公开(公告)号：US06514632B1

公开(公告)日：2003-02-04

申请号：US09661264

申请日：2000-09-13

申请人： Edmund P. Woo ,  William R. Shiang ,  Michael Inbasekaran ,  Gordon R. Roof ,  Mark T. Bernius ,  Weishi Wu

发明人： Edmund P. Woo ,  William R. Shiang ,  Michael Inbasekaran ,  Gordon R. Roof ,  Mark T. Bernius ,  Weishi Wu

IPC分类号： B32B900

CPC分类号： H01L51/0043 ,  C07C17/2637 ,  C07C17/266 ,  C07C25/22 ,  C07C25/24 ,  C07C211/48 ,  C07C2602/44 ,  C07C2603/18 ,  C08G61/00 ,  C08G61/02 ,  C08G61/10 ,  C09B69/105 ,  C09B69/109 ,  C09K11/06 ,  C09K2211/1408 ,  C09K2211/1416 ,  H01L51/0036 ,  H01L51/0037 ,  H01L51/0038 ,  H01L51/0039 ,  H01L51/0042 ,  H01L51/0052 ,  H01L51/0059 ,  H01L51/0062 ,  H01L51/007 ,  H01L51/0081 ,  H01L51/42 ,  H01L51/5012 ,  H01L2251/308 ,  Y10S428/917

摘要： A compound of the formula: and compounds of the formulas: wherein R1 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl containing one or more S, N, O, P or Si atoms, C4-16 hydrocarbyl carbonyloxy, C4-16 aryl(trialkylsiloxy) or both R1 may form with the 9-carbon on the fluorene ring a C5-20 ring structure or a C4-20 ring structure containing one or more heteroatoms of S, N or O; R2 is independently in each occurrence C1-20 hydrocarbyl, C120 hydrocarbyloxy, C1-20 thioether, C1-20 hydrocarbylcarbonyloxy or cyano; R3 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl substituted with di(C1-20 alkyl)amino, C1-20 hydrocarbyloxy or C1-20 hydrocarbyl or tri(C1-10 alkyl)siloxy; a is independently in each occurrence 0 or 1; X is independently in each occurrence a halogen moiety; and Z is independently in each occurrence —B(OH)2, —B(OR4)2 or  wherein R4 is independently in each occurrence a C1-10 alkyl group and, R5 is independantly in each occurrence a C2-10 alkylene group.

摘要翻译： 下式的化合物和下式的化合物：其中R 1在每次出现时独立地为C 1-20烃基或含有一个或多个S，N，O，P或Si原子的C 1-20烃基，C 4-16烃基羰氧基，C 4 -16芳基（三烷基甲硅烷氧基）或两者R 1可以与芴环上的9-碳形成C5-20环结构或含有一个或多个S，N或O杂原子的C 4-20环结构; R 2各自独立地表示 C 1-20烃基，C 1-20烃基羰基氧基或氰基; R 3在每次出现时独立地为C 1-20烃基或被二（C 1-20烷基）氨基取代的C 1-20烃基，C 1-20 烃氧基或C 1-20烃基或三（C 1-10烷基）甲硅烷氧基; a各自独立地为0或1; X各自独立地为卤素部分; 和Z各自独立地为-B（OH）2，-B（OR 4）2或其中R 4在每次出现时独立地为C 1-10烷基，并且R 5在每次出现时独立地为C 2-10亚烷基。

公开(公告)号：US06512083B1

公开(公告)日：2003-01-28

申请号：US09661237

申请日：2000-09-13

申请人： Edmund P. Woo ,  William R. Shiang ,  Michael Inbasekaran ,  Gordon R. Roof ,  Mark T. Bernius ,  Weishi Wu

发明人： Edmund P. Woo ,  William R. Shiang ,  Michael Inbasekaran ,  Gordon R. Roof ,  Mark T. Bernius ,  Weishi Wu

