Manufacture of gamma-iron(III) oxide
    1.
    发明授权
    Manufacture of gamma-iron(III) oxide 失效
    制造γ-铁(III)氧化物

    公开(公告)号:US4071610A

    公开(公告)日:1978-01-31

    申请号:US677920

    申请日:1976-04-19

    摘要: A process for the manufacture of acicular gamma-iron(III) oxide, in which the non-magnetic, acicular iron(III) oxide is treated with a solution of a compound of the formula I ##STR1## where R.sup.1 and R.sup.2 are ##STR2## or O--R.sup.5, R.sup.3 is H, OH, ##STR3## or O--R.sup.5, R.sup.4 is alkyl or cycloalkyl of 1 to 16 carbon atoms and the R.sup.4 's may be identical or different, and R.sup.5 is alkyl, cycloalkyl or aralkyl of 3 to 18 carbon atoms, and is then converted to gamma-iron(III) oxide by reduction to magnetite, followed by oxidation.The gamma-iron(III) oxide obtained is distinguished by a high coercive force and improved magnetic orientation when used as a magnetic pigment for the manufacture of magnetic recording media.

    摘要翻译: 一种用于制造针状γ-铁(III)氧化物的方法,其中非磁性针状铁(III)氧化物用式I化合物(I)的溶液处理,其中R1和R2 或者O-R5,R 3是H,OH,O或R 5,R 4是1至16个碳原子的烷基或环烷基,R 4可以相同或不同,R 5是烷基,环烷基或 3至18个碳原子的芳烷基,然后通过还原成磁铁矿转化为γ-铁(III)氧化物,随后进行氧化。

    Manufacture of gamma-iron (III) oxide
    2.
    发明授权
    Manufacture of gamma-iron (III) oxide 失效
    制造γ-铁(III)氧化物

    公开(公告)号:US4018882A

    公开(公告)日:1977-04-19

    申请号:US616863

    申请日:1975-09-25

    摘要: A process for the manufacture of acicular magnetic gamma-iron(III) oxide by reducing acicular alpha-iron(III) oxide to magnetite and then oxidizing it to gamma-iron(III) oxide, wherein the alpha-iron(III) oxide is treated with a water-soluble alkaline earth metal compound and an alkylphenol with one to three alkyl radicals, each of 4 to 24 carbon atoms, on the benzene nucleus. Gamma-iron(III) oxides manufactured in this way show better magnetic orientability in the binder-containing dispersion, and a higher coercive force than prior art magnetic pigments.

    摘要翻译: 通过将针状氧化铁(III)还原成磁铁矿然后将其氧化成γ-铁(III)氧化物来制造针状磁性γ-铁(III)氧化物的方法,其中氧化铁(III)为 在苯核上用水溶性碱土金属化合物和烷基酚与一至三个碳原子数为4〜24个的烷基进行处理。 以这种方式制造的γ-氧化铁(III)氧化物在含粘合剂的分散体中显示出更好的磁定向性,并且比现有技术的磁性颜料具有更高的矫顽力。

    Magnetic materials with exchange anisotropy and process for their
manufacture
    7.
    发明授权
    Magnetic materials with exchange anisotropy and process for their manufacture 失效
    具有交换各向异性的磁性材料及其制造方法

    公开(公告)号:US3959032A

    公开(公告)日:1976-05-25

    申请号:US535577

    申请日:1974-12-23

    摘要: Magnetic materials which essentially consist of a phase A with a ferromagnetic spin system and a phase B with an anti-ferromagnetic spin system, phases A and B interacting by exchange coupling, and the manufacture of such materials. The materials consist essentially of two-phase magnetic single-domain particles, with the alloy [Co.sub.x Ni.sub.1.sub.-x ] as the ferromagnetic phase A and its oxidized form [(CoO).sub.x (NiO).sub.1.sub.-x ] as the anti-ferromagnetic phase B, with values of x of 0.04 to 0.96. They are manufactured by surface oxidation of a pigment layer, which at least covers the surface but may extend deeper, having the composition of phase A, to form an oxide layer, at least 40 A thick, of the phase B, followed by heating in an inert gas atmosphere, or by reduction of a corresponding layer of phase B to a layer of phase A. Magnetic single-domain particles of this composition have a Neel temperature which varies with X. As a result, materials are obtained which have an asymmetrical hysteresis loop, attributable to exchange anisotropy, at temperatures which can be varied within wide limits in accordance with the intended use of the material.

    摘要翻译: 磁性材料基本上由具有铁磁自旋系统的相A和具有反铁磁旋转系统的相B组成,A相和B相通过交换耦合相互作用,并且制造这种材料。 这些材料基本上由两相磁性单畴粒子组成,合金[CoxNi1-x]作为铁磁相A,其氧化形式[(CoO)x(NiO)1-x]作为反铁磁相B ,值x为0.04至0.96。 它们通过颜料层的表面氧化制造,颜料层至少覆盖表面但可以延伸得更深,具有相A的组成,以形成相B的至少40μA的氧化物层,随后加热 惰性气体气氛,或通过将相B的相应层减少到相A层。该组合物的磁性单畴颗粒具有随X变化的Neel温度。结果,获得具有不对称性的材料 可归因于交换各向异性的磁滞回线,其温度可以根据材料的预期用途在宽范围内变化。

    Manufacture of magnetic recording media having a wear-resistant surface
    8.
    发明授权
    Manufacture of magnetic recording media having a wear-resistant surface 失效
    具有耐磨表面的磁记录介质的制造

    公开(公告)号:US4272563A

    公开(公告)日:1981-06-09

    申请号:US765159

    申请日:1977-02-03

    CPC分类号: G11B5/72 G11B5/84

    摘要: A process for the manufacture of wear-resistant magnetic recording media comprising a dimensionally stable base, a thin ferromagnetic metal layer, containing cobalt and/or nickel, firmly bonded thereto and a thin protective layer applied thereon. The protective layer is produced by treating the recording medium in a liquid basic medium, containing gaseous oxygen, for from 1 to 60 minutes at from 5.degree. to 70.degree. C., washing and drying the treated recording medium and then heating it in air at from 170.degree. to 300.degree. C. This method offers a particularly simple way of providing the ferromagnetic layer of the recording medium with a thin but uniform, mechanically stable and wear-resistant protective layer.

    摘要翻译: 一种用于制造耐磨磁记录介质的方法,其包括尺寸稳定的基底,与包含钴和/或镍的薄的铁磁金属层,其牢固地结合到其上并施加有薄的保护层。 保护层通过在含有气态氧的液体碱性介质中在5至70℃下处理记录介质1至60分钟来制备,洗涤和干燥经处理的记录介质,然后在空气中加热 从170℃到300℃。该方法提供了一种特别简单的方式来提供记录介质的铁磁层,其具有薄而均匀的机械稳定且耐磨的保护层。

    Anode for electrochemical processes
    10.
    发明授权
    Anode for electrochemical processes 失效
    阳极电化学过程

    公开(公告)号:US4060476A

    公开(公告)日:1977-11-29

    申请号:US640575

    申请日:1975-12-15

    IPC分类号: C25B11/16 C25B11/04

    CPC分类号: C25B11/16

    摘要: An anode for electrochemical processes consists of an electrode base plate of a metal which can be passivated electrochemically, a protective layer deposited thereon, and a further layer, consisting of manganese dioxide. The protective layer consists of the nitride of the metal of the electrode base plate.

    摘要翻译: 用于电化学过程的阳极由可以电化学钝化的金属的电极基板,沉积在其上的保护层和由二氧化锰组成的另一层组成。 保护层由电极基板的金属的氮化物构成。