公开(公告)号：US5296573A

公开(公告)日：1994-03-22

申请号：US648725

申请日：1991-01-31

申请人： Eberhard Esselborn ,  Jurgen Fock ,  Gotz Koerner ,  Dietmar Schaefer

发明人： Eberhard Esselborn ,  Jurgen Fock ,  Gotz Koerner ,  Dietmar Schaefer

IPC分类号： B01F17/52 ,  C08F8/14 ,  C08F20/26 ,  C08G81/02 ,  C08F220/26 ,  C08F220/28

CPC分类号： A61Q5/02 ,  A61K8/86 ,  C08F8/14 ,  C08G81/025 ,  C08F2810/30

摘要： Polyacrylate esters with long-chain alkoxylated hydrocarbonoxy groups are disclosed which can be obtained by the transesterification of polyacrylate esters with polyoxyalkylene monools, wherein the polyacrylate esters, up to 50% of which can be replaced by the corresponding methacrylate esters, have been obtained by free radical polymerization and wherein the polyoxyalkylene monools have the average formulaR.sup.1 O(C.sub.n H.sub.2n O--).sub.x HwhereinR.sup.1 is an alkyl, alkenyl or alkylphenyl group,n has an absolute value of 2, 3 or 4 and an average value of 2.0 to 2.5 andx is 10 to 200.The compounds, which can be used as emulsifiers, solubilizers and for thickening aqueous solutions which contain anionic surfactants, particularly in cosmetics and for personal grooming, are distinguished by a content of low molecular weight components, which is smaller compared to that of products obtained by copolymerization.

摘要翻译： 公开了具有长链烷氧基化烃氧基的聚丙烯酸酯，其可通过聚丙烯酸酯与聚氧化烯一醇的酯交换获得，其中至多50％可被相应的甲基丙烯酸酯代替的聚丙烯酸酯已经通过游离 自由基聚合，其中聚氧化烯一元醇具有平均式R1O（CnH2nO-）xH，其中R1是烷基，烯基或烷基苯基，n的绝对值为2,3或4，平均值为2.0至2.5，x为 可用作乳化剂，增溶剂和含有阴离子表面活性剂，特别是化妆品中和用于个人修饰的阴离子表面活性剂的水溶液的化合物的特征在于低分子量组分的含量比其低 的共聚产物。

公开(公告)号：US5338485A

公开(公告)日：1994-08-16

申请号：US843912

申请日：1992-02-27

申请人： Jurgen Fock ,  Eberhard Esselborn ,  Dietmar Schaefer

发明人： Jurgen Fock ,  Eberhard Esselborn ,  Dietmar Schaefer

IPC分类号： B01F17/00 ,  B01F17/42 ,  C08F8/14 ,  C08F20/18 ,  C08F120/18

CPC分类号： B01F17/0028 ,  C08F8/14 ,  C08F2810/30 ,  Y10S516/06

摘要： Polyacrylate esters with long-chain hydrocarbon and polyoxyalkylene groups are disclosed, which are prepared by transesterification of polyacrylate alkyl esters, the alkyl groups of which have 1 to 4 carbon atoms and which were obtained by free radical polymerization, wherein the transesterification is carried out with a mixture of selected alcohols and polyoxyalkylene monools. Compared to products obtained by copolymerization, the transesterification products are largely free of undesirable low molecular weight components, have a narrow molecular weight distribution and exhibit excellent surfactant properties. They are useful especially as W/O emulsifiers for natural and synthetic oils.

摘要翻译： 公开了具有长链烃和聚氧化烯基团的聚丙烯酸酯，其通过聚丙烯酸酯烷基酯（其烷基具有1至4个碳原子并通过自由基聚合获得）的酯交换制备，其中酯交换反应是用 选择的醇和聚氧化烯一元醇的混合物。 与通过共聚获得的产物相比，酯交换产物大部分没有不期望的低分子量组分，具有窄的分子量分布并且表现出优异的表面活性剂性质。 它们特别适用于天然和合成油的W / O乳化剂。

