacting said monomer(s) with hydrogen in the presence of a reaction solvent in which the resulting cis-2,2,4,4-tetramethylcyclobutane-1,3-diol is partially soluble and further in the presence of a catalyst comprising about 0.1 to about 10 weight percent ruthenium, based on the total weight of the catalyst, deposited on a support material, under reaction conditions sufficient to produce a cis-2,2,4,4-tetramethylcyclobutane-1,3-diol having a final cis:trans molar ratio of from 2:1 to about 25:1; (B) removal of the reaction solvent, whether by filtration, centrifugation, or other methods known to one of ordinary skill in the art; (C) dissolution of the 2,2,4,4-tetramethylcyclobutane-1,3-diol with at least one solvent; and, optionally, (D) washing the catalyst at least once, and optionally, (E) reuse of the catalyst.

Abstract translation: 本发明一般涉及制备顺式-2,2,4,4-四甲基环丁烷-1,3-二醇的分批方法，其包括：（A）处理至少一种选自2,2,4,4 - 四甲基环丁烷-1,3-二酮，3-羟基-2,2,4,4-四甲基环丁酮和2,2,4,4-四甲基环丁烷-1,3-二醇，所述二醇的起始顺式：反式摩尔比为 0:1至约2:1，或其混合物通过在反应溶剂存在下使所述单体与氢接触，其中所得顺式-2,2,4,4-四甲基环丁烷-1,3-二醇为 在足以产生顺式-2,2,4或4的反应条件下，在包含约0.1至约10重量％钌的催化剂存在下进一步沉积在载体材料上的催化剂总重量， 具有最终顺式：反式摩尔比为2:1至约25:1的4-四甲基环丁烷-1,3-二醇; （B）通过过滤，离心或本领域普通技术人员已知的其它方法除去反应溶剂; （C）使用至少一种溶剂使2,2,4,4-四甲基环丁烷-1,3-二醇溶解; 和（D）将催化剂洗涤至少一次，任选地（E）催化剂的再利用。

公开(公告)号：US09108895B2

公开(公告)日：2015-08-18

申请号：US13661088

申请日：2012-10-26

Applicant: Eastman Chemical Company

Inventor： Zhufang Liu ,  Brent Alan Tennant ,  Jerome Leonard Stavinoha, Jr. ,  Anthony Dominick Messina ,  Noah Glenn McMillan

IPC: C07C27/04 ,  C07C29/149

CPC classification number: C07C29/149 ,  C07C31/10 ,  C07C31/12 ,  C07C31/125

Abstract: The invention relates to ruthenium-rhenium-tin and ruthenium-rhenium catalysts effective for the reduction of carboxylic acids to the corresponding alcohols and processes for the reduction of carboxylic acids to the corresponding alcohols using the ruthenium-rhenium-tin and ruthenium-rhenium catalysts.

Abstract translation: 本发明涉及有效将羧酸还原成相应的醇的钌 - 铼 - 锡和钌 - 铼催化剂，以及使用钌 - 铼 - 锡和钌 - 铼催化剂将羧酸还原成相应的醇的方法。

公开(公告)号：US12215283B2

公开(公告)日：2025-02-04

申请号：US17594370

申请日：2020-05-22

Applicant: Eastman Chemical Company

Inventor： Daryl Bitting ,  Kenny Randolph Parker ,  Michael Gary Polasek ,  David Eugene Sllivensky ,  Xianchun Wu ,  Jerome Leonard Stavinoha, Jr.

IPC: C10G51/02 ,  C10G1/00 ,  C10G1/10

Abstract: Recycle content pyoil is cracked in a cracker furnace to make olefins and the coil outlet temperature of the r-pyoil fed coils can be lowered by adding r-pyoil to the cracker feedstock, or alternatively, the coil outlet temperature of the r-pyoil fed tubes can rise if the mass flow rates of the combined cracker stream containing r-pyoil are kept the same or lowered. Further, increasing the hydrocarbon mass flow rate by addition of r-pyoil can be achieved to also increase the output of ethylene and propylene in the cracker effluent. The cracker furnace can accept ethane and/or propane feedstocks in vapor form along with a liquid and/or vapor feed of r-pyoil.

公开(公告)号：US12018220B2

公开(公告)日：2024-06-25

申请号：US17593383

申请日：2020-05-22

Applicant: Eastman Chemical Company

Inventor： Daryl Bitting ,  Kenny Randolph Parker ,  Michael Gary Polasek ,  David Eugene Slivensky ,  Xianchun Wu ,  Jerome Leonard Stavinoha, Jr.

