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    Process for the ammoxidation of alkanes and olefins
    1.
    发明授权
    Process for the ammoxidation of alkanes and olefins 有权
    烷烃和烯烃的氨氧化方法

    公开(公告)号：US07186670B2

    公开(公告)日：2007-03-06

    申请号：US10955550

    申请日：2004-09-30

    申请人： Edouard A. Mamedov ,  Kathleen A. Bethke ,  Shahid N. Shaikh ,  Armando Araujo ,  Neeta K. Kulkarni

    发明人： Edouard A. Mamedov ,  Kathleen A. Bethke ,  Shahid N. Shaikh ,  Armando Araujo ,  Neeta K. Kulkarni

    IPC分类号： B01J23/20

    CPC分类号： C07C253/24 ,  C07C253/26 ,  Y02P20/142 ,  C07C255/03

    摘要： A process for the vapor phase ammoxidation of alkanes and olefins with a catalyst of the general empirical formula: VSbaMbQcOx wherein M is at least one element selected from magnesium, aluminum, zirconium, silicon, hafnium, titanium and niobium, Q is at least one element selected from rhenium, tungsten, molybdenum, tantalum, manganese, phosphorus, cerium, tin, boron, scandium, bismuth, gallium, indium, iron, chromium, lanthanum, yttrium, zinc, cobalt, nickel, cadmium, copper, strontium, barium, calcium, silver, potassium, sodium and cesium, a is 0.5 to 20, b is 2 to 50, c is 0 to 10 and x is determined by the valence requirements of the elements present. The process has a co-feed of gaseous carbon dioxide with an alkane (paraffin) and/or alkene, ammonia and an oxygen-containing gas which react in the presence of the catalyst to form a nitrile and by-products.

    摘要翻译： 烷烃和烯烃的气相氨氧化方法，其催化剂具有以下通用经验公式：<？in-line-formula description =“In-line Formulas”end =“lead”？> VSb >>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>> 其中M是选自镁，铝，锆，硅，铪，钛和铌中的至少一种元素，Q是选自铼，钨，钼，钽，锰，磷，铈，锡，硼，钪中的至少一种元素 ，铋，镓，铟，铁，铬，镧，钇，锌，钴，镍，镉，铜，锶，钡，钙，银，钾，钠和铯，a为0.5〜20，b为2〜50 ，c为0至10，x由所存在的元素的化合价要求确定。 该方法具有气态二氧化碳与烷烃（石蜡）和/或烯烃，氨和含氧气体的共同进料，其在催化剂存在下反应以形成腈和副产物。

    Method of forming a syngas mixture
    5.
    发明授权
    Method of forming a syngas mixture 有权
    形成合成气混合物的方法

    公开(公告)号：US08551434B1

    公开(公告)日：2013-10-08

    申请号：US13537302

    申请日：2012-06-29

    申请人： Aghaddin Mammadov ,  Mike Huckman ,  Clark Rea ,  Xiankuan Zhang ,  Shahid N. Shaikh

    发明人： Aghaddin Mammadov ,  Mike Huckman ,  Clark Rea ,  Xiankuan Zhang ,  Shahid N. Shaikh

    IPC分类号： B01D53/14

    CPC分类号： C01B3/16 ,  C01B32/40 ,  C10K3/026 ,  Y02P20/142

    摘要： A method for making a syngas mixture is accomplished by introducing a gaseous feed mixture containing carbon dioxide and hydrogen into a reactor containing a non-zinc catalyst. The catalyst contacts the gaseous feed mixture to form syngas mixture reaction products. The reaction takes place in the presence of nickel-containing and/or iron-containing materials. The gaseous feed mixture is introduced into the reactor at a reactor inlet temperature of from 700° C. to 800° C., with the reaction being carried out at substantially adiabatic conditions or wherein the syngas mixture reaction products are removed from the reactor at a reactor outlet temperature of from 500° C. to 600° C.

    摘要翻译： 制备合成气混合物的方法是通过将含有二氧化碳和氢气的气态进料混合物引入含有非锌催化剂的反应器来完成的。 催化剂接触气态进料混合物以形成合成气混合反应产物。 反应在含镍和/或含铁材料的存在下进行。 将气态进料混合物在700℃至800℃的反应器入口温度下引入反应器，反应在基本上绝热的条件下进行，或者其中合成气混合物反应产物在反应器中以 反应器出口温度为500℃至600℃

    Mixed oxide based catalyst for the conversion of carbon dioxide to syngas and method of preparation and use
    6.
    发明授权
    Mixed oxide based catalyst for the conversion of carbon dioxide to syngas and method of preparation and use 有权
    用于将二氧化碳转化为合成气的混合氧化物基催化剂及其制备和使用方法

    公开(公告)号：US08962702B2

    公开(公告)日：2015-02-24

    申请号：US13315083

    申请日：2011-12-08

    申请人： Aghaddin Mamedov ,  Shahid N. Shaikh ,  Clark Rea ,  Xiankuan Zhang

    发明人： Aghaddin Mamedov ,  Shahid N. Shaikh ,  Clark Rea ,  Xiankuan Zhang

    IPC分类号： C07C27/00

    CPC分类号： C10G2/32 ,  B01J23/8892 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/009 ,  B01J37/031 ,  B01J37/08 ,  C01B3/40 ,  C01B2203/0238 ,  C01B2203/1041 ,  C10K3/026 ,  Y02E60/364 ,  Y02P20/142 ,  Y02P20/52

    摘要： The invention relates to a catalyst and process for making syngas mixtures including hydrogen, carbon monoxide and carbon dioxide. The process comprises contacting a gaseous feed mixture containing carbon dioxide and hydrogen with the catalyst, where the catalyst comprises Mn oxide and an auxiliary metal oxide selected from the group consisting of La, Ca, K, W, Cu, Al and mixtures or combinations thereof. The process enables hydrogenation of carbon dioxide into carbon monoxide with high selectivity, and good catalyst stability over time and under variations in processing conditions. The process can be applied separately, but can also be integrated with other processes, both up-stream and/or down-stream including methane reforming or other synthesis processes for making products like alkanes, aldehydes, or alcohols.