公开(公告)号：US5115039A

公开(公告)日：1992-05-19

申请号：US711364

申请日：1991-06-05

申请人： Jurgen Fock ,  Dietmar Schaefer ,  Eberhard Esselborn

发明人： Jurgen Fock ,  Dietmar Schaefer ,  Eberhard Esselborn

IPC分类号： A61K8/00 ,  A61K8/72 ,  A61Q5/00 ,  A61Q5/02 ,  B01F17/18 ,  C08F8/02 ,  C08F8/14 ,  C08F8/30 ,  C08F8/32 ,  C08F8/44 ,  C08F20/34 ,  C08F220/34 ,  C08G81/02 ,  C09K3/16 ,  D06M15/267

CPC分类号： A61Q5/02 ,  A61K8/8152 ,  A61Q5/12 ,  C08F8/14 ,  C08F8/44 ,  C08F2810/30

摘要： Polyacrylate esters with quaternary ammonium groups are disclosed. The esters are obtained by transesterifying alkyl polyacrylate esters with a mixture of dialkylaminoalkanols and saturated or unsaturated aliphatic alcohols with 8 to 22 carbon atoms, followed by quaternization.The polymers are free of physiologically questionable components and can therefore be used for the preparation of cosmetic products, preferably for hair cosmetics. The polymers furthermore are suitable for finishing fibers or of textile products.The invention is furthermore directed to polyacrylate esters with tertiary amino groups, which are formed as intermediates in the preparation of polyacrylate esters with quaternary ammonium groups.

公开(公告)号：US5115040A

公开(公告)日：1992-05-19

申请号：US718193

申请日：1991-06-20

申请人： Jurgen Fock ,  Dietmar Schaefer ,  Eberhard Esselborn

发明人： Jurgen Fock ,  Dietmar Schaefer ,  Eberhard Esselborn

IPC分类号： A61K8/72 ,  A61K8/00 ,  A61Q5/00 ,  A61Q5/02 ,  B01F17/18 ,  C08F8/02 ,  C08F8/30 ,  C08F8/32 ,  C08F8/44 ,  C08F20/34 ,  C08F220/34 ,  C08G81/02 ,  C09K3/16 ,  D06M15/267

CPC分类号： A61Q5/02 ,  A61K8/8152 ,  A61Q5/12 ,  C08F8/44

摘要： Polyacrylate esters with quaternary ammonium groups are disclosed. The esters are obtained by transesterifying alkyl polyacrylate esters with dialkylaminoalkanols, followed by quaternization.The polymers are free of physiologically questionable components and can therefore be used for the preparation of cosmetic products, preferably for hair cosmetics. The polymers furthermore are suitable for finishing fibers or of textile products.The invention is furthermore directed to polyacrylate esters with tertiary amino groups, which are formed as intermediates in the preparation of polyacrylate esters with quaternary ammonium groups.

公开(公告)号：US5057579A

公开(公告)日：1991-10-15

申请号：US448169

申请日：1989-12-08

申请人： Jurgen Fock ,  Dietmar Schaefer ,  Eberhard Esselborn

发明人： Jurgen Fock ,  Dietmar Schaefer ,  Eberhard Esselborn

IPC分类号： A61K8/72 ,  A61K8/00 ,  A61Q5/00 ,  A61Q5/02 ,  B01F17/18 ,  C08F8/02 ,  C08F8/30 ,  C08F8/32 ,  C08F8/44 ,  C08F20/34 ,  C08F220/34 ,  C08G81/02 ,  C09K3/16 ,  D06M15/267

CPC分类号： A61Q5/02 ,  A61K8/8152 ,  A61Q5/12 ,  C08F8/44

摘要： Polyacrylate esters with quaternary ammonium groups are disclosed. The esters are obtained by transesterifying alkyl polyacrylate esters with dialkylaminoalkanols, followed by quaternization.The polymers are free of physiologically questionable components and can therefore be used for the preparation of cosmetic products, preferably for hair cosmetics. The polymers furthermore are suitable for finishing fibers or of textile products.The invention is furthermore directed to polyacrylate esters with tertiary amino groups, which are formed as intermediates in the preparation of polyacrylate esters with quaternary ammonium groups.