IPC分类号： C08G6100

CPC分类号： H01L51/0043 ,  C07C17/2637 ,  C07C17/266 ,  C07C25/22 ,  C07C25/24 ,  C07C211/48 ,  C07C2602/44 ,  C07C2603/18 ,  C08G61/00 ,  C08G61/02 ,  C08G61/10 ,  C09B69/105 ,  C09B69/109 ,  C09K11/06 ,  C09K2211/1408 ,  C09K2211/1416 ,  H01L51/0036 ,  H01L51/0037 ,  H01L51/0038 ,  H01L51/0039 ,  H01L51/0042 ,  H01L51/0052 ,  H01L51/0059 ,  H01L51/0062 ,  H01L51/007 ,  H01L51/0081 ,  H01L51/42 ,  H01L51/5012 ,  H01L2251/308 ,  Y10S428/917

摘要： A compound of the formula: and compounds of the formulas: wherein R1 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl containing one or more S, N, O, P or Si atoms, C4-16 hydrocarbyl carbonyloxy, C4-16 aryl(trialkylsiloxy) or both R1 may form with the 9-carbon on the fluorene ring a C5-20 ring structure or a C4-20 ring structure containing one or more heteroatoms of S, N or O; R2 is independently in each occurrence C1-20 hydrocarbyl, C1-20 hydrocarbyloxy, C1-20 thioether, C1-20 hydrocarbylcarbonyloxy or cyano; R3 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl substituted with di(C1-20 alkyl)amino, C1-20 hydrocarbyloxy or C1-20 hydrocarbyl or tri(C1-10 alkyl)siloxy; a is independently in each occurrence 0 or 1; X is independently in each occurrence a halogen moiety; and Z is independently in each occurrence —B(OH)2, —B(OR4)2 or  wherein R4 is independently in each occurrence a C1-10 alkyl group and R5 is independently in each occurrence a C2-10 alkylene group.

摘要翻译： 下式的化合物及下式的化合物：其中R1各自独立地为C 1-20烃基或含有一个或多个S，N，O，P或Si原子的C 1-20烃基，C 4-16烃基羰氧基， 16芳基（三烷基甲硅烷氧基）或两者可以与芴环上的9-碳形成C5-20环结构或含有一个或多个S，N或O的杂原子的C 4-20环结构; R 2在每次出现时独立地 C 1-20烃基，C 1-20烃基氧基，C 1-20硫醚，C 1-20烃基羰基氧基或氰基; R 3在每次出现时独立地为C 1-20烃基或被二（C 1-20烷基）氨基取代的C 1-20烃基， 20烃氧基或C 1-20烃基或三（C 1-10烷基）甲硅烷氧基; a各自独立地为0或1; X在每次出现时独立地为卤素部分; 和Z各自独立地为-B（OH）2，-B（OR 4）2或其中R 4在每次出现时独立地为C 1-10烷基，R 5在每次出现时独立地为C 2-10亚烷基。

公开(公告)号：US06362310B1

公开(公告)日：2002-03-26

申请号：US09661263

申请日：2000-09-13

申请人： Edmund P. Woo ,  Michael Inbasekaran ,  William R. Shiang ,  Gordon R. Roof ,  Mark T. Bernius ,  Weishi Wu

发明人： Edmund P. Woo ,  Michael Inbasekaran ,  William R. Shiang ,  Gordon R. Roof ,  Mark T. Bernius ,  Weishi Wu

IPC分类号： C08L2712

CPC分类号： H01L51/0043 ,  C07C17/2637 ,  C07C17/266 ,  C07C25/22 ,  C07C25/24 ,  C07C211/48 ,  C07C2602/44 ,  C07C2603/18 ,  C08G61/00 ,  C08G61/02 ,  C08G61/10 ,  C09B69/105 ,  C09B69/109 ,  C09K11/06 ,  C09K2211/1408 ,  C09K2211/1416 ,  H01L51/0036 ,  H01L51/0037 ,  H01L51/0038 ,  H01L51/0039 ,  H01L51/0042 ,  H01L51/0052 ,  H01L51/0059 ,  H01L51/0062 ,  H01L51/007 ,  H01L51/0081 ,  H01L51/42 ,  H01L51/5012 ,  H01L2251/308 ,  Y10S428/917

