公开(公告)号：US20120315065A1

公开(公告)日：2012-12-13

申请号：US13579298

申请日：2011-03-03

申请人： Eiji Akiba ,  Masaaki Hachiya ,  Hidetaka Yamauchi ,  Bunshi Fugetsu

发明人： Eiji Akiba ,  Masaaki Hachiya ,  Hidetaka Yamauchi ,  Bunshi Fugetsu

IPC分类号： D02G3/44 ,  G03G15/02 ,  D06M11/74 ,  G03G21/00 ,  B82Y30/00

CPC分类号： D06M11/74 ,  D01D5/253 ,  D06M23/08 ,  G03G15/0233 ,  G03G21/0035 ,  Y10T428/292

摘要： An electro-conductive multifilament yarn for forming an electro-conductive brush comprises an electro-conductive fiber containing a synthetic fiber and a carbon nanotube covering a surface of the fiber. The synthetic fiber may have a single-filament fineness of not more than 30 dtex. The synthetic fiber may have 3 to 6 elongated recesses or grooves extending in a longitudinal direction thereof and have a multi-leaves or star-shaped cross-section. The electro-conductive multifilament yarn of the present invention has a high electro-conductivity and may have an electric resistance value of 1×106 to 1×1011 Ω/cm at 20° C. Further, the electro-conductivity has a high uniformity; the standard deviation of a logarithm of the electric resistance value may be not more than 1.0. Since the electro-conductive multifilament yarn of the present invention possesses uniform and excellent electro-conductive characteristics (charging or static removal property) required for an electro-conductive brush for an electrophotographic apparatus, the yarn is suitable as a cleaning brush for an electrophotographic apparatus.

摘要翻译： 用于形成导电刷的导电复丝纱线包括含有合成纤维的导电纤维和覆盖纤维表面的碳纳米管。 合成纤维的单丝细度可以不超过30分特。 合成纤维可以具有在其纵向方向上延伸的3至6个细长凹槽或凹槽，并且具有多叶或星形横截面。 本发明的导电性复丝纱具有高导电性，在20℃下的电阻值可以为1×10 6〜1×10 11＆OHgr / cm 2。此外，导电性具有高均匀性 ; 电阻值的对数的标准偏差可以不大于1.0。 由于本发明的导电复丝纱线具有电子照相设备用导电刷所需的均匀且优异的导电特性（充电或静电除去性），因此该纱线适合作为电子照相设备的清洁刷 。

公开(公告)号：US09035188B2

公开(公告)日：2015-05-19

申请号：US13579298

申请日：2011-03-03

申请人： Eiji Akiba ,  Masaaki Hachiya ,  Hidetaka Yamauchi ,  Bunshi Fugetsu

发明人： Eiji Akiba ,  Masaaki Hachiya ,  Hidetaka Yamauchi ,  Bunshi Fugetsu

IPC分类号： D02G3/44 ,  G03G15/02 ,  D06M11/74 ,  G03G21/00 ,  B82Y30/00

CPC分类号： D06M11/74 ,  D01D5/253 ,  D06M23/08 ,  G03G15/0233 ,  G03G21/0035 ,  Y10T428/292

摘要： An electro-conductive multifilament yarn for an electro-conductive brush that includes an electro-conductive fiber containing a synthetic fiber and a carbon nanotube covering a surface of the fiber. The synthetic fiber may have a single-filament fineness of not more than 30 dtex. The synthetic fiber may have 3 to 6 elongated recesses or grooves extending in a longitudinal direction thereof and have a multi-leaves or cross-section.

摘要翻译： 一种用于导电刷的导电复丝纱，其包括含有合成纤维的导电纤维和覆盖纤维表面的碳纳米管。 合成纤维的单丝细度可以不超过30分特。 合成纤维可以具有3至6个在其纵向方向上延伸的细长凹槽或凹槽，并且具有多叶或横截面。