摘要翻译： 公开了具有季铵基团的聚丙烯酸酯。 酯是通过酯交换烷基聚丙烯酸酯与二烷基氨基链烷醇，然后季铵化获得的。 聚合物不含生理上有疑问的组分，因此可用于制备化妆品，优选用于头发化妆品。 聚合物还适用于整理纤维或纺织品。 本发明还涉及具有叔氨基的聚丙烯酸酯，其在制备具有季铵基团的聚丙烯酸酯的中间体形成。

公开(公告)号：US5133898A

公开(公告)日：1992-07-28

申请号：US471554

申请日：1990-01-29

申请人： Jurgen Fock ,  Eberhard Esselborn ,  Dietmar Schaefer

发明人： Jurgen Fock ,  Eberhard Esselborn ,  Dietmar Schaefer

IPC分类号： B01F17/00 ,  B01F17/42 ,  B01F17/52 ,  B01F17/54 ,  C08F8/14 ,  C08G81/02 ,  C10L1/192 ,  C10L1/195 ,  C10L1/198 ,  C10L10/18

CPC分类号： B01F17/0028 ,  C08F8/14 ,  C08F2810/30 ,  Y10S516/918

摘要： Polyacrylate esters with long-chain hydrocarbon and polyoxyalkylene groups are disclosed, which are prepared by transesterification of polyacrylate alkyl esters, the alkyl groups of which have 1 to 4 carbon atoms and which were obtained by free radical polymerization, wherein the transesterification is carried out with a mixture of selected alcohols and polyoxyalkylene monools. Compared to products obtained by copolymerization, the transesterification products are largely free of undesirable low molecular weight components, have a narrow molecular weight distribution and exhibit excellent surfactant properties. They are useful especially as W/O emulsifiers for natural and synthetic oils.

摘要翻译： 公开了具有长链烃和聚氧化烯基团的聚丙烯酸酯，其通过聚丙烯酸酯烷基酯（其烷基具有1至4个碳原子并通过自由基聚合获得）的酯交换制备，其中酯交换反应是用 选择的醇和聚氧化烯一元醇的混合物。 与通过共聚获得的产物相比，酯交换产物大部分没有不期望的低分子量组分，具有窄的分子量分布并且表现出优异的表面活性剂性质。 它们特别适用于天然和合成油的W / O乳化剂。

公开(公告)号：US5057580A

公开(公告)日：1991-10-15

申请号：US448168

申请日：1989-12-08

申请人： Jurgen Fock ,  Dietmar Schaefer ,  Eberhard Esselborn

发明人： Jurgen Fock ,  Dietmar Schaefer ,  Eberhard Esselborn

IPC分类号： A61K8/00 ,  A61K8/72 ,  A61Q5/00 ,  A61Q5/02 ,  B01F17/18 ,  C08F8/02 ,  C08F8/14 ,  C08F8/30 ,  C08F8/32 ,  C08F8/44 ,  C08F20/34 ,  C08F220/34 ,  C08G81/02 ,  C09K3/16 ,  D06M15/267

CPC分类号： A61Q5/02 ,  A61K8/8152 ,  A61Q5/12 ,  C08F8/14 ,  C08F8/44 ,  C08F2810/30

摘要： Polyacrylate esters with quaternary ammonium groups are disclosed. The esters are obtained by transesterifying alkyl polyacrylate esters with a mixture of dialkylaminoalkanols and saturated or unsaturated aliphatic alcohols with 8 to 22 carbon atoms, followed by quaternization.The polymers are free of physiologically questionable components and can therefore be used for the preparation of cosmetic products, preferably for hair cosmetics. The polymers furthermore are suitable for finishing fibers or of textile products.The invention is furthermore directed to polyacrylate esters with tertiary amino groups, which are formed as intermediates in the preparation of polyacrylate esters with quaternary ammonium groups.

摘要翻译： 公开了具有季铵基团的聚丙烯酸酯。 酯是通过二烷基氨基链烷醇和碳原子数为8-22的饱和或不饱和脂族醇的混合物酯交换烷基聚丙烯酸酯，然后季铵化而得到的。 聚合物不含生理上有疑问的组分，因此可用于制备化妆品，优选用于头发化妆品。 聚合物还适用于整理纤维或纺织品。 本发明还涉及具有叔氨基的聚丙烯酸酯，其在制备具有季铵基团的聚丙烯酸酯的中间体形成。

公开(公告)号：US5633325A

公开(公告)日：1997-05-27

申请号：US593768

申请日：1996-01-29

申请人： Eberhard Esselborn ,  Jurgen Fock

发明人： Eberhard Esselborn ,  Jurgen Fock

IPC分类号： C08F2/42 ,  C08F8/14 ,  C08F8/30 ,  C08F20/10 ,  C08F20/12 ,  C08F8/34

CPC分类号： C08F8/14 ,  C08F8/30 ,  C08F2810/30 ,  C08F2810/40

摘要： Novel polymethacrylate esters are prepared; the ester groups of which in the .alpha. and optionally also in the .omega. position differ from the ester groups in the chain. The invention furthermore relates to a method for the synthesis of these compounds by transesterification under selected method conditions.