摘要： A compound of the formula: and compounds of the formulas: wherein R1 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl containing one or more S, N, O, P or Si atoms, C4-16 hydrocarbyl carbonyloxy, C14-16 aryl(trialkylsiloxy) or both R1 may form with the 9-carbon on the fluorene ring a C5-20 ring structure or a C4-20 ring structure containing one or more heteroatoms of S, N or O; R2 is independently in each occurrence C1-20 hydrocarbyl, C1-20 hydrocarbyloxy, C1-20 thioether, C1-20 hydrocarbylcarbonyloxy or cyano; R3 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl substituted with di(C1-20 alkyl)amino, C1-20 hydrocarbyloxy or C1-20 hydrocarbyl or tri(C1-10 alkyl)siloxy; a is independently in each occurrence 0 or 1; X is independently in each occurrence a halogen moiety; and Z is independently in each occurrence —B(OH)2, —B(OR4)2 or  wherein R4 is independently in each occurrence a C1-10 alkyl group and R5 is independently in each occurence a C2-10 alkylene group.

摘要翻译： 下式的化合物及下式的化合物：其中R1各自独立地为C 1-20烃基或含有一个或多个S，N，O，P或Si原子的C 1-20烃基，C 4-6烃基羰基氧基，C 14 -16芳基（三烷基甲硅烷氧基）或两者R 1可以与芴环上的9-碳形成C5-20环结构或含有一个或多个S，N或O杂原子的C 4-20环结构; R 2各自独立地表示 C 1-20烃基，C 1-20烃基，C 2-20烃基羰基氧基或氰基; R 3在每次出现时独立地为C 1-20烃基或被二（C 1-20烷基）氨基取代的C 1-20烃基，C 1 -20烃氧基或C 1-20烃基或三（C 1-10烷基）甲硅烷氧基; a各自独立地为0或1; X在每次出现时独立地为卤素部分; 并且Z各自独立地为-B（OH）2，-B（OR 4）2，或其中R 4在每次出现时独立地为C 1-10烷基，R 5在每次出现时为C 2-10亚烷基。

公开(公告)号：US06255449B1

公开(公告)日：2001-07-03

申请号：US09661234

申请日：2000-09-13

申请人： Edmund P. Woo ,  Michael Inbasekaran ,  William R. Shiang ,  Gordon R. Roof ,  Mark T. Bernius ,  Weishi Wu

发明人： Edmund P. Woo ,  Michael Inbasekaran ,  William R. Shiang ,  Gordon R. Roof ,  Mark T. Bernius ,  Weishi Wu

IPC分类号： C08G7324

CPC分类号： H01L51/0043 ,  C07C17/2637 ,  C07C17/266 ,  C07C25/22 ,  C07C25/24 ,  C07C211/48 ,  C07C2602/44 ,  C07C2603/18 ,  C08G61/00 ,  C08G61/02 ,  C08G61/10 ,  C09B69/105 ,  C09B69/109 ,  C09K11/06 ,  C09K2211/1408 ,  C09K2211/1416 ,  H01L51/0036 ,  H01L51/0037 ,  H01L51/0038 ,  H01L51/0039 ,  H01L51/0042 ,  H01L51/0052 ,  H01L51/0059 ,  H01L51/0062 ,  H01L51/007 ,  H01L51/0081 ,  H01L51/42 ,  H01L51/5012 ,  H01L2251/308 ,  Y10S428/917

