摘要:
A process for the manufacture of acicular magnetic gamma-iron(III) oxide by reducing acicular alpha-iron(III) oxide to magnetite and then oxidizing it to gamma-iron(III) oxide, wherein the alpha-iron(III) oxide is treated with a water-soluble alkaline earth metal compound and an alkylphenol with one to three alkyl radicals, each of 4 to 24 carbon atoms, on the benzene nucleus. Gamma-iron(III) oxides manufactured in this way show better magnetic orientability in the binder-containing dispersion, and a higher coercive force than prior art magnetic pigments.
摘要:
A process for the manufacture of acicular gamma-iron(III) oxide, in which the non-magnetic, acicular iron(III) oxide is treated with a solution of a compound of the formula I ##STR1## where R.sup.1 and R.sup.2 are ##STR2## or O--R.sup.5, R.sup.3 is H, OH, ##STR3## or O--R.sup.5, R.sup.4 is alkyl or cycloalkyl of 1 to 16 carbon atoms and the R.sup.4 's may be identical or different, and R.sup.5 is alkyl, cycloalkyl or aralkyl of 3 to 18 carbon atoms, and is then converted to gamma-iron(III) oxide by reduction to magnetite, followed by oxidation.The gamma-iron(III) oxide obtained is distinguished by a high coercive force and improved magnetic orientation when used as a magnetic pigment for the manufacture of magnetic recording media.
摘要:
Goethite is obtained by reacting an aqueous solution of an iron (II) salt with an aqueous solution of an alkali metal hydroxide and oxidizing the resulting iron(II) hydroxide. The oxidation is carried out in three stages. In the first stage, from 4 to 15% by weight are oxidized in the course of from 0.4 to 5 hours, in the second stage from 60 to 85% by weight are oxidized in the course of from 1.5 to 6 hours and in a third stage the remaining amount of iron is oxidized.
摘要:
A process for the manufacture of acicular ferromagnetic metal pigments containing iron, having a reduced field strength distribution and a steeper residual magnetization curve, by applying an alkaline earth metal cation and an organic compound having at least one group capable of forming a chelate to appropriate acicular iron oxides and then reducing the treated oxides.
摘要:
A process for the manufacture of acicular ferromagnetic metal pigments containing iron, having a reduced field strength distribution and a steeper residual magnetization curve, by applying equivalent amounts of an alkaline earth metal cation and of a monobasic, dibasic or tribasic aliphatic carboxylic acid of up to 6 carbon atoms onto appropriate acicular iron oxides and then reducing the treated oxides.
摘要:
A method of stabilizing pyrophoric metal powders by treating the metal powders with alkylene oxides to form a polymer coating on the metal particles.
摘要:
Chromium dioxide magnetic pigments can be stabilized against the loss of their magnetic properties by treating them, in alcoholic aqueous suspension, with a silane or a hydrolysis product thereof, so that when the pigment is isolated from the suspension medium the particles bear at least partially hydrolyzed silane on their surfaces, and then drying the magnetic pigment at from 50.degree. to 200.degree. C.
摘要:
The invention relates to the manufacture of acicular cobalt-modified .gamma.-iron(III) oxide by coating an acicular .alpha.-iron(III) oxide or its hydrate with an inorganic protective coating, subsequent reduction to magnetite at 350.degree. to 650.degree. C, application of the cobalt compound to this magnetite or to the .gamma.-iron(III) oxide obtained therefrom by oxidation, and subsequent heat treatment at 80.degree. to 300.degree. C, if necessary with simultaneous oxidation of the magnetite to the corresponding .gamma.-iron(III) oxide. This iron oxide has high coercivity and can be used as the magnetic component in magnetic recording media for recording high frequencies without having the disadvantage of thermal and mechanical instability.
摘要:
A process for stabilizing pyrophoric acicular metal particles consisting essentially of iron, by reaction with oxygen-containing gases in two stages, wherein, in the first stage, up to 1/3 of the passivating layer present in the final state is formed at from 25.degree. to 45.degree. C. and, in a subsequent second stage, the remainder of the passivating layer is formed at from 50.degree. to 70.degree. C.
摘要:
A process for the preparation of acicular ferrimagnetic iron oxides by reducing gamma-iron(III) oxide hydroxide to magnetite, at from 280.degree. to 620.degree. C., by means of an organic compound which is decomposable at this temperature in the presence of iron oxide, and, optionally, a stream of reducing gas, and, if desired, then oxidizing the magnetite with oxygen-containing gases, at from 150.degree. to 450.degree. C., to acicular ferrimagnetic iron oxide of the formula FeO.sub.x, where x is from above 1.33 to 1.50, wherein the organic compound used for the reduction is a non-polar glycerol ester of a fatty acid which is introduced into the aqueous reaction suspension during the preparation of the gamma-iron(III) oxide hydroxide.