摘要翻译： 制备新型聚甲基丙烯酸酯; 其中α基团和任选还在ω位置的酯基与链中的酯基不同。 本发明还涉及通过在选择的方法条件下酯交换合成这些化合物的方法。

公开(公告)号：US5523373A

公开(公告)日：1996-06-04

申请号：US424745

申请日：1995-04-18

申请人： Eberhard Esselborn ,  Jurgen Fock

发明人： Eberhard Esselborn ,  Jurgen Fock

IPC分类号： C08G77/442 ,  C08G81/02 ,  C08G77/04

CPC分类号： C08G77/442 ,  C08G81/024

摘要： The invention relates to polymethacrylate ester/polysiloxane block copolymer of the ABA or AB type, A being a polymethacrylate ester block and B a polysiloxane block. The invention furthermore relates to a method for the synthesis of such block copolymers as well as to a method to modify synthetic resins, particularly those based on (meth)acrylates, by adding an effective amount of the inventive block copolymer. The invention also relates to the block copolymer as additives for organic lacquer and varnish systems.

摘要翻译： 本发明涉及ABA或AB型的聚甲基丙烯酸酯/聚硅氧烷嵌段共聚物，A是聚甲基丙烯酸酯嵌段，B是聚硅氧烷嵌段。 本发明还涉及一种合成这种嵌段共聚物的方法以及通过加入有效量的本发明嵌段共聚物来改性合成树脂，特别是基于（甲基）丙烯酸酯的那些的方法。 本发明还涉及嵌段共聚物作为有机漆和清漆体系的添加剂。

公开(公告)号：US5145914A

公开(公告)日：1992-09-08

申请号：US665778

申请日：1991-03-07

申请人： Eberhard Esselborn ,  Jurgen Fock ,  Helmut Lammerting

发明人： Eberhard Esselborn ,  Jurgen Fock ,  Helmut Lammerting

IPC分类号： B01F17/52 ,  C08F8/44 ,  C08F20/34 ,  D06M13/02 ,  D06M13/322 ,  D06M13/467 ,  D06M13/47 ,  D06M13/477 ,  D06M15/267

CPC分类号： C08F8/44

摘要： Polyacrylate esters with ammonium salt groups obtained by the transesterification of alkyl polyacrylates produced by free radical polymerization are disclosed, wherein the alkyl groups of the acrylate esters have 1 to 8 carbon atoms, up to 50% of the acrylate esters can be replaced by the corresponding methacrylate esters and the transesterification is carried out witha) compounds of the formula ##STR1## b) saturated or unsaturated aliphatic alcohols having 8 to 22 carbon atoms or alkoxylated alkylphenols having 9 to 27 carbon atoms in the alkylphenol group,wherein the molar ratio of component a) to component b) is 1:9 to 9:1, in such amount that 5 to 70% of the ester groups are transesterified and subsequently, the transesterification product is transformed into a salt. The new polyacrylate esters with ammonium salt groups are distinguished by containing a lesser amount of low molecular weight compounds than products obtained through copolymerization and can be used as cationic surfactants and particularly, as active ingredients of metal adjuvants.

摘要翻译： 公开了通过通过自由基聚合制备的烷基聚丙烯酸酯的酯交换获得的具有铵盐基团的聚丙烯酸酯，其中丙烯酸酯的烷基具有1至8个碳原子，至多50％的丙烯酸酯可以被相应的 甲基丙烯酸酯和酯交换是用下列化合物进行的：a）下式化合物：b）烷基酚基中具有8-22个碳原子的饱和或不饱和脂族醇或具有9至27个碳原子的烷氧基化烷基酚，其中摩尔比 组分a）至组分b）为1:9至9:1，其用量为5至70％的酯基酯交换，随后将酯交换产物转化为盐。 具有铵盐基团的新的聚丙烯酸酯通过含有比通过共聚获得的产物更少量的低分子量化合物来区分，并且可以用作阳离子表面活性剂，特别是作为金属助剂的活性成分。