    摘要翻译： 本发明涉及一种制备合成气混合物的催化剂和方法，包括氢气，一氧化碳和二氧化碳。 该方法包括使含有二氧化碳和氢气的气态进料混合物与催化剂接触，其中催化剂包含Mn氧化物和选自La，Ca，K，W，Cu，Al及其混合物或组合的辅助金属氧化物 。 该方法能够以高选择性将二氧化碳氢化为一氧化碳，并且随着时间和处理条件的变化，催化剂的稳定性良好。 该方法可以分开应用，但也可以与上游和/或下游的其它方法（包括甲烷重整或用于制备产物如烷烃，醛或醇的其它合成方法）整合。

    Tetraalykylammonium polyoxoanionic oxidation catalysts
    8.
    发明授权
    Tetraalykylammonium polyoxoanionic oxidation catalysts 失效
    四亚烷基铵聚氧乙烯氧化催化剂

    公开(公告)号：US5817881A

    公开(公告)日：1998-10-06

    申请号：US902931

    申请日：1997-07-30

    申请人： Paul E. Ellis ,  James E. Lyons ,  Harry K. Myers, Jr. ,  Shahid N. Shaikh

    发明人： Paul E. Ellis ,  James E. Lyons ,  Harry K. Myers, Jr. ,  Shahid N. Shaikh

    IPC分类号： B01J23/881 ,  B01J27/188 ,  C07C29/50 ,  C07C45/33

    CPC分类号： C07C29/50 ,  B01J23/881 ,  B01J27/188 ,  C07C45/33

    摘要： Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H.sub.e-z �(n-C.sub.4 H.sub.9).sub.4 N!.sub.z (XM.sub.11 M'O.sub.39).sup.-eThe M' (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

    摘要翻译： 烷烃在空气或​​氧气中使用下式的铁取代的聚氧阴离子（POA）催化氧化：He-z [（n-C4H9）4N] z（XM11M'O39）-e M'（例如铁（III）/ 铁（II））还原电位受中心原子X和骨架金属M的选择以及四丁基铵基团的数量的影响。 已经发现Fe（III）/ Fe（II）还原电位的降低与增加的氧化活性相关。

    MIXED OXIDE BASED CATALYST FOR THE CONVERSION OF CARBON DIOXIDE TO SYNGAS AND METHOD OF PREPARATION AND USE
    10.
    发明申请
    MIXED OXIDE BASED CATALYST FOR THE CONVERSION OF CARBON DIOXIDE TO SYNGAS AND METHOD OF PREPARATION AND USE 有权
    用于将二氧化碳转化为合成物的混合氧化物催化剂及其制备和使用方法

    公开(公告)号：US20130150466A1

    公开(公告)日：2013-06-13

    申请号：US13315083

    申请日：2011-12-08

    申请人： Aghaddin Mamedov ,  Shahid N. Shaikh ,  Clark Rea ,  Xiankuan Zhang

    发明人： Aghaddin Mamedov ,  Shahid N. Shaikh ,  Clark Rea ,  Xiankuan Zhang

    IPC分类号： C07C27/00 ,  C01B3/40 ,  C01B3/04 ,  B01J23/889 ,  B01J21/04

    CPC分类号： C10G2/32 ,  B01J23/8892 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/009 ,  B01J37/031 ,  B01J37/08 ,  C01B3/40 ,  C01B2203/0238 ,  C01B2203/1041 ,  C10K3/026 ,  Y02E60/364 ,  Y02P20/142 ,  Y02P20/52

    摘要： The invention relates to a catalyst and process for making syngas mixtures including hydrogen, carbon monoxide and carbon dioxide. The process comprises contacting a gaseous feed mixture containing carbon dioxide and hydrogen with the catalyst, where the catalyst comprises Mn oxide and an auxiliary metal oxide selected from the group consisting of La, Ca, K, W, Cu, Al and mixtures or combinations thereof. The process enables hydrogenation of carbon dioxide into carbon monoxide with high selectivity, and good catalyst stability over time and under variations in processing conditions. The process can be applied separately, but can also be integrated with other processes, both up-stream and/or down-stream including methane reforming or other synthesis processes for making products like alkanes, aldehydes, or alcohols.

    摘要翻译： 本发明涉及一种制备合成气混合物的催化剂和方法，包括氢气，一氧化碳和二氧化碳。 该方法包括使含有二氧化碳和氢气的气态进料混合物与催化剂接触，其中催化剂包含Mn氧化物和选自La，Ca，K，W，Cu，Al及其混合物或组合的辅助金属氧化物 。 该方法能够以高选择性将二氧化碳氢化为一氧化碳，并且随着时间和处理条件的变化，催化剂的稳定性良好。 该方法可以分开应用，但也可以与上游和/或下游的其它方法（包括甲烷重整或用于制备产物如烷烃，醛或醇的其它合成方法）整合。