公开(公告)号：US09885146B2

公开(公告)日：2018-02-06

申请号：US13060596

申请日：2009-08-31

申请人： Bunshi Fugetsu ,  Eiji Akiba ,  Masaaki Hachiya

发明人： Bunshi Fugetsu ,  Eiji Akiba ,  Masaaki Hachiya

IPC分类号： D06M11/74 ,  D06M10/02 ,  D06M10/06

CPC分类号： D06M11/74 ,  D06M10/02 ,  D06M10/06 ,  D06M2200/00 ,  Y10T428/292

摘要： Electro-conductive fibers comprise synthetic fibers and an electro-conductive layer containing carbon nanotubes and covering a surface of the synthetic fibers, and the coverage of the electro-conductive layer relative to the whole surface of the synthetic fibers is not less than 60% (particularly not less than 90%). The electric resistance value of the electro-conductive fibers ranges from 1×10−2 to 1×1010 Ω/cm, and the standard deviation of the logarithm of the electric resistance value is less than 1.0. The thickness of the electro-conductive layer ranges from 0.1 to 5 μm, and the ratio of the carbon nanotubes may be 0.1 to 50 parts by mass relative to 100 parts by mass of the synthetic fibers. The electro-conductive layer may further contain a binder. The electro-conductive fibers may be produced by immersing the synthetic fibers in a dispersion with vibrating the synthetic fibers to form the electro-conductive layer adhered to the surface of the synthetic fibers. The electro-conductive fibers have the carbon nanotubes homogeneously and firmly adhered to an almost whole of a surface thereof and have an electro-conductivity and a softness.

公开(公告)号：US20110151254A1

公开(公告)日：2011-06-23

申请号：US13060596

申请日：2009-08-31

申请人： Bunshi Fugetsu ,  Eiji Akiba ,  Masaaki Hachiya

发明人： Bunshi Fugetsu ,  Eiji Akiba ,  Masaaki Hachiya

IPC分类号： D02G3/36 ,  B05D5/12 ,  B82Y40/00

CPC分类号： D06M11/74 ,  D06M10/02 ,  D06M10/06 ,  D06M2200/00 ,  Y10T428/292

摘要： Electro-conductive fibers comprise synthetic fibers and an electro-conductive layer containing carbon nanotubes and covering a surface of the synthetic fibers, and the coverage of the electro-conductive layer relative to the whole surface of the synthetic fibers is not less than 60% (particularly not less than 90%). The electric resistance value of the electro-conductive fibers ranges from 1×10−2 to 1×1010 Ω/cm, and the standard deviation of the logarithm of the electric resistance value is less than 1.0. The thickness of the electro-conductive layer ranges from 0.1 to 5 μm, and the ratio of the carbon nanotubes may be 0.1 to 50 parts by mass relative to 100 parts by mass of the synthetic fibers. The electro-conductive layer may further contain a binder. The electro-conductive fibers may be produced by immersing the synthetic fibers in a dispersion with vibrating the synthetic fibers to form the electro-conductive layer adhered to the surface of the synthetic fibers. The electro-conductive fibers have the carbon nanotubes homogeneously and firmly adhered to an almost whole of a surface thereof and have an electro-conductivity and a softness.

摘要翻译： 导电纤维包括合成纤维和含有碳纳米管的导电层并覆盖合成纤维的表面，并且导电层相对于合成纤维的整个表面的覆盖率不小于60％（ 特别是不低于90％）。 导电性纤维的电阻值为1×10 -2〜1×10 10Ω·OHgr·/ cm，电阻值的对数的标准偏差小于1.0。 导电层的厚度为0.1〜5μm，相对于合成纤维100质量份，碳纳米管的比例可以为0.1〜50质量份。 导电层还可以含有粘合剂。 导电纤维可以通过将合成纤维浸入分散体中而使合成纤维振动而形成粘附在合成纤维表面上的导电层来制造。 导电纤维具有均匀且牢固地粘附到其几乎整个表面的碳纳米管，并且具有导电性和柔软性。

公开(公告)号：US08273290B2

公开(公告)日：2012-09-25

申请号：US12739175

申请日：2008-10-16

申请人： Katsuyoshi Kondoh ,  Bunshi Fugetsu

发明人： Katsuyoshi Kondoh ,  Bunshi Fugetsu

IPC分类号： C22C1/10 ,  B22F1/02 ,  B22F3/24 ,  C01B31/30

CPC分类号： C22C47/14 ,  B22F1/02 ,  B22F2998/10 ,  B22F2999/00 ,  C01B32/921 ,  C22C1/05 ,  C22C1/101 ,  C22C26/00 ,  C22C32/0084 ,  C22C2026/001 ,  C22C2026/002 ,  C22C2026/006 ,  C22C1/1084 ,  B22F9/026 ,  B22F3/10 ,  B22F3/20 ,  B22F2201/013 ,  B22F2201/02 ,  C22C1/0408

摘要： A method for producing a composite metal material includes preparing a solution containing a surfactant having both hydrophilicity and hydrophobicity, dispersing a nanosized to micro-sized fine carbonaceous substance into a state of being monodispersed in the solution, bringing the solution having the dispersed fine carbonaceous substance into contact with surface of a metal powder particle, drying the metal powder particle to make the fine carbonaceous substance in the monodispersed state adhere to the surface of the metal powder particle via a component of the solution, and thermally decomposing and removing the solution component adhering to the surface of the metal powder particle by heat-treating the metal powder particle either in a hydrogen-containing reducing atmosphere or in a vacuum atmosphere to partially expose the surface of the metal powder particle out of the adhering fine carbonaceous substance, and thus progress diffusion and sintering among the metal powder particles through exposed parts.