摘要： A compound of the formula: and compound of the formulas: wherein R1 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl containing one or more S, N, O, P or Si atoms, C4-16 hydrocarbyl carbonyloxy, C4-16 aryl(trialkylsiloxy) or both R1 may form with the 9-carbon on the fluorene ring a C5-20 ring structure or a C4-20 ring structure containing one or more heteroatoms of S, N or O; R2 is independently in each occurrence C1-20 hydrocarbyl, C1-20 hydrocarbyloxy, C1-20 thioether, C1-20 hydrocarbylcarbonyloxy or cyano; R3 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl substituted with di(C1-20 alkyl)amino, C1-20 hydrocarbyloxy or C1-20 hydrocarbyl or tri(C1-10 alkyl)siloxy; a is independently in each occurrence 0 or 1; X is independently in each occurrence a halogen moiety; and Z is independently in each occurrence —B(OH)2, —B(OR4)2 or wherein R4 is independently in each occurrence a C1-10 alkyl group. and R5 is independently in each occurrence a C2-10 alkylene group

摘要翻译： 下式化合物及下式化合物：其中R 1在每次出现时独立地为C 1-20烃基或含有一个或多个S，N，O，P或Si原子的C 1-20烃基，C 4-16烃基羰氧基，C 4 -16芳基（三烷基甲硅烷氧基）或两者可以与芴环上的9-碳形成C5-20环结构或含有一个或多个S，N或O杂原子的C 4-20环结构; R 2各自独立地表示 C 1-20烃基，C 1-20烃基，C 2-20烃基羰基氧基或氰基; R 3在每次出现时独立地为C 1-20烃基或被二（C 1-20烷基）氨基取代的C 1-20烃基，C 1 -20烃氧基或C 1-20烃基或三（C 1-10烷基）甲硅烷氧基; a各自独立地为0或1; X在每次出现时独立地为卤素部分; 和Z各自独立地为-B（OH）2，-B（OR 4）2，或者R 4在每次出现时独立地为C 1-10烷基。 在每次出现时，R 5独立地为C 2-10亚烷基

公开(公告)号：US06900285B2

公开(公告)日：2005-05-31

申请号：US10318579

申请日：2002-12-13

申请人： Edmund P. Woo ,  William R. Shiang ,  Michael Inbasekaran ,  Gordon R. Roof ,  Mark T. Bernius ,  Weishi Wu

发明人： Edmund P. Woo ,  William R. Shiang ,  Michael Inbasekaran ,  Gordon R. Roof ,  Mark T. Bernius ,  Weishi Wu

IPC分类号： C07C17/26 ,  C07C17/266 ,  C07C25/22 ,  C07C25/24 ,  C07C43/225 ,  C07C69/00 ,  C07C211/48 ,  C07C211/52 ,  C08G61/00 ,  C08G61/02 ,  C08G61/10 ,  C09K11/06 ,  H01L51/00 ,  H01L51/30 ,  H01L51/42 ,  H01L51/50 ,  C08G75/00

CPC分类号： H01L51/0043 ,  C07C17/2637 ,  C07C17/266 ,  C07C25/22 ,  C07C25/24 ,  C07C211/48 ,  C07C2602/44 ,  C07C2603/18 ,  C08G61/00 ,  C08G61/02 ,  C08G61/10 ,  C09B69/105 ,  C09B69/109 ,  C09K11/06 ,  C09K2211/1408 ,  C09K2211/1416 ,  H01L51/0036 ,  H01L51/0037 ,  H01L51/0038 ,  H01L51/0039 ,  H01L51/0042 ,  H01L51/0052 ,  H01L51/0059 ,  H01L51/0062 ,  H01L51/007 ,  H01L51/0081 ,  H01L51/42 ,  H01L51/5012 ,  H01L2251/308 ,  Y10S428/917

摘要： A polymer comprising repeat units of the formula: wherein R1 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl containing one or more heteroatoms of S, N, O, P or Si or both R1 may form, with the 9-carbon of the fluorene ring, a C5-20 ring structure containing one or more heteroatoms of S, N, or O; R2 is independently in each occurrence C1-20 hydrocarbyl, C1-20 hydrocarbyloxy, C1-20 thioether, C1-20 hydrocarbyloxycarbonyl, hydrocarbylcarbonyloxy, or cyano; a is independently in each occurrence a number from about 0 to about 1; m is a number from about 1 to about 2; and n is a number from about 3 or greater.

