公开(公告)号：US07449426B2

公开(公告)日：2008-11-11

申请号：US11288681

申请日：2005-11-29

申请人： Edouard A. Mamedov ,  Shahid N. Shaikh ,  Armando Araujo

发明人： Edouard A. Mamedov ,  Shahid N. Shaikh ,  Armando Araujo

IPC分类号： B01J23/20 ,  C07C253/26

CPC分类号： C07C253/24 ,  B01J23/002 ,  B01J23/31 ,  B01J37/0236 ,  B01J37/03 ,  B01J2523/00 ,  C07C253/26 ,  Y02P20/52 ,  C07C255/08 ,  B01J2523/31 ,  B01J2523/54 ,  B01J2523/55 ,  B01J2523/69 ,  B01J2523/32 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/48 ,  B01J2523/36 ,  B01J2523/33 ,  B01J2523/56 ,  B01J2523/42 ,  B01J2523/64 ,  B01J2523/47 ,  B01J2523/12 ,  B01J2523/22 ,  B01J2523/43 ,  B01J2523/57 ,  B01J2523/30 ,  B01J2523/41 ,  C07C255/50 ,  C07C255/51

摘要： Disclosed is a catalyst composition which does not contain antimony or molybdenum for the vapor phase ammoxidation of alkanes of the general empirical formula: VWaBibMcOx wherein M is one or more elements selected from sodium, cesium, magnesium, calcium, barium, boron, yttrium, indium, aluminum, gallium, tin, titanium, silicon, zirconium, germanium, niobium and tantalum, a is 0.2 to 10, b is 0.5 to 5, c is 0 to 10 and x is determined by the valence requirements of the elements present. The catalyst precursor is precipitated from a solution or slurry of compounds of vanadium, tungsten, bismuth and, optionally, M, then separated, dried and calcined to give a phase or combination of phases active in the ammoxidation of low-weight paraffins to the corresponding unsaturated mononitriles. Nitriles may be produced in a gas phase catalytic reaction of alkanes with ammonia and oxygen in the presence of the catalyst.

摘要翻译： 公开了一种催化剂组合物，其不含锑或钼，用于通用经验式的烷烃的气相氨氧化：<？in-line-formula description =“In-line formula”end =“lead”？> VW

公开(公告)号：US07186670B2

公开(公告)日：2007-03-06

申请号：US10955550

申请日：2004-09-30

申请人： Edouard A. Mamedov ,  Kathleen A. Bethke ,  Shahid N. Shaikh ,  Armando Araujo ,  Neeta K. Kulkarni

发明人： Edouard A. Mamedov ,  Kathleen A. Bethke ,  Shahid N. Shaikh ,  Armando Araujo ,  Neeta K. Kulkarni

IPC分类号： B01J23/20

CPC分类号： C07C253/24 ,  C07C253/26 ,  Y02P20/142 ,  C07C255/03

摘要： A process for the vapor phase ammoxidation of alkanes and olefins with a catalyst of the general empirical formula: VSbaMbQcOx wherein M is at least one element selected from magnesium, aluminum, zirconium, silicon, hafnium, titanium and niobium, Q is at least one element selected from rhenium, tungsten, molybdenum, tantalum, manganese, phosphorus, cerium, tin, boron, scandium, bismuth, gallium, indium, iron, chromium, lanthanum, yttrium, zinc, cobalt, nickel, cadmium, copper, strontium, barium, calcium, silver, potassium, sodium and cesium, a is 0.5 to 20, b is 2 to 50, c is 0 to 10 and x is determined by the valence requirements of the elements present. The process has a co-feed of gaseous carbon dioxide with an alkane (paraffin) and/or alkene, ammonia and an oxygen-containing gas which react in the presence of the catalyst to form a nitrile and by-products.

摘要翻译： 烷烃和烯烃的气相氨氧化方法，其催化剂具有以下通用经验公式：<？in-line-formula description =“In-line Formulas”end =“lead”？> VSb >>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>> 其中M是选自镁，铝，锆，硅，铪，钛和铌中的至少一种元素，Q是选自铼，钨，钼，钽，锰，磷，铈，锡，硼，钪中的至少一种元素 ，铋，镓，铟，铁，铬，镧，钇，锌，钴，镍，镉，铜，锶，钡，钙，银，钾，钠和铯，a为0.5〜20，b为2〜50 ，c为0至10，x由所存在的元素的化合价要求确定。 该方法具有气态二氧化碳与烷烃（石蜡）和/或烯烃，氨和含氧气体的共同进料，其在催化剂存在下反应以形成腈和副产物。

公开(公告)号：US06710011B2

公开(公告)日：2004-03-23

申请号：US10036866

申请日：2001-12-21

申请人： Edouard A. Mamedov ,  Kathleen A. Bethke ,  Shahid N. Shaikh ,  Armando Araujo ,  Neeta K. Kulkarni ,  Andrei Khodakov

发明人： Edouard A. Mamedov ,  Kathleen A. Bethke ,  Shahid N. Shaikh ,  Armando Araujo ,  Neeta K. Kulkarni ,  Andrei Khodakov