IPC: C10G9/00 ,  C10G1/00 ,  C10G1/10 ,  C10G9/14

CPC classification number: C10G9/00 ,  C10G1/002 ,  C10G1/10 ,  C10G2300/1003 ,  C10G2400/20

Abstract: A predominantly C2 to C4 hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to a first coil while a second cracker feed with none of the r-pyoil or less of the r-pyoil is fed to a second coil, and both are cracked in a cracker furnace to form an olefin-containing effluent stream. Alternatively, the r-pyoil can be fed and distributed across multiple coils along with the non-recycle cracker feed. The furnace can be a gas fed furnace, or split cracker furnace. Further, a first cracker stream with r-pyoil in a first coil can have a lower total molar flow rate than a second cracker stream in a second coil in the same furnace.

公开(公告)号：US20220282163A1

公开(公告)日：2022-09-08

申请号：US17663219

申请日：2022-05-13

Applicant: Eastman Chemical Company

Inventor： Daryl Bitting ,  Kenny Randolph Parker ,  Michael Gary Polasek ,  David Eugene Slivensky ,  Xianchun Wu ,  Jerome Leonard Stavinoha, Jr.

IPC: C10G9/36 ,  C10B53/07

Abstract: A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. Alternatively, the r-pyoil with a predominantly c8+ fraction can be fed to the cracker feed. The furnace can be a gas fed furnace, or split cracker furnace.

公开(公告)号：US20220267679A1

公开(公告)日：2022-08-25

申请号：US17595512

申请日：2020-05-22

Applicant: Eastman Chemical Company

Inventor： Daryl Bitting ,  Kenny Randolph Parker ,  Michael Gary Polasek ,  David Eugene Slivensky ,  Xianchun Wu ,  Jerome Leonard Stavinoha, Jr.

IPC: C10G3/00 ,  C10G1/10

Abstract: A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. More specifically the-pyoil is present in said feedstock in an amount of not more than 20% by weight, based on the total weight of the feedstock.

公开(公告)号：US09238602B1

公开(公告)日：2016-01-19

申请号：US14566154

申请日：2014-12-10

Applicant: Eastman Chemical Company

Inventor： Jerome Leonard Stavinoha, Jr. ,  Carey Dan Ashcroft ,  Kelmara Khadene Kelly ,  Craig Alan Hoyme

IPC: C07C29/132 ,  C07C29/145 ,  C07C29/56

CPC classification number: C07C29/132 ,  C07B2200/09 ,  C07C29/145 ,  C07C29/56 ,  C07C2601/04 ,  C07C35/045

Abstract: This invention is generally directed to a process for the preparation of cis-2,2,4,4-tetramethylcyclobutane-1,3-diol comprising: treatment of at least one monomer selected from 2,2,4,4-tetramethylcyclobutane-1,3-dione, 3-hydroxy-2,2,4,4-tetramethylcyclobutanone, and 2,2,4,4-tetramethylcyclobutane-1,3-diol said diol having a starting cis:trans molar ratio of 0:1 to about 2:1, or mixtures thereof by contacting said monomer(s) with hydrogen in the presence of a reaction solvent in which the resulting cis-2,2,4,4-tetramethylcyclobutane-1,3-diol is partially soluble and further in the presence of a catalyst comprising about 0.1 to about 10 weight percent ruthenium, based on the total weight of the catalyst, deposited on a support material, under reaction conditions sufficient to produce a cis-2,2,4,4-tetramethylcyclobutane-1,3-diol having a final cis:trans molar ratio of from 2:1 to about 25:1.

Abstract translation: 本发明一般涉及一种制备顺式-2,2,4,4-四甲基环丁烷-1,3-二醇的方法，包括：处理至少一种选自2,2,4,4-四甲基环丁烷-1 1,3-二酮，3-羟基-2,2,4,4-四甲基环丁酮和2,2,4,4-四甲基环丁烷-1,3-二醇，所述二醇的起始顺式：反式摩尔比为0:1至 约2:1，或其混合物通过在反应溶剂存在下使所述单体与氢接触，其中所得顺式-2,2,4,4-四甲基环丁烷-1,3-二醇是部分可溶的，并且进一步 在催化剂存在下，在足以产生顺式-2,2,4,4-四甲基环丁烷-1-酮的反应条件下，基于沉积在载体材料上的催化剂的总重量计，约0.1至约10重量％的钌， 1,3-二醇的顺式：反式摩尔比为2：1至25：1。