摘要翻译： 包含下式重复单元的聚合物：其中R 1在每次出现时独立地为含有一个或多个S，N的杂原子的烃基或C 1-20烃基 ，O，P或Si或两者R 1可以与芴环的9-碳形成含有一个或多个杂原子的C 5-20-20环结构， S，N或O; R 2在每次出现时独立地为C 1-20烃基，C 1-20烃氧基，C 1-20 >硫醚，C 1-20烃氧基羰基，烃基羰基氧基或氰基; a在每次出现时独立地为约0至约1的数; m为约1至约2的数; n为约3以上的数。

公开(公告)号：US06169163A

公开(公告)日：2001-01-02

申请号：US08861469

申请日：1997-05-21

申请人： Edmund P. Woo ,  Michael Inbasekaran ,  William R. Shiang ,  Gordon R. Roof ,  Mark T. Bernius ,  Weishi Wu

发明人： Edmund P. Woo ,  Michael Inbasekaran ,  William R. Shiang ,  Gordon R. Roof ,  Mark T. Bernius ,  Weishi Wu

IPC分类号： C08G6100

CPC分类号： H01L51/0043 ,  C07C17/2637 ,  C07C17/266 ,  C07C25/22 ,  C07C25/24 ,  C07C211/48 ,  C07C2602/44 ,  C07C2603/18 ,  C08G61/00 ,  C08G61/02 ,  C08G61/10 ,  C09B69/105 ,  C09B69/109 ,  C09K11/06 ,  C09K2211/1408 ,  C09K2211/1416 ,  H01L51/0036 ,  H01L51/0037 ,  H01L51/0038 ,  H01L51/0039 ,  H01L51/0042 ,  H01L51/0052 ,  H01L51/0059 ,  H01L51/0062 ,  H01L51/007 ,  H01L51/0081 ,  H01L51/42 ,  H01L51/5012 ,  H01L2251/308 ,  Y10S428/917

摘要： A compound of the formula: and compounds of the formulas: wherein R1 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl containing one or more S, N, O, P or Si atoms, C4-16 hydrocarbyl carbonyloxy, C4-16 aryl(trialkylsiloxy) or both R1 may form with the 9-carbon on the fluorene ring a C5-20 ring structure or a C4-20 ring structure containing one or more heteroatoms of S, N or O; R2 is independently in each occurrence C1-20 hydrocarbyl, C1-20 hydrocarbyloxy, C1-20 thioether, C1-20 hydrocarbylcarbonyloxy or cyano; R3 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl substituted with di(C1-20 alkyl)amino, C1-20 hydrocarbyloxy or C1-20 hydrocarbyl or tri(C1-10 alkyl)siloxy; a is independently in each occurrence 0 or 1; X is independently in each occurrence a halogen moiety; and Z is independently in each occurrence —B(OH)2, —B(OR4)2 or wherein R4 is independently in each occurrence a C1-10 alkyl group and R5 is independently in each occurrence a C2-10 alkylene group.

摘要翻译： 下式的化合物和下式的化合物：其中R 1在每次出现时独立地为C 1-20烃基或含有一个或多个S，N，O，P或Si原子的C 1-20烃基，C 4-16烃基羰氧基，C 4 -16芳基（三烷基甲硅烷氧基）或两者R 1可以与芴环上的9-碳形成C5-20环结构或含有一个或多个S，N或O杂原子的C 4-20环结构; R 2各自独立地表示 C 1-20烃基，C 1-20烃基，C 2-20烃基羰基氧基或氰基; R 3在每次出现时独立地为C 1-20烃基或被二（C 1-20烷基）氨基取代的C 1-20烃基，C 1 -20烃氧基或C 1-20烃基或三（C 1-10烷基）甲硅烷氧基; a各自独立地为0或1; X在每次出现时独立地为卤素部分; 和Z各自独立地为-B（OH）2，-B（OR 4）2，或者R 4在每次出现时独立地为C 1-10烷基，R 5在每次出现时独立地为C 2-10亚烷基。