IPC分类号： B01J2320

CPC分类号： C07C253/24 ,  B01J23/002 ,  B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/8472 ,  B01J2523/00 ,  Y02P20/52 ,  C07C255/08 ,  B01J2523/31 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/32 ,  B01J2523/33 ,  B01J2523/22 ,  B01J2523/41 ,  B01J2523/69 ,  B01J2523/35 ,  B01J2523/305 ,  B01J2523/48 ,  B01J2523/51 ,  B01J2523/36 ,  B01J2523/47 ,  B01J2523/13 ,  B01J2523/67 ,  B01J2523/57 ,  B01J2523/68 ,  B01J2523/54 ,  B01J2523/56 ,  B01J2523/43 ,  B01J2523/49 ,  B01J2523/17 ,  B01J2523/3712 ,  B01J2523/27 ,  B01J2523/845 ,  B01J2523/842 ,  B01J2523/24 ,  B01J2523/74 ,  B01J2523/28 ,  B01J2523/12 ,  B01J2523/25 ,  B01J2523/847 ,  B01J2523/23 ,  B01J2523/72

摘要： A catalyst composition for the vapor phase ammoxidation of alkanes and olefins of the general empirical formulae: VSbaMbOx VSbaMbM′b′Ox VSbaMbQcOx VSbaMbQcQ′c′Ox wherein M and M′ are at least one element selected from magnesium, aluminum, zirconium, silicon, hafnium, titanium and niobium, M and M′ being different, Q and Q′ are at least one element selected from rhenium, tungsten, molybdenum, tantalum, manganese, phosphorus, cerium, tin, boron, scandium, bismuth, gallium, indium, iron, chromium, lanthanum, yttrium, zinc, cobalt, nickel, cadmium, copper, strontium, barium, calcium, silver, potassium, sodium and cesium, Q and Q′ being different, a is 0.5 to 20, b is 2 to 50, b′ is 0 to 50, c is 0 to 10, c′ is 0 to 10 and x is determined by the valence requirements of the elements present. The catalyst composition containing isolated vanadium and antimony species in an inert matrix is prepared by incorporating respective compounds of vanadium and antimony into the oxide of at least one or more M and adding by co-precipitation or impregnation one or more optional Q in the relative atomic proportions indicated by the subscripts.

摘要翻译： 用于烷烃和烯烃的气相氨氧化的催化剂组合物的一般经验式：其中M和M'是选自镁，铝，锆，硅，铪，钛和铌中的至少一种元素，M和M'是不同的 Q，Q'为选自铼，钨，钼，钽，锰，磷，铈，锡，硼，钪，铋，镓，铟，铁，铬，镧，钇， 镍，镉，铜，锶，钡，钙，银，钾，钠和铯，Q和Q'不同，a为0.5至20，b为2至50，b'为0至50，c为0至 10，c'为0至10，x由所存在的元素的化合价要求确定。 在惰性基质中含有分离的钒和锑物质的催化剂组合物是通过将各种化合物的钒和锑引入到至少一个或多个M的氧化物中并通过共沉淀或浸渍加入相对原子中的一个或多个任选Q来制备的 比例由下标表示。

公开(公告)号：US06235678B1

公开(公告)日：2001-05-22

申请号：US09330690

申请日：1999-06-11

申请人： Edouard A. Mamedov ,  Shahid N. Shaikh

发明人： Edouard A. Mamedov ,  Shahid N. Shaikh

IPC分类号： B01J2328

CPC分类号： C07C5/48 ,  B01J21/04 ,  B01J23/002 ,  B01J23/02 ,  B01J23/06 ,  B01J23/08 ,  B01J23/14 ,  B01J23/18 ,  B01J23/22 ,  B01J23/26 ,  B01J23/74 ,  B01J37/038 ,  B01J37/08 ,  B01J2523/00 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/06 ,  C07C2523/08 ,  C07C2523/10 ,  C07C2523/14 ,  C07C2523/18 ,  C07C2523/20 ,  C07C2523/26 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  B01J2523/31 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/25 ,  B01J2523/842 ,  B01J2523/56 ,  B01J2523/13 ,  B01J2523/847 ,  B01J2523/54 ,  B01J2523/28 ,  B01J2523/43 ,  B01J2523/67 ,  B01J2523/845 ,  B01J2523/15 ,  B01J2523/27 ,  B01J2523/12 ,  B01J2523/32 ,  B01J2523/22

摘要： A catalyst composition for oxidative dehydrogenation of paraffinic hydrocarbons and other compounds having at least two adjacent carbon atoms each having at least one hydrogen atom. The catalyst composition is represented by the formula AaBbSbcVdAleOx wherein A is an alkali or alkaline earth metal; B is one or more optional elements selected from zinc, cadmium, lead, nickel, cobalt, iron, chromium, bismuth, gallium, niobium, tin and neodymium; a is 0 to 0.3, b is 0 to 5, c is 0.5 to 10, d is 1, e is 3 to 10, 7≦a+b+c+d+e≦25, and x is determined by the valence requirements of the elements present. A process for the oxidative dehydrogenation of paraffins using the catalyst composition.

摘要翻译： 用于链烷烃和具有至少两个相邻碳原子的其它化合物的氧化脱氢的催化剂组合物各自具有至少一个氢原子。 所述催化剂组合物由碱土金属和碱土金属代表， B是选自锌，镉，铅，镍，钴，铁，铬，铋，镓，铌，锡和钕中的一种或多种任选元素; a为0〜0.3，b为0〜5，c为0.5〜10，d为1，e为3〜10,7，= a + b + c + d + e <= 25，x由 现有要素的价格要求。 使用催化剂组合物对石蜡进行氧化脱氢的方法。