摘要翻译： 复合金属材料的制造方法包括制备含有具有亲水性和疏水性的表面活性剂的溶液，将纳米尺寸的微细粒状碳质物质分散到单分散在溶液中的状态，使具有分散的细小碳质物质的溶液 与金属粉末颗粒的表面接触，干燥金属粉末颗粒，以使单分散状态的细小碳质物质通过溶液的一部分与金属粉末颗粒的表面粘合，并且热分解和除去粘附在其上的溶液成分 通过在含氢还原气氛或真空气氛中对金属粉末颗粒进行热处理，将金属粉末颗粒的表面部分地从粘附的细小碳质物质中露出，从而进行到金属粉末颗粒的表面，从而进行 金属粉末颗粒之间的扩散和烧结 通过暴露部分。

公开(公告)号：US20100329966A1

公开(公告)日：2010-12-30

申请号：US12598624

申请日：2008-05-01

申请人： Bunshi Fugetsu

发明人： Bunshi Fugetsu

IPC分类号： D01F9/12 ,  C09K3/00

CPC分类号： D01F9/12 ,  B01F17/0007 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/16 ,  C01B32/174

摘要： The disclosed is a redispersible agglomerate of fine carbon fibers, which is obtained by adding the fine carbon fibers and a dispersing agent which shows solid state at least at ordinary temperature (20±10° C.) into an aqueous dispersion medium, and then removing the dispersion medium from a dispersion system where the carbon fibers are isolated individually and dispersed in the dispersion medium; and in which the carbon fibers are got together and solidified in the agglomerate while each carbon fiber maintains its isolated dispersibility; wherein the carbon content is in the range of 0.01-99.5% by weight, the dispersing agent content is in the range of 0.1-99.5% by weight, and the moisture content is in the range of less than. 10% by weight, based on the total weight of the agglomerate; and wherein the dispersing agent is one member selected from the group consisting of (1) surfactants capable of forming spheroidal, cylindrical, or tabular micelles of 5-2000 nm in diameter in an aqueous solution; (2) water-soluble high polymers having a weight average molecular weight in the range of 10,000-50,000,000; and (3) a combination of cyclodextrin and fullerene. This redispersible agglomerate of fine carbon fibers has a good handling property and would form a dispersed state of individually isolated carbon fibers when it is added in any of various dispersion media.

摘要翻译： 所公开的是通过将细碳纤维和至少在常温（20±10℃）下显示固态的分散剂添加到水性分散介质中而获得的细碳纤维的可再分散的团块，然后除去 来自分散体系的分散介质，其中碳纤维被单独分离并分散在分散介质中; 并且其中碳纤维聚集在一起并固化在附聚物中，而每个碳纤维保持其分离的分散性; 其中碳含量在0.01-99.5重量％的范围内，分散剂含量在0.1-99.5重量％的范围内，并且水分含量在小于等于的范围内。 10重量％，基于附聚物的总重量; 并且其中所述分散剂是选自（1）在水溶液中直径为5-2000nm的球形，圆柱形或片状胶束的表面活性剂中的一种; （2）重均分子量在10,000-50,000,000范围内的水溶性高聚物; 和（3）环糊精和富勒烯的组合。 这种可再分散的细碳纤维聚集体具有良好的处理性能，并且当将其分散在任何各种分散介质中时，将形成单独分离的碳纤维的分散状态。

公开(公告)号：US20080023396A1

公开(公告)日：2008-01-31

申请号：US11579905

申请日：2005-05-13

申请人： Bunshi Fugetsu

发明人： Bunshi Fugetsu

IPC分类号： B01J20/20 ,  C01B31/02

CPC分类号： C02F1/288 ,  B01J20/20 ,  B01J20/205 ,  B01J20/28004 ,  B01J20/28007 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/152 ,  C01B32/174 ,  C01B2202/02 ,  C01B2202/06 ,  C02F1/283 ,  C02F2305/08

摘要： Disclosed is a means for enabling fine carbons, which include from nano-sized to micro-sized carbons, to disperse uniformly. Specifically disclosed is a fine carbon dispersion which is produced by using a liquid fine carbon dispersion medium containing fine carbons including from nano-sized to micro-sized carbons and a dispersing agent for fine carbons.