公开(公告)号：US5962631A

公开(公告)日：1999-10-05

申请号：US994187

申请日：1997-12-19

申请人： Edmund P. Woo ,  William R. Shiang ,  Michael Inbasekaran ,  Gordon R. Roof

发明人： Edmund P. Woo ,  William R. Shiang ,  Michael Inbasekaran ,  Gordon R. Roof

IPC分类号： C07C17/26 ,  C07C17/266 ,  C07C25/22 ,  C07C25/24 ,  C07C43/225 ,  C07C69/00 ,  C07C211/48 ,  C08G61/00 ,  C08G61/02 ,  C08G61/10 ,  C09K11/06 ,  H01L21/28 ,  H01L21/336 ,  H01L21/66 ,  H01L29/423 ,  H01L51/00 ,  H01L51/30 ,  H01L51/42 ,  H01L51/50

CPC分类号： H01L51/0052 ,  C07C17/2637 ,  C07C17/266 ,  C07C211/48 ,  C07C25/22 ,  C07C25/24 ,  C08G61/00 ,  C08G61/02 ,  C08G61/10 ,  C09K11/06 ,  H01L21/28035 ,  H01L21/28167 ,  H01L22/20 ,  H01L29/42364 ,  H01L29/42376 ,  H01L29/66575 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/0058 ,  C07C2103/18 ,  H01L51/0094 ,  H01L51/42 ,  H01L51/5012 ,  Y10S428/917 ,  Y10T428/3154

摘要： The invention relates to 2,7-substituted-9-substituted fluorenes and 9-substituted fluorene oligomers and polymers. The fluorenes, oligomers and polymers are substituted at the 9-position with two hydrocarbyl moieties which may optionally contain one or more of sulfur, nitrogen, oxygen, phosphorous or silicon heteroatoms; a C.sub.5-20 ring structure formed with the 9-carbon on the fluorene ring or a C.sub.4-20 ring structure formed with the 9-carbon containing one or more heteroatoms of sulfur, nitrogen or oxygen; or a hydrocarbylidene moiety. In one embodiment, the fluorenes are substituted at the 2- and 7-positions with aryl moieties which may further be substituted with moieties which are capable of crosslinking or chain extension or a trialkylsiloxy moiety. The fluorene polymers and oligomers may be substituted at the 2- and 7'-positions. The monomer units of the fluorene oligomers and polymers are bound to one another at the 2- and 7'-positions. The 2,7'-aryl-9-substituted fluorene oligomers and polymers may be further reacted with one another to form higher molecular weight polymers by causing the optional moieties on the terminal 2,7'-aryl moieties, which are capable of crosslinking or chain extension, to undergo chain extension or crosslinking. Also disclosed are processes for preparing the disclosed compounds.

摘要翻译： 本发明涉及2,7-取代的9-取代的芴和9-取代的芴低聚物和聚合物。 芴，低聚物和聚合物在9位被两个烃基部分取代，该烃基部分可任选地含有一个或多个硫，氮，氧，磷或硅杂原子; 由芴环上的9-碳形成的C5-20环结构或由含有一个或多个硫，氮或氧杂原子的9-碳形成的C 4-20环结构; 或亚烃基部分。 在一个实施方案中，芴在2-和7-位被芳基部分取代，芳基部分可进一步被能够交联或延伸的部分或三烷基甲硅烷氧基部分取代。 芴聚合物和低聚物可以在2-和7-位取代。 芴低聚物和聚合物的单体单元在2和7'位置彼此结合。 2,7'-芳基-9-取代的芴低聚物和聚合物可以进一步彼此反应以通过在端基2,7'-芳基部分上引入任选的部分来形成较高分子量的聚合物，其能够交联或 链延伸，进行链延长或交联。 还公开了制备所公开的化合物的方法。

公开(公告)号：US06593450B2

公开(公告)日：2003-07-15

申请号：US09755507

申请日：2001-01-05

申请人： Edmund P. Woo ,  William R. Shiang ,  Michael Inbasekaran ,  Gordon R. Roof

发明人： Edmund P. Woo ,  William R. Shiang ,  Michael Inbasekaran ,  Gordon R. Roof

IPC分类号： C08G6100

CPC分类号： H01L51/0052 ,  C07C17/2637 ,  C07C17/266 ,  C07C25/22 ,  C07C25/24 ,  C07C211/48 ,  C07C2603/18 ,  C08G61/00 ,  C08G61/02 ,  C08G61/10 ,  C09K11/06 ,  H01L21/28035 ,  H01L21/28167 ,  H01L22/20 ,  H01L29/42364 ,  H01L29/42376 ,  H01L29/66575 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/0058 ,  H01L51/0094 ,  H01L51/42 ,  H01L51/5012 ,  Y10S428/917 ,  Y10T428/3154

摘要： The invention relates to 2,7-substituted-9-substituted fluorenes and 9-substituted fluorene oligomers and polymers. The fluorenes, oligomers and polymers are substituted at the 9-position with two hydrocarbyl moieties which may optionally contain one or more of sulfur, nitrogen, oxygen, phosphorous or silicon heteroatoms; a C5-20 ring structure formed with the 9-carbon on the fluorene ring or a C4-20 ring structure formed with the 9-carbon containing one or more heteroatoms of sulfur, nitrogen or oxygen; or a hydrocarbylidene moiety. In one embodiment, the fluorenes are substituted at the 2- and 7-positions with aryl moieties which may further be substituted with moieties which are capable of crosslinking or chain extension or a trialkylsiloxy moiety. The fluorene polymers and oligomers may be substituted at the 2- and 7′-positions. The monomer units of the fluorene oligomers and polymers are bound to one another at the 2- and 7′-positions. The 2,7′-aryl-9-substituted fluorene oligomers and polymers may be further reacted with one another to form higher molecular weight polymers by causing the optional moieties on the terminal 2,7′-aryl moieties, which are capable of crosslinking or chain extension, to undergo chain extension or crosslinking. Also disclosed are processes for preparing the disclosed compounds.

摘要翻译： 本发明涉及2,7-取代的9-取代的芴和9-取代的芴低聚物和聚合物。 芴，低聚物和聚合物在9位被两个烃基部分取代，该烃基部分可任选地含有一个或多个硫，氮，氧，磷或硅杂原子; 由芴环上的9-碳形成的C5-20环结构或由含有一个或多个硫，氮或氧杂原子的9-碳形成的C 4-20环结构; 或亚烃基部分。 在一个实施方案中，芴在2-和7-位被芳基部分取代，芳基部分可进一步被能够交联或延伸的部分或三烷基甲硅烷氧基部分取代。 芴聚合物和低聚物可以在2-和7-位取代。 芴低聚物和聚合物的单体单元在2和7'位置彼此结合。 2,7'-芳基-9-取代的芴低聚物和聚合物可以进一步彼此反应以通过在端基2,7'-芳基部分上引入任选的部分来形成较高分子量的聚合物，其能够交联或 链延伸，进行链延长或交联。 还公开了制备所公开的化合物的方法。

公开(公告)号：US5929194A

公开(公告)日：1999-07-27

申请号：US967348

申请日：1997-10-27

申请人： Edmund P. Woo ,  Michael Inbasekaran ,  William R. Shiang ,  Gordon R. Roof

发明人： Edmund P. Woo ,  Michael Inbasekaran ,  William R. Shiang ,  Gordon R. Roof

IPC分类号： C08G73/02 ,  C09K11/06 ,  H01L51/30 ,  H01L51/50 ,  C08G12/00 ,  C08G69/26 ,  C08G73/00

CPC分类号： H01L51/5012 ,  C08G73/02 ,  C08G73/026 ,  C09K11/06 ,  H01L51/0035 ,  H01L51/0059 ,  H01L51/0052

摘要： The invention relates to poly(tertiary di- or polyarylamines) which have more than one aryl moiety which is further substituted with a moiety capable of chain extension or crosslinking. In another aspect, the invention relates to poly(tertiary di- or polyarylamines) which have more than one aryl moiety which is further substituted with a moiety capable of chain extension or crosslinking which are partially or completely crosslinked or chain extended. The invention further relates to films prepared from such chain extended or crosslinked poly(tertiary di- or polyarylamines). The invention further relates to electrophotographic devices and electroluminescent devices, such as polymeric light-emitting diodes, containing such films.

摘要翻译： 本发明涉及具有多于一个芳基部分的聚（叔二或多芳基胺），其进一步被能够扩链或交联的部分取代。 在另一方面，本发明涉及具有多于一个芳基部分的聚（叔二或多芳基胺），其进一步被部分或完全交联或链延长的能够扩链或交联的部分取代。 本发明还涉及由这种扩链或交联的聚（叔二或多芳基胺）制备的膜。 本发明还涉及包含这种膜的电子照相设备和电致发光器件，例如聚合物发光二极管。

公开(公告)号：US5708130A

公开(公告)日：1998-01-13

申请号：US508942

申请日：1995-07-28

申请人： Edmund P. Woo ,  William R. Shiang ,  Michael Inbasekaran ,  Gordon R. Roof

发明人： Edmund P. Woo ,  William R. Shiang ,  Michael Inbasekaran ,  Gordon R. Roof

IPC分类号： C07C17/26 ,  C07C17/266 ,  C07C25/22 ,  C07C25/24 ,  C07C43/225 ,  C07C69/00 ,  C07C211/48 ,  C08G61/00 ,  C08G61/02 ,  C08G61/10 ,  C09K11/06 ,  H01L21/28 ,  H01L21/336 ,  H01L21/66 ,  H01L29/423 ,  H01L51/00 ,  H01L51/30 ,  H01L51/42 ,  H01L51/50

CPC分类号： H01L51/0052 ,  C07C17/2637 ,  C07C17/266 ,  C07C211/48 ,  C07C25/22 ,  C07C25/24 ,  C08G61/00 ,  C08G61/02 ,  C08G61/10 ,  C09K11/06 ,  H01L21/28035 ,  H01L21/28167 ,  H01L22/20 ,  H01L29/42364 ,  H01L29/42376 ,  H01L29/66575 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/0058 ,  C07C2103/18 ,  H01L51/0094 ,  H01L51/42 ,  H01L51/5012 ,  Y10S428/917 ,  Y10T428/3154

摘要： The invention relates to 2,7-substituted-9-substituted fluorenes and 9-substituted fluorene oligomers and polymers. The fluorenes, oligomers and polymers are substituted at the 9-position with two hydrocarbyl moieties which may optionally contain one or more of sulfur, nitrogen, oxygen, phosphorous or silicon heteroatoms; a C.sub.5-20 ring structure formed with the 9-carbon on the fluorene ring or a C.sub.4-20 ring structure formed with the 9-carbon containing one or more heteroatoms of sulfur, nitrogen or oxygen; or a hydrocarbylidene moiety. In one embodiment, the fluorenes are substituted at the 2- and 7-positions with aryl moieties which may further be substituted with moieties which are capable of crosslinking or chain extension or a trialkylsiloxy moiety. The fluorene polymers and oligomers may be substituted at the 2- and 7'-positions. The monomer units of the fluorene oligomers and polymers are bound to one another at the 2- and 7'-positions. The 2,7'-aryl-9-substituted fluorene oligomers and polymers may be further reacted with one another to form higher molecular weight polymers by causing the optional moieties on the terminal 2,7'-aryl moieties, which are capable of crosslinking or chain extension, to undergo chain extension or crosslinking. Also disclosed are processes for preparing the disclosed compounds.