摘要翻译： 公开了一种使纳米尺寸和微尺寸碳原子的细小碳均匀分散的方法。 具体公开的是通过使用包含纳米尺寸和微小尺寸碳的细碳的液体细碳分散介质和用于细小碳分子的分散剂制备的细碳分散体。

公开(公告)号：US08486362B2

公开(公告)日：2013-07-16

申请号：US12598624

申请日：2008-05-01

申请人： Bunshi Fugetsu

发明人： Bunshi Fugetsu

IPC分类号： D01F9/12

CPC分类号： D01F9/12 ,  B01F17/0007 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/16 ,  C01B32/174

摘要： The disclosed is a redispersible agglomerate of fine carbon fibers, which is obtained by adding the fine carbon fibers and a dispersing agent which shows solid state at least at ordinary temperature (20±10° C.) into an aqueous dispersion medium, and then removing the dispersion medium from a dispersion system where the carbon fibers are isolated individually and dispersed in the dispersion medium; and in which the carbon fibers are got together and solidified in the agglomerate while each carbon fiber maintains its isolated dispersibility; wherein the carbon content is in the range of 0.01-99.5% by weight, the dispersing agent content is in the range of 0.1-99.5% by weight, and the moisture content is in the range of less than. 10% by weight, based on the total weight of the agglomerate; and wherein the dispersing agent is one member selected from the group consisting of (1) surfactants capable of forming spheroidal, cylindrical, or tabular micelles of 5-2000 nm in diameter in an aqueous solution; (2) water-soluble high polymers having a weight average molecular weight in the range of 10,000-50,000,000; and (3) a combination of cyclodextrin and fullerene. This redispersible agglomerate of fine carbon fibers has a good handling property and would form a dispersed state of individually isolated carbon fibers when it is added in any of various dispersion media.

摘要翻译： 所公开的是通过将细碳纤维和至少在常温（20±10℃）下显示固态的分散剂添加到水性分散介质中而获得的细碳纤维的可再分散的团块，然后除去 来自分散体系的分散介质，其中碳纤维被单独分离并分散在分散介质中; 并且其中碳纤维聚集在一起并固化在附聚物中，而每个碳纤维保持其分离的分散性; 其中碳含量在0.01-99.5重量％的范围内，分散剂含量在0.1-99.5重量％的范围内，并且水分含量在小于等于的范围内。 10重量％，基于附聚物的总重量; 并且其中所述分散剂是选自（1）在水溶液中直径为5-2000nm的球形，圆柱形或片状胶束的表面活性剂中的一种; （2）重均分子量在10,000-50,000,000范围内的水溶性高聚物; 和（3）环糊精和富勒烯的组合。 这种可再分散的细碳纤维聚集体具有良好的处理性能，并且当其加入到各种分散介质中时，将形成单独分离的碳纤维的分散状态。

公开(公告)号：US06685837B2

公开(公告)日：2004-02-03

申请号：US10311927

申请日：2003-04-02

申请人： Bunshi Fugetsu

发明人： Bunshi Fugetsu

IPC分类号： B01D1508

CPC分类号： G01N30/96 ,  G01N30/02 ,  B01D15/362

摘要： A method for the separation of hydrogen ion, characterized in that a substance having a conjugate base (A−) of an acid (HA) as a functional group is used as a stationary phase, and an electrolyte containing a cation having a larger ion exchanging force than that of hydrogen ion is used as an eluent. The method allows the selective separation of hydrogen ion and the quantitative analysis thereof with high precision.

摘要翻译： 一种用于分离氢离子的方法，其特征在于使用具有作为官能团的酸（HA）的共轭碱（A - ）的物质作为固定相，并且使用含有较大的阳离子的电解质 离子交换力比氢离子交换力用作洗脱液。 该方法允许以高精度选择性分离氢离子及其定量分析。

公开(公告)号：US09327985B2

公开(公告)日：2016-05-03

申请号：US13515889

申请日：2009-12-18

申请人： Bunshi Fugetsu

发明人： Bunshi Fugetsu

IPC分类号： C01B31/02 ,  C01B31/04 ,  H01B1/04 ,  B82Y30/00 ,  B82Y40/00 ,  F16D69/02

CPC分类号： C01B31/0476 ,  B82Y30/00 ,  B82Y40/00 ,  C01B31/043 ,  C01B32/192 ,  C01B32/23 ,  F16D69/026 ,  F16D2200/006 ,  F16D2200/0095

摘要： [Means for solving]A graphene oxide sheet which changes to a substance having a graphene structure when reduced, and which is obtainable by dispersing a graphene-containing carbon substance using a dispersant to reduce the size of the aggregate units of the graphene-containing carbon substance, and then oxidizing the graphene-containing carbon substance.

摘要翻译： [解决方法]在还原时改变为具有石墨烯结构的物质的石墨烯氧化物片材，其可以通过使用分散剂分散含石墨烯的碳物质以减小含石墨烯碳的骨料单元的尺寸而获得 物质，然后氧化含石墨烯